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Chemical Communications: Chem Comm, ISSN 1359-7345, 01/2015, Volume 51, Issue 13, pp. 2495 - 2505
Amide bond formation reactions are among the most important transformations in organic chemistry because of the widespread occurrence of amides in... 
Organic chemistry | Synthesis (chemistry) | Catalysts | Natural products | Amides | Transformations | Catalysis | Bonding
Journal Article
Chemical Communications, ISSN 1359-7345, 1/2015, Volume 51, Issue 13, pp. 2495 - 255
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 11/2018, Volume 83, Issue 21, pp. 13103 - 13110
A novel rearrangement reaction based on the structure of N-fluoro-N-alkyl benzenesulfonamide was developed. The reaction proceeded readily at 50 °C in formic... 
CHEMISTRY, ORGANIC | MECHANISTIC INSIGHT | BECKMANN REARRANGEMENT
Journal Article
Industrial & Engineering Chemistry Research, ISSN 0888-5885, 12/2017, Volume 56, Issue 48, pp. 14207 - 14213
The main impurities produced in the Beckmann rearrangement of cyclohexanone oxime (CHO) to yield ε-caprolactam (CPL) in oleum were identified as cyclohexanone,... 
SYSTEM | ENGINEERING, CHEMICAL | QUALITY | TRIFLUOROACETIC-ACID | ALPHA-HYDROXY KETONE | CHROMATOGRAPHY | HETEROGENEOUS CATALYST | APROTIC-SOLVENT
Journal Article
Industrial & Engineering Chemistry Research, ISSN 0888-5885, 02/2016, Volume 55, Issue 5, pp. 1202 - 1214
Reaction kinetics of the gas-phase Beckmann rearrangement of cyclohexanone oxime to ε-caprolactam was studied over a NbO x /SiO2 catalyst in a fixed-bed... 
ALCOHOLS | ENGINEERING, CHEMICAL | NB-DIMER CATALYST | ACID | MECHANISM | ACETOPHENONE | ACTIVE-SITES | KETOXIMES | B-MFI ZEOLITES | OXIDE CATALYSTS | BETA ZEOLITES | Oximes | Partial pressure | Cyclohexanone | Adsorption | Catalysts | Ethanol | Reaction kinetics | Ethyl alcohol
Journal Article
Synlett, ISSN 0936-5214, 07/2018, Volume 29, Issue 11, pp. 1465 - 1468
Abstract We developed a Beckmann rearrangement employing hypervalent iodine reagent under mild conditions. The reaction of ketoxime with hypervalent iodine... 
letter | Lewis acid | hypervalent iodine reagent | amide | oxime | Beckmann rearrangement | DECARBOXYLATIVE HALOGENATION | REAGENTS | CHEMISTRY | CHEMISTRY, ORGANIC | INDOLECARBOXYLIC ACIDS | ARYL
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2004, Volume 126, Issue 20, pp. 6280 - 6286
Recent experiments have shown that supercritical water (SCW) has the ability to accelerate and make selective synthetic organic reactions, thus replacing the... 
OXIDATION | DENSITY | MOLECULAR-DYNAMICS | KINETICS | PROTON | NONCATALYTIC BECKMANN | FREE-ENERGY | CHEMISTRY, MULTIDISCIPLINARY | SCATTERING | Caprolactam | Molecular dynamics | Chemical reactions | Research | Hydrogen bonding | Rearrangements (Chemistry)
Journal Article
AIChE Journal, ISSN 0001-1541, 06/2019, Volume 65, Issue 6, pp. e16603 - n/a
ε‐Caprolactam (CPL) is mainly produced through Beckmann rearrangement of cyclohexanone oxime catalyzed by oleum in industry nowadays, which suffers the... 
mixed acids | trifluoroacetic acid | ε‐caprolactam | oleum | Beckmann rearrangement | ENGINEERING, CHEMICAL | EFFICIENT CATALYST | CAPROLACTAM | TRIFLUOROACETIC-ACID | HETEROGENEOUS CATALYST | epsilon-caprolactam | Analysis | Sulfuric acid | Viscosity | Parameters | Cyclohexanone | Acids | Trifluoroacetic acid | Caprolactam | Sulfur trioxide | Selectivity | Catalysis | Heat transfer
Journal Article
Green Chemistry, ISSN 1463-9262, 2018, Volume 20, Issue 14, pp. 3318 - 3326
Here we present the highly effective cleavage of C-C bonds in lignin model compounds for the production of N-substituted aromatics in up to 96% total yield,... 
C BOND-CLEAVAGE | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | ONE-POT CONVERSION | ALCOHOL OXIDATION | ACID | HYDROGENOLYSIS | DEHYDRATION | DEPOLYMERIZATION | COPPER | DIRECT ARYLATIONS | OXIDATIVE CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | Aromatics | Substitutes | Lignin | Transformation | Aromatic compounds | Extraction processes | Oxazole | Chemical bonds | Amides | Yield | Carboxylic acids | Substrates
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 11/2017, Volume 82, Issue 22, pp. 11848 - 11853
An umpolung approach to amides via hypervalent iodine-mediated oxidative rearrangement of N–H ketimines under mild reaction conditions is described. This... 
CATALYZED AMINOCARBONYLATION | ONE-POT SYNTHESIS | SYNTHETIC APPLICATIONS | CHEMISTRY, ORGANIC | 2+2+2 CASCADE ANNULATION | COUPLING REAGENTS | DIARYLIODONIUM SALTS | BOND FORMATION | QUINAZOLINE DERIVATIVES | CARBOXYLIC-ACIDS | BECKMANN REARRANGEMENT
Journal Article
Molecules (Basel, Switzerland), ISSN 1420-3049, 07/2018, Volume 23, Issue 7, p. 1764
Beckmann rearrangement of ketoxime catalyzed by acidic ionic liquid-N-methyl-imidazolium hydrosulfate was studied. Rearrangement of benzophenone oxime gave the... 
catalysis | acidic ionic liquid | Beckmann rearrangement | ketoxime | MILD | OXIMES | SOLVENTS | BIOCHEMISTRY & MOLECULAR BIOLOGY | CHEMISTRY, MULTIDISCIPLINARY | CYANURIC CHLORIDE | AMIDES | Oximes - chemistry | Ionic Liquids - chemistry | Imidazoles - chemistry | Ionic liquids | Phosphorus pentoxide | Catalysis | Catalysts | Benzophenone
Journal Article
Synlett, ISSN 0936-5214, 02/2015, Volume 26, Issue 3, pp. 331 - 334
Abstract A simple, iron-based catalytic system allows for facile Beckmann rearrangement of various oximes. The mild conditions avoid the use of harsh or... 
cluster | Lewis acid | iron | amides | oximes | Beckmann rearrangement | ALCOHOLS | lewis acid | KETOXIMES | CHEMISTRY, ORGANIC | ASYMMETRIC TOTAL-SYNTHESIS
Journal Article
JOURNAL OF CATALYSIS, ISSN 0021-9517, 02/2018, Volume 358, pp. 71 - 79
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 05/2018, Volume 360, Issue 10, pp. 2020 - 2031
Journal Article
Chemical Engineering & Technology, ISSN 0930-7516, 2012, Volume 35, Issue 7, pp. 1257 - 1261
The selectivity and conversion of the sulfuric acid-catalyzed Beckmann rearrangement of cyclohexanone oxime, dissolved in cyclooctane, to ¿-caprolactam are... 
Microreactor | Selectivity | Micromixer | ϵ‐Caprolactam | Beckmann rearrangement | ε{lunate}-Caprolactam | ENGINEERING, CHEMICAL | CHEMICAL-REACTIONS | epsilon-Caprolactam
Journal Article
Synlett, ISSN 0936-5214, 03/2014, Volume 25, Issue 5, pp. 665 - 670
Abstract A new and efficient approach for the Beckmann rearrangement is reported. The protocol involves eosin Y catalyzed, visible-light-mediated in situ... 
letter | amides | eosin Y | visible light | photoredox | Beckmann rearrangement | MILD | DYES | KETOXIMES | CHEMISTRY, ORGANIC | LACTAMS | THIOAMIDES | PHOTOREDOX CATALYSIS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2018, Volume 140, Issue 15, pp. 5264 - 5271
Catalytic activation of hydroxyl functionalities is of great interest for the production of pharmaceuticals and commodity chemicals. Here, 2-alkoxycarbonyl-... 
MILD | ALCOHOLS | CHEMISTRY, MULTIDISCIPLINARY | ACID CATALYSIS | Carbonyl compounds | Boric acid | Analysis | Chemical bonds | Mechanical properties | Chemical properties | Catalysis | Research
Journal Article
AIChE Journal, ISSN 0001-1541, 03/2012, Volume 58, Issue 3, pp. 925 - 931
A microstructured chemical system, constructed with a microsieve dispersion mixer, a delay loop and a microhydrolyzer is designed to carry out the Beckmann... 
selectivity | ϵ‐caprolactam | microstructured chemical system | Beckmann rearrangement | conversion | ε-caprolactam | Selectivity | Microstructured chemical system | Conversion
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 12/2016, Volume 57, Issue 50, pp. 5575 - 5580
[Display omitted] •Stereoselective synthesis of novel (Z)-2-organylselanyl ketoximes in good yields.•Beckmann rearrangement of (Z)-2-organylselanyl ketoximes... 
(Z)-2-Organylselanyl ketoxime | Anthracnose | Organochalcogen | Antioxidant activity | Beckmann rearrangement | ASSAY | CHEMISTRY, ORGANIC | MICROWAVE IRRADIATION | SOLVENT | OXIMES | ACETOPHENONE | BIOLOGICAL EVALUATION | BROMIDE | Antioxidants | Health aspects
Journal Article
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