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1967, Organic chemistry, Volume 11., xi, 386
Book
Chemical science, ISSN 2041-6520, 2015, Volume 6, Issue 9, pp. 5128 - 5132
One of the most challenging goals of modern synthetic chemistry is to develop multi-step reactions for rapid and efficient access to complex molecules. We... 
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 03/2012, Volume 14, Issue 6, pp. 1363 - 1365
A new protocol for the efficient synthesis of o-diiodoarenes has been developed. This method allows the synthesis of substituted and polycyclic o-diiodoarenes,... 
CHEMISTRY | CHEMISTRY, ORGANIC | IODINATION | BENZYNE
Journal Article
The Journal of Physical Chemistry A, ISSN 1089-5639, 04/2018, Volume 122, Issue 14, pp. 3688 - 3696
The 9,10-didehydroanthracene is an aromatic diradical produced by the Bergman cyclization of a benzannulated 10-membered enediyne. It is a 1,4 diradical,... 
ANTITUMOR ANTIBIOTICS | P-BENZYNE | NEOCARZINOSTATIN CHROMOPHORE | ORTHO-BENZYNE | AB-INITIO | EQUILIBRIUM GEOMETRIES | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | META-BENZYNE | COUPLED-CLUSTER | HYDROGEN ABSTRACTION REACTIONS | BERGMAN CYCLIZATION | Chemistry | Physics
Journal Article
Nature, ISSN 0028-0836, 10/2012, Volume 490, Issue 7419, pp. 179 - 180
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 09/2013, Volume 52, Issue 40, pp. 10589 - 10592
Journal Article
Tetrahedron, ISSN 0040-4020, 08/2019, Volume 75, Issue 33, pp. 4663 - 4668
Journal Article
Tetrahedron, ISSN 0040-4020, 02/2018, Volume 74, Issue 5, pp. 544 - 548
Recent reports describe the different products resulting from the reaction of C with benzyne generated from anthranilic acid derivatives and isoamyl nitrate in... 
C60-fused δ lactone | Benzyne-C60 addition | [5,6] fulleroid | Benzyne-C | C | fused δ lactone | addition
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 03/2017, Volume 46, Issue 6, pp. 1707 - 1719
One of the most distinct characters of aryne chemistry over other synthetic methodologies is its ability to simultaneously functionalize the vicinal two... 
POLYHALOBENZENES | PRECURSOR | MOLECULAR-STRUCTURE | ONE-POT | PRODUCT | CYCLOADDITIONS | DIAMINATION | AROMATIC-HYDROCARBON | GENERATION | CHEMISTRY, MULTIDISCIPLINARY | BENZYNE
Journal Article
Chemical Science, ISSN 2041-6520, 06/2015, Volume 6, Issue 9, pp. 5128 - 5132
One of the most challenging goals of modern synthetic chemistry is to develop multi-step reactions for rapid and efficient access to complex molecules. We... 
CHEMISTRY, MULTIDISCIPLINARY | BENZYNE | Catalysts | Couples
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 09/2016, Volume 49, Issue 9, pp. 1658 - 1670
Arynes are highly reactive intermediates having several applications in organic synthesis for the construction of various ortho-disubstituted arenes.... 
O-ARYLATION | CYCLOADDITION | FACILE N-ARYLATION | HETEROCYCLES | AMINES | ACIDS | ONE-POT | 1,2-BENZOQUINONES | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | BENZYNE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2017, Volume 139, Issue 25, pp. 8400 - 8403
We demonstrate that the hexadehydro-Diels–Alder (HDDA) cycloisomerization reaction to produce reactive benzyne derivatives can be initiated photochemically. As... 
HDDA-DERIVED BENZYNES | INSERTION | O-BENZYNES | STEPWISE MECHANISMS | GENERATED BENZYNES | INTERMEDIATE | BOND | CHEMISTRY, MULTIDISCIPLINARY | TETRAYNES | CYCLOAROMATIZATION | REGIOSELECTIVITIES | Molecular Structure | Benzene Derivatives - chemistry | Cycloaddition Reaction | Isomerism | Light
Journal Article
JOURNAL OF CHEMICAL THEORY AND COMPUTATION, ISSN 1549-9618, 05/2015, Volume 11, Issue 5, pp. 2097 - 2108
We introduce a multireference version of the driven similarity renormalization group (DSRG) approach [Evangelista, F. A. J. Chem. Phys. 2014, 141, 054109]... 
SCF METHOD | DENSITY-MATRIX | P-BENZYNE | SELF-CONSISTENT-FIELD | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | IMPLEMENTATION | DECOMPOSITION | CHEMISTRY | CHEMISTRY, PHYSICAL | FORMULATION | BENZYNE THERMOCHEMISTRY | COUPLED-CLUSTER THEORY
Journal Article
Organic Letters, ISSN 1523-7060, 04/2013, Volume 15, Issue 8, pp. 1938 - 1941
Efficient Alder-ene reactions of various arynes generated directly from bis-1,3-diynes are described. The reactivity of ene donors with different tethers was... 
SYSTEM | ORGANIC-SYNTHESIS | CHEMISTRY, ORGANIC | OLEFINS | BENZYNE | CYCLIZATION | CYCLOAROMATIZATION
Journal Article
Organic Letters, ISSN 1523-7060, 02/2017, Volume 19, Issue 3, pp. 666 - 669
The reaction of in situ generated arynes with aryl vinyl sulfoxides provides ortho-arylsulfinylaryl vinyl ethers via aryne σ-bond insertion into the S–O-bond... 
INSERTION | ARYLATION | CHEMISTRY | CHEMISTRY, ORGANIC | BOND | UTILITY | BENZYNE | YLIDE
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 10/2018, Volume 83, Issue 20, pp. 12390 - 12396
Experiments have demonstrated that nucleophiles can attack singlet diradicals to generate bonded, closed-shell addition products. Here, we present a molecular... 
TRIPLET SPLITTINGS | P-BENZYNE | BIRADICAL THERMOCHEMISTRY | ELECTRON-TRANSFER | GAS-PHASE | CHEMISTRY, ORGANIC | META-BENZYNE | SRN1 MECHANISM | THRESHOLD ENERGY MEASUREMENTS | AROMATIC-SUBSTITUTION | THERMAL GENERATION
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 11/2019, Volume 21, Issue 22, pp. 9019 - 9023
A synthetic method for diverse gamma-aryl-beta-ketoesters through gamma-aryl-beta-ketoester-type arynes triggered by C-C bond cleavage has been developed. The... 
CHEMISTRY, ORGANIC | SULFOXIMINES | DIRECT THIOAMINATION | BENZDIYNE | BENZYNE
Journal Article
Journal of the Iranian Chemical Society, ISSN 1735-207X, 9/2019, Volume 16, Issue 9, pp. 1965 - 1976
(Z)-enediynes equipped with aliphatic n-membered ring undergo a thermal rearrangement known as the Bergman cyclization. The rearrangement of these molecules... 
Biochemistry, general | Chemistry | Analytical Chemistry | DFT | Physical Chemistry | Reaction kinetic | Bergman cyclization | para -Benzyne | Enediynes | Inorganic Chemistry | Ring size effect | Organic Chemistry | MECHANISM | para-Benzyne | DECOMPOSITION | CHEMISTRY, MULTIDISCIPLINARY | BENZYNE
Journal Article
The Journal of Physical Chemistry A, ISSN 1089-5639, 12/2013, Volume 117, Issue 50, pp. 13605 - 13615
Three open-chain isomers of C6H4 + and two cyclic ones were detected following mass-selective trapping in 6 K neon matrixes. The open-chain cations... 
O-BENZYNE | P-BENZYNE | STATES | COUPLED-CLUSTER METHOD | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | RADICAL CATIONS | GAS | CHEMISTRY, PHYSICAL | ABSORPTION-SPECTRA | DERIVATIVES | BENZYNE NEGATIVE-IONS | PHOTOELECTRON-SPECTROSCOPY
Journal Article
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