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b (22) 22
chemistry, inorganic & nuclear (10) 10
chemistry, multidisciplinary (10) 10
frustrated lewis pairs (8) 8
polymer science (8) 8
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chemistry, organic (6) 6
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chemistry (5) 5
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trisborane (5) 5
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imines (4) 4
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effect of alkylaluminums (2) 2
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ethylene (2) 2
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guanidinate ligands synthesis (2) 2
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The Journal of Organic Chemistry, ISSN 0022-3263, 06/2014, Volume 79, Issue 12, pp. 5794 - 5798
Unlike the extensively studied perfluoroalkyl fullerene adducts, perfluorophenyl fullerene adducts are quite difficult to prepare by known methods.... 
OXIDATION | ALCOHOLS | BUCKMINSTERFULLERENE | ETHERS | NUCLEOPHILIC-SUBSTITUTION | B(C6F5) | FLUOROALKYL GROUP | CHEMISTRY, ORGANIC | VICINAL FULLERENDIOL | DERIVATIVES | TRIS(PENTAFLUOROPHENYL)BORON | Epoxy compounds | Chemical properties | Research
Journal Article
JOURNAL OF CHEMICAL PHYSICS, ISSN 0021-9606, 09/2017, Volume 147, Issue 9, p. 094302
Using Born-Oppenheimer molecular dynamics (BOMD), we explore the nature of interactions between H-2 and the activated carbonyl carbon, C(carbonyl), of the... 
GRAPHICAL PROCESSING UNITS | QUANTUM-CHEMISTRY | THERMODYNAMICS | DIHYDROGEN ACTIVATION | B(C6F5) | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | HYDROGEN-ATOM | ALDEHYDES | PROTON-TRANSFER | ASSOCIATION | PAIRS
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 12/2010, Volume 29, Issue 23, pp. 6422 - 6432
Reaction of 1-morpholinocyclohexene with B(C6F5)(3) and phenylacetylene gave a mixture of two compounds, [C6H10N(CH2CH2)(2)O][PhCCB(C6F5)(3)] (1a) and... 
VINYLPYRROLES | ACTIVATION | HYDROGENATION | ZWITTERIONS | REACTIVITY | CHEMISTRY, ORGANIC | GENERATION | METALLOCENE | ACIDIC SP CARBONS | N-HETEROCYCLE-B(C6F5) COMPLEXES | C-H BONDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
European Polymer Journal, ISSN 0014-3057, 04/2020, Volume 129, p. 109632
[Display omitted] •B(C6F5)3 affords high molecular weight poly(p-metoxystyrene) at room temperature.•Acetontirile participates in stabilization of growing... 
Cationic polymerization | p-Metoxystyrene | Proton trap | Acetonitrile | B(C6F5)3
Journal Article
EUROPEAN POLYMER JOURNAL, ISSN 0014-3057, 04/2020, Volume 129
The cationic polymerization of p-metoxystyrene co-initiated by B(C6F5)(3) in CH2Cl2/CH3CN mixtures at room temperature has been studied. It was shown that in... 
POLYMER SCIENCE | p-Metoxystyrene | TRIS(PENTAFLUOROPHENYL)BORANE | MECHANISM | Proton trap | LEWIS-ACID | ISOBUTENE | B(C6F5) | Cationic polymerization | ADDUCTS | ISOBUTYLENE POLYMERIZATION | ELECTRON-PAIR DONORS | Acetonitrile | LIVING CARBOCATIONIC POLYMERIZATION | HALOBORATION | COPOLYMERIZATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2017, Volume 139, Issue 29, pp. 10062 - 10071
Single electron transfer (SET) reactions are effected by the combination of a Lewis acid (e.g., E­(C6F5)3 E = B or Al) with a small molecule substrate and... 
FREE HYDROGEN ACTIVATION | DIHYDROGEN | TRIS(PENTAFLUOROPHENYL)BORANE | REDUCTION | PHOSPHINES | COMPLEXES | B(C6F5) | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE | RADICAL-ION | Anions | Chemical properties | Research | Acids
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 06/2016, Volume 45, Issue 26, pp. 10717 - 10729
Tris(pentafluorophenyl)borane, [B(C6F5)3], has been used as an efficient catalyst in the guanylation reaction of amines with carbodiimide under mild... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2009, Volume 131, Issue 25, pp. 8958 - 8970
The addition of alkali or silver salts of dicyanoamide (dca), tricyanomethanide (tcm) and tetracyanoborate (tcb) to a solution of B(C6F5)3 in diethyl ether... 
VOLUMES | CRYSTAL-STRUCTURE | COMPLEXES | B(C6F5) | IONIC LIQUIDS | (FLUOROORGANO)FLUOROBORANES | SALTS | CHEMISTRY, MULTIDISCIPLINARY | NONCOORDINATING ANIONS | CATIONS | Cyanides | Catalysis | Chemical properties | Ether | Structure | Analysis
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 07/2017, Volume 56, Issue 31, pp. 9202 - 9206
Frustrated Lewis pair (FLP) chemistry enables a rare example of alkyne 1,2-hydrocarbation with N-methyl-acridinium salts as the carbon Lewis acid. This... 
hydride transfer | SIGMA-BOND ACTIVATION | ACIDS | alkynes | carbocations | B(C6F5) | REACTIVITY | 1,2-hydrocarbation | SALTS | CHEMISTRY, MULTIDISCIPLINARY | ALKENES | ADDITIONS | frustrated Lewis pairs
Journal Article
Organometallics, ISSN 0276-7333, 08/2011, Volume 30, Issue 16, pp. 4284 - 4291
The syntheses of some novel fluorinated and nonfluorinated hydroxyborate salts, [Q]+[HOB(C6F5)3]− and [Q]+[HOBPh3]− ([Q]+ = aprotic cation), are reported. The... 
ELECTRON-TRANSFER | BORON | ACID | LIGANDS | BOROXIDE COMPLEXES | CRYSTAL-STRUCTURE | B(C6F5) | OLEFIN POLYMERIZATION | WATER ADDUCTS | CHEMISTRY, ORGANIC | SELECTIVE SYNTHESIS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Zeitschrift für Physikalische Chemie, ISSN 0942-9352, 06/2013, Volume 227, Issue 6, pp. 751 - 773
H and F NMR spectroscopy, X-ray diffractometry and DFT computations have been used for investigating the interaction between the Lewis base pyridine and... 
19F NMR Spectroscopy | DFT Computations | Lewis Bases | Fluoroarylboranes | Hydrogen Bond | F NMR spectroscopy | Lewis bases | DFT computations | Hydrogen bond | B(C6F5) | F-19 NMR Spectroscopy | CHEMISTRY, PHYSICAL | BASICITY | PROTON-TRANSFER | H-1 | WATER
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2018, Volume 24, Issue 29, pp. 7364 - 7368
This work showcases the 1,3‐haloboration reaction of alkynes in which boron and chlorine add to propargyl systems in a proposed sequential oxazoliumborate... 
boranes | Lewis acid | haloboration | boron | alkynes | HYDROBORATION | HYDROGENATION | HOMOALLYLIC ALCOHOLS | B(C6F5) | HALOBORATION REACTION | ALLYL-BORON | TERMINAL ALKYNES | FRUSTRATED LEWIS PAIRS | CHEMISTRY, MULTIDISCIPLINARY | ALKENES | CYCLIZATION | Boron | Chlorine | Migration | Esters | Density functional theory | Chelates | Alkynes | Communications | Communication
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2011, Volume 50, Issue 51, pp. 12227 - 12231
Channeling the frustration: Frustrated Lewis pairs (FLPs) consisting of ArF2BH 1 with NEt3 or DABCO can activate H2 under mild conditions. Theoretical... 
boranes | amines | hydrogen | frustrated Lewis pairs | CARBENE | COMPLEX | MOLECULAR-STRUCTURE | IMINES | B(C6F5) | FREE CATALYTIC-HYDROGENATION | REACTIVITY | CRYSTAL | H-2 ACTIVATION | BORANE | CHEMISTRY, MULTIDISCIPLINARY | Activated | Channeling | Amines | Pathways | Mathematical analysis | Cleavage | Frustration
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2017, Volume 56, Issue 32, pp. 9512 - 9516
The development of a boron/nitrogen‐centered frustrated Lewis pair (FLP) with remarkably high water tolerance is presented. As systematic steric tuning of the... 
water tolerance | strained molecules | reductive amination | boron | frustrated Lewis pairs | STERIC STRAINS | DIHYDROGEN ACTIVATION | CATALYTIC-HYDROGENATION | B(C6F5) | ALDEHYDES | IRON | CHEMISTRY, MULTIDISCIPLINARY | KETONES | AMINES | ARYLAMINES | Hydrogenation | Lewis acid | Carbonyl compounds | Boron | Acids | Amination | Catalysis | Carbonyls
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 09/2000, Volume 19, Issue 19, pp. 3983 - 3990
The reaction of tris(pentafluorophenyl)boron trihydrate, B(C6F5)(3).3H(2)O (1), with the nickel dimer [(PPh2CH=C(O)Ph)Ni(Ph)](2) (3) (synthesized by phosphine... 
LIGANDS | HOMOGENEOUS OLEFIN POLYMERIZATION | MOLECULAR-STRUCTURE | LEWIS-ACID | ORGANOMETALLIC COMPLEXES | CATALYTIC ACTIVITY | CHEMISTRY, ORGANIC | METALLOCENE-LIKE INITIATOR | (ETA-CME)TIME(MU-ME)B(C6F5) | ETHYLENE POLYMERIZATION | NONCOORDINATING ANIONS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 02/2015, Volume 54, Issue 6, pp. 1749 - 1753
Ansa-aminoborane 1 (ortho-TMPC6H4BH2; TMP=2,2,6,6-tetramethylpiperid-1-yl), a frustrated Lewis pair with the smallest possible Lewis acidic boryl site (BH2),... 
FREE HYDROGEN ACTIVATION | IMINES | CATALYTIC-HYDROGENATION | B(C6F5) | thermodynamics | REACTIVITY | BORANE | CHEMISTRY, MULTIDISCIPLINARY | EXCHANGE-REACTIONS | density functional calculations | ENANTIOSELECTIVE HYDROGENATION | aminoboranes | METAL-FREE HYDROGENATION | ASYMMETRIC HYDROGENATION | kinetics | frustrated Lewis pairs
Journal Article
Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 04/2012, Volume 50, Issue 7, pp. 1325 - 1332
Tris(pentafluorophenyl)gallium (3) and aluminum (7) are active coinitiators for the production of medium‐high molecular weight (MW) polymers of styrene and... 
polymerization | cationic | green | tris(pentafluorophenyl)gallium | polystyrene | tris(pentafluorophenyl)aluminum | aqueous | polyisobutene | MOLECULAR-DYNAMICS | POLYMER SCIENCE | YB(OTF) | LEWIS-ACID | EMULSION | P-METHOXYSTYRENE | SUSPENSION | H2O-CENTER-DOT-B(C6F5) | MINIEMULSION | MEDIA | WATER | Solvents | Aluminum | Styrenes | Media | Polymerization | Droplets | Aliphatic compounds | Monomers
Journal Article
Chem, ISSN 2451-9294, 08/2017, Volume 3, Issue 2, pp. 259 - 267
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 2016, Volume 45, Issue 26, pp. 10717 - 10729
Tris(pentafluorophenyl)borane, [B(C6F5)(3)], has been used as an efficient catalyst in the guanylation reaction of amines with carbodiimide under mild... 
COORDINATION CHEMISTRY | DOT-F-C | SUBSTITUTED GUANIDINES | GUANIDINATE LIGANDS SYNTHESIS | COMPLEXES | B(C6F5) | OLEFIN POLYMERIZATION | N-H | FRUSTRATED LEWIS PAIRS | CARBODIIMIDES | CHEMISTRY, INORGANIC & NUCLEAR | Amines | Pathways | Catalysts | Nitrogen atoms | Guanidines | Catalysis | Carbodiimides | Adducts
Journal Article
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