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1. Full Text Osmium(III) Analogues of KP1019: Electrochemical and Chemical Synthesis, Spectroscopic Characterization, X‑ray Crystallography, Hydrolytic Stability, and Antiproliferative Activity
by Kuhn, Paul-Steffen and Büchel, Gabriel E and Jovanović, Katarina K and Filipović, Lana and Radulović, Siniša and Rapta, Peter and Arion, Vladimir B
Inorganic Chemistry, ISSN 0020-1669, 10/2014, Volume 53, Issue 20, pp. 11130 - 11139
A one-electron reduction of osmium(IV) complexes trans-[OsIVCl4(Hazole)2], where Hazole = 1H-pyrazole ([1]0), 2H-indazole ([2]0), 1H-imidazole ([3]0), and... 
CANCER-CELLS | DRUG | IN-VITRO | CRYSTAL-STRUCTURE | AZOLE HETEROCYCLES | RUTHENIUM COMPLEXES | TUMOR | ARENE ANTICANCER COMPLEX | ALPHA-AMINO-ACIDS | ANTITUMOR COMPLEX | CHEMISTRY, INORGANIC & NUCLEAR | Indazoles - chemistry | Electrochemical Techniques | Indazoles - chemical synthesis | Antineoplastic Agents - chemical synthesis | Humans | Osmium - chemistry | Models, Molecular | Crystallography, X-Ray | Structure-Activity Relationship | Antineoplastic Agents - chemistry | Spectrophotometry, Ultraviolet | Dose-Response Relationship, Drug | Hydrolysis | Indazoles - pharmacology | Organometallic Compounds - chemical synthesis | Cell Line, Tumor | Organometallic Compounds - chemistry | Antineoplastic Agents - pharmacology | Cell Proliferation - drug effects | Molecular Structure | HeLa Cells | Organometallic Compounds - pharmacology | Drug Screening Assays, Antitumor | X-ray crystallography | Analysis | Spectrum analysis | Chemical properties | Research | Osmium | Electric properties
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2. Full Text Nickel‐Catalyzed CH Arylation of Azoles with Haloarenes: Scope, Mechanism, and Applications to the Synthesis of Bioactive Molecules
by Yamamoto, Takuya and Muto, Kei and Komiyama, Masato and Canivet, Jérôme and Yamaguchi, Junichiro and Itami, Kenichiro
Chemistry – A European Journal, ISSN 0947-6539, 08/2011, Volume 17, Issue 36, pp. 10113 - 10122
Novel nickel‐based catalytic systems for the CH arylation of azoles with haloarenes and aryl triflates have been developed. We have established that... 
natural products | nickel | drug discovery | CH functionalization | cross‐coupling | heterocycles | cross-coupling | C-H functionalization | NATURAL-PRODUCT HENNOXAZOLE | NITROGEN-HETEROCYCLES | INCLUDING FREE (NH)-IMIDAZOLE | SELECTIVE ALKENYLATION | DIRECT C-2 ARYLATION | HETEROAROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | CROSS-COUPLING REACTIONS | BOND ARYLATION | CYANOBACTERIUM NOSTOC-MUSCORUM | BACTERIAL PROTEIN-SYNTHESIS | Azoles - chemistry | Biological Products - chemical synthesis | Oxazoles - chemical synthesis | Nickel - chemistry | Thiazoles - chemical synthesis | Febuxostat | Pyridines - chemical synthesis | Catalysis | Benzoxazoles - chemical synthesis | Synthesis (chemistry) | Catalysts | Aromatic compounds | Heterocyclic compounds | Chlorides | Joining | Nickel | Environmental and Society | Chemical Sciences | Environmental Sciences
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3. Full Text Decarbonylative C–H Coupling of Azoles and Aryl Esters: Unprecedented Nickel Catalysis and Application to the Synthesis of Muscoride A
by Amaike, Kazuma and Muto, Kei and Yamaguchi, Junichiro and Itami, Kenichiro
Journal of the American Chemical Society, ISSN 0002-7863, 08/2012, Volume 134, Issue 33, pp. 13573 - 13576
A nickel-catalyzed decarbonylative C–H biaryl coupling of azoles and aryl esters is described. The newly developed catalytic system does not require the use of... 
FUNCTIONALIZATION | HETEROARENES | DIRECT ARYLATION | REAGENTS | HETEROCYCLES | BOND ARYLATION | CYANOBACTERIUM NOSTOC-MUSCORUM | DECARBOXYLATIVE ARYLATION | ANHYDRIDES | CHEMISTRY, MULTIDISCIPLINARY | BENZOIC-ACIDS | Azoles - chemistry | Oxazoles - chemical synthesis | Nickel - chemistry | Pyrrolidines - chemical synthesis | Esters - chemistry | Models, Molecular | Catalysis | Azoles - chemical synthesis | Pyrrolidines - chemistry | Oxazoles - chemistry | Azoles (Class of compounds) | Arylation | Carbonyl compounds | Analysis | Nickel | Chemical properties
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4. Full Text Organocatalytic Reactions Enabled by N‑Heterocyclic Carbenes
by Flanigan, Darrin M and Romanov-Michailidis, Fedor and White, Nicholas A and Rovis, Tomislav
Chemical Reviews, ISSN 0009-2665, 09/2015, Volume 115, Issue 17, pp. 9307 - 9387
HIGHLY ENANTIOSELECTIVE SYNTHESIS | FORMAL 3+2 ANNULATION | TRANSITION-METAL-COMPLEXES | DIELS-ALDER REACTIONS | TO-TAIL DIMERIZATION | ONE-POT SYNTHESIS | ACYCLIC ALPHA,BETA-UNSATURATED CARBONYLS | ASYMMETRIC BENZOIN CONDENSATION | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED CONJUGATE ADDITIONS | INTRAMOLECULAR STETTER REACTION | Azoles - chemistry | Catalysis | Azoles - chemical synthesis | Stereoisomerism | Lewis Bases - chemistry | Chemical properties | Research | Chemical synthesis | Heterocyclic compounds | Carbenes
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5. Full Text Metathesis in the Synthesis of Aromatic Compounds
by van Otterlo, Willem A. L and de Koning, Charles B
Chemical Reviews, ISSN 0009-2665, 08/2009, Volume 109, Issue 8, pp. 3743 - 3782
NITROGEN-CONTAINING HETEROCYCLES | RUTHENIUM CARBENE COMPLEXES | RING-CLOSING METATHESIS | TRANSITION-METAL-COMPLEXES | DIELS-ALDER REACTION | DOUBLE-BOND MIGRATION | TANDEM ENYNE METATHESIS | BENZO-FUSED HETEROCYCLES | CHEMISTRY, MULTIDISCIPLINARY | BIS(ALPHA-AMINO ACID) DERIVATIVES | NATURAL-PRODUCT FRAMEWORKS | Azoles - chemistry | Hydrocarbons, Aromatic - chemistry | Furans - chemistry | Pyridines - chemistry | Pyridines - chemical synthesis | Indoles - chemical synthesis | Furans - chemical synthesis | Hydrocarbons, Aromatic - chemical synthesis | Azoles - chemical synthesis | Indoles - chemistry | Hydrocarbons | Chemical properties | Structure | Aromatic compounds | Benzene
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6. Full Text Bis[3-(5-nitroimino-1,2,4-triazolate)]-Based Energetic Salts: Synthesis and Promising Properties of a New Family of High-Density Insensitive Materials
by Wang, Ruihu and Xu, Hongyan and Guo, Yong and Sa, Rongjian and Shreeve, Jean’ne M
Journal of the American Chemical Society, ISSN 0002-7863, 09/2010, Volume 132, Issue 34, pp. 11904 - 11905
Bis[3-(5-nitroimino-1,2,4-triazolate)]-based energetic salts were synthesized in a simple, straightforward manner. They exhibit low solubility in available... 
ACID | IONIC LIQUIDS | CHEMISTRY, MULTIDISCIPLINARY | 2-NITROGUANIDINE DERIVATIVES | Salts - chemistry | Temperature | Solvents - chemistry | Triazoles - chemistry | Imines - chemistry | Solubility | Triazoles - chemical synthesis | Molecular Structure | Imines - chemical synthesis | Energy-Generating Resources | Azoles (Class of compounds) | Thermal properties | Hydrolysis | Schiff bases | Analysis | Chemical properties | Structure
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7. Full Text Synthesis of N‑(α-Fluorovinyl)azoles by the Reaction of Difluoroalkenes with Azoles
by Xiong, Yang and Zhang, Xuxue and Huang, Tao and Cao, Song
The Journal of Organic Chemistry, ISSN 0022-3263, 07/2014, Volume 79, Issue 14, pp. 6395 - 6402
A mild and versatile method for the construction of C–N bonds by the reaction of (2,2-difluorovinyl)arenes with various N–H-containing heterocycles in the... 
NITROGEN-CONTAINING HETEROCYCLES | ARYL BROMIDES | CATALYZED N-ARYLATION | INTRAMOLECULAR CYCLIZATION | DIPEPTIDYL-PEPTIDASE-IV | CROSS-COUPLING REACTION | NUCLEOPHILIC 5-ENDO-TRIG CYCLIZATION | C-N | CHEMISTRY, ORGANIC | ULLMANN-TYPE REACTION | VINYL BROMIDES | Azoles - chemistry | Hydrocarbons, Fluorinated - chemical synthesis | Heterocyclic Compounds - chemical synthesis | Hydrocarbons, Fluorinated - chemistry | Molecular Structure | Heterocyclic Compounds - chemistry | Azoles (Class of compounds) | Chemical properties | Research | Structure | Chemical synthesis | Olefins
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8. Full Text Synthesis of [5,6]‐Bicyclic Heterocycles with a Ring‐Junction Nitrogen Atom: Rhodium(III)‐Catalyzed C−H Functionalization of Alkenyl Azoles
by Halskov, Kim Søholm and Roth, Howard S and Ellman, Jonathan A
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2017, Volume 56, Issue 31, pp. 9183 - 9187
The first syntheses of privileged [5,6]‐bicyclic heterocycles, with ring‐junction nitrogen atoms, by transition metal catalyzed C−H functionalization of... 
C−H activation | homogeneous catalysis | cyclization | nitrogen heterocycles | rhodium | Azoles - chemistry | Cyclization | Nitrogen - chemistry | Bridged Bicyclo Compounds, Heterocyclic - chemistry | Alkynes - chemistry | Catalysis | Coordination Complexes - chemistry | Hydrogen - chemistry | Isomerism | Carbon - chemistry | Rhodium - chemistry | Bridged Bicyclo Compounds, Heterocyclic - chemical synthesis | DESIGN | OLEDS | CHEMISTRY, MULTIDISCIPLINARY | EXCIMER EMISSION | MOLECULES | WIDE TEMPERATURE-RANGE | PHOSPHORESCENCE | C-H activation | LUMINESCENCE | FLUORESCENCE | PHOTOPHYSICS | CYCLOMETALATED PLATINUM(II) COMPLEXES | Rhodium | Nitrogen | Azoles | Synthesis | Triazoles | Heterocyclic compounds | Pyrazoles | Nitrogen atoms | Chemical reactions | Coupling | Alkynes
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9. Full Text Total Synthesis of (−)-Enigmazole A
by Ai, Yanran and Kozytska, Mariya V and Zou, Yike and Khartulyari, Anton S and Smith, Amos B
Journal of the American Chemical Society, ISSN 0002-7863, 12/2015, Volume 137, Issue 49, pp. 15426 - 15429
A highly convergent, stereocontrolled total synthesis of the architecturally complex marine sponge metabolite (−)-enigmazole A has been achieved. Highlights... 
OXIDATION | ALCOHOLS | REARRANGEMENT | ENIGMAZOLE | EVOLUTION | CONSTRUCTION | ANION RELAY CHEMISTRY | MULTICOMPONENT LINCHPIN COUPLINGS | CHEMISTRY, MULTIDISCIPLINARY | STEREOCONTROLLED SYNTHESIS | METATHESIS | Organophosphorus Compounds - chemical synthesis | Oxazoles - chemical synthesis | Macrolides - chemistry | Macrolides - chemical synthesis | Organophosphorus Compounds - chemistry | Molecular Structure | Oxazoles - chemistry | Azoles (Class of compounds) | Oxidation-reduction reaction | Usage | Chemical properties | Chemical synthesis | Communication
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10. Full Text Single-Step Synthesis of Iodinated Oxazoles from N‑Propargyl Amides Mediated by I2/Iodosylbenzene/Trimethylsilyl Trifluoromethanesulfonate Systems
by Suzuki, Sho and Saito, Akio
The Journal of Organic Chemistry, ISSN 0022-3263, 11/2017, Volume 82, Issue 22, pp. 11859 - 11864
A combination of I2, iodosylbenzene, and trimethylsilyl trifluoromethanesulfonate (TMSOTf) is effective for single-step synthesis of iodinated oxazoles from... 
Azoles (Class of compounds) | Usage | Chemical properties | Ring formation (Chemistry) | Chemical synthesis
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11. Full Text o-Iodoxybenzoic Acid Mediated Oxidative Desulfurization Initiated Domino Reactions for Synthesis of Azoles
by Chaudhari, Pramod S and Pathare, Sagar P and Akamanchi, Krishnacharaya G
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2012, Volume 77, Issue 8, pp. 3716 - 3723
A systematic exploration of thiophilic ability of o-iodoxybenzoic acid (IBX) for oxidative desulfurization to trigger domino reactions leading to new... 
Azoles - chemistry | Thiadiazoles - chemical synthesis | Models, Chemical | Nitrogen - chemistry | Oxidation-Reduction | Iodobenzenes - chemistry | Thiadiazoles - chemistry | Triazoles - chemistry | Triazoles - chemical synthesis | Azoles - chemical synthesis | Chemical properties | Structure | Triazoles | Cascade reactions | Benzene | Analysis
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12. Full Text Total Synthesis of Lycoricidine and Narciclasine by Chemical Dearomatization of Bromobenzene
by Southgate, Emma H and Holycross, Daniel R and Sarlah, David
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2017, Volume 56, Issue 47, pp. 15049 - 15052
The total synthesis of lycoricidine and narciclasine is enabled by an arenophile‐mediated dearomative dihydroxylation of bromobenzene. Subsequent transpositive... 
total synthesis | narciclasine | lycoricidine | alkaloids | dearomatization | Amaryllidaceae Alkaloids - chemistry | Phenanthridines - chemical synthesis | Amaryllidaceae Alkaloids - chemical synthesis | Hydroxylation | Phenanthridines - chemistry | Stereoisomerism | Amides - chemistry | Molecular Structure | Bromobenzenes - chemistry | TRIARYLATED AZOLES | 1,4-BENZADIYNE EQUIVALENT | OLEFIN SYNTHESIS | PROGRAMMED SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | DIVERSITY-ORIENTED SYNTHESIS | EXTENDED PI-SYSTEMS | SEQUENTIAL ARYLATION | ORGANIC ELECTRONICS | TETRAARYL-SUBSTITUTED PYRAZOLES | AROMATIC-HYDROCARBON | Synthesis | Organic compounds | Dihydrodiol | Bromobenzene | Chemical synthesis
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13. Full Text Direct Arylation of Imidazo[1,2-a]pyridine at C-3 with Aryl Iodides, Bromides, and Triflates via Copper(I)-Catalyzed C–H Bond Functionalization
by Cao, Hua and Zhan, Haiying and Lin, Yuanguang and Lin, Xiulian and Du, Zuodong and Jiang, Huanfeng
Organic Letters, ISSN 1523-7060, 04/2012, Volume 14, Issue 7, pp. 1688 - 1691
A convenient method for the copper(I)-catalyzed arylation of substituted imidazo[1,2-a]pyridine has been developed. This method is applicable to a variety of... 
COPPER-CATALYZED ARYLATION | AZOLES | PALLADIUM | ACTIVATION | HETEROARENES | HETEROCYCLES | COUPLING REACTIONS | MEDIATED DIRECT ARYLATION | CHEMISTRY, ORGANIC | DERIVATIVES | GENERAL-METHOD | Pyridines - chemistry | Imidazoles - chemistry | Pyridines - chemical synthesis | Hydrocarbons, Brominated - chemical synthesis | Mesylates - chemistry | Hydrocarbons, Iodinated - chemical synthesis | Combinatorial Chemistry Techniques | Copper - chemistry | Hydrocarbons, Brominated - chemistry | Molecular Structure | Catalysis | Hydrocarbons, Iodinated - chemistry | Imidazoles - chemical synthesis | Mesylates - chemical synthesis
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14. Full Text Ligand-Controlled Synthesis of Azoles via Ir-Catalyzed Reactions of Sulfoxonium Ylides with 2‑Amino Heterocycles
by Phelps, Alicia M and Chan, Vincent S and Napolitano, José G and Krabbe, Scott W and Schomaker, Jennifer M and Shekhar, Shashank
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2016, Volume 81, Issue 10, pp. 4158 - 4169
An iridium-catalyzed method was developed for the synthesis of imidazo-fused pyrrolopyrazines. The presence or absence of a nitrogenated ligand controlled the... 
CYCLOPROPANATION | CHEMISTRY, ORGANIC | SULFUR YLIDES | DIAZOKETONES | METAL CARBENES | Azoles (Class of compounds) | Sulfur compounds | Research | Chemical properties | Chemical synthesis
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15. Full Text Conversion of amides to esters by the nickel-catalysed activation of amide C-N bonds
by Hie, Liana and Fine Nathel, Noah F and Shah, Tejas K and Baker, Emma L and Hong, Xin and Yang, Yun-Fang and Liu, Peng and Houk, K.N and Garg, Neil K
Nature, ISSN 0028-0836, 08/2015, Volume 524, Issue 7563, pp. 79 - 83
Amides are common functional groups that have been studied for more than a century(1). They are the key building blocks of proteins and are present in a broad... 
AZOLES | MILD | CROSS-COUPLING REACTIONS | ARYL CARBOXYLATES | AMINES | SCOPE | MULTIDISCIPLINARY SCIENCES | TRANSAMIDATION | CLEAVAGE | CHEMOSELECTIVITY | METHYL-ESTERS | Thermodynamics | Nickel - chemistry | Nitrogen - chemistry | Amides - chemistry | Benzoates - chemical synthesis | Catalysis | Carbon - chemistry | Esters - chemical synthesis | Alcohols | Benzamides - chemistry | Chemistry Techniques, Synthetic - methods | Density functionals | Amides | Nickel | Chemical properties | Proteases | Analysis | Studies | Chemical bonds | Ligands | Nitrogen | Conversion | Carbon
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16. Full Text Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
by Zhang, Jie-Peng and Zhang, Yue-Biao and Lin, Jian-Bin and Chen, Xiao-Ming
Chemical Reviews, ISSN 0009-2665, 02/2012, Volume 112, Issue 2, pp. 1001 - 1033
ZEOLITIC IMIDAZOLATE FRAMEWORKS | SELECTIVE GAS-ADSORPTION | RAY-POWDER DIFFRACTION | ROOM-TEMPERATURE SYNTHESIS | CARBON-DIOXIDE CAPTURE | MOLECULAR-SIEVE MEMBRANE | INDUCED SUPRAMOLECULAR ISOMERISM | INFINITE POLYMERIC FRAMEWORKS | STATE COORDINATION CHEMISTRY | HIGH THERMAL-STABILITY | CHEMISTRY, MULTIDISCIPLINARY | Azoles - chemistry | Models, Molecular | Organometallic Compounds - chemistry | Molecular Structure | Metals, Heavy - chemistry | Organometallic Compounds - chemical synthesis | Azoles (Class of compounds) | Analysis | Organometallic compounds | Chemical bonds | Chemical properties | Structure | Zeolites
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17. Full Text Rhodium‐Catalyzed Direct CH Amination of Benzamides with Aryl Azides: A Synthetic Route to Diarylamines
by Ryu, Jaeyune and Shin, Kwangmin and Park, Sae Hume and Kim, Ji Young and Chang, Sukbok
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2012, Volume 51, Issue 39, pp. 9904 - 9908
No muss, no fuss: A rhodium‐catalyzed direct intermolecular CH amination of benzamides and ketoximes using aryl azides as the amine source has been developed.... 
CH activation | amination | diarylamines | aryl azides | rhodium | C-H activation | AZOLES | ROOM-TEMPERATURE | TRANSITION-METAL-COMPLEXES | FUNCTIONALIZATIONS | VINYL AZIDES | AMIDATION | C?H activation | ORGANIC AZIDES | CHEMISTRY, MULTIDISCIPLINARY | CHLOROAMINES | N BOND FORMATION | INHIBITORS | Amines - chemistry | Amination | Amines - chemical synthesis | Aniline Compounds - chemistry | Catalysis | Azides - chemical synthesis | Azides - chemistry | Benzamides - chemical synthesis | Aniline Compounds - chemical synthesis | Rhodium - chemistry | Benzamides - chemistry | Amines | Oxidants | Aromatic compounds | Oxidizing agents | Byproducts | Tolerances | Benzamide
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