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INORGANIC CHEMISTRY, ISSN 0020-1669, 07/2019, Volume 58, Issue 14, pp. 9225 - 9235
A suite of lanthanoenediyne complexes of the form Ln(macrocycle)X-3 (Ln = La3+, Ce3+, Gd3+, Tb3+, Lu3+; X = NO3-, Cl-, OTf-) was prepared by utilizing an... 
ASYMMETRIC CATALYSIS | CHEMICAL-SHIFTS | ELECTRONIC CONTRIBUTIONS | REACTIVITY | STERIC CONTROL | LANTHANIDE(III) COMPLEXES | LIGAND | RECYCLABLE CATALYSTS | METAL-COMPLEXES | BERGMAN CYCLIZATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2009, Volume 131, Issue 43, pp. 15695 - 15704
A competitive scenario between Myers−Saito (MS) and Garratt−Braverman (GB) cyclization has been created in a molecule. High-level computations indicate a... 
SINGLET-TRIPLET SPLITTINGS | P-BENZYNES | DNA CLEAVAGE | SPIN-DENSITY | AB-INITIO | ENEDIYNES | ENYNE-ALLENES | CHEMISTRY, MULTIDISCIPLINARY | BRIDGED PROPARGYLIC SYSTEMS | BERGMAN CYCLIZATION | BIRADICAL FORMATION | Models, Theoretical | Kinetics | Cyclization | Sulfones - chemistry | Chemical properties | Ring formation (Chemistry) | Structure | Benzene | Analysis | DNA
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2016, Volume 138, Issue 34, pp. 10963 - 10967
We investigate the thermally induced cyclization of 1,2-bis­(2-phenylethynyl)­benzene on Au(111) using scanning tunneling microscopy and computer simulations.... 
THERMOLYSIS | POLYPHENYLENE | SURFACE | CHEMISTRY | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | BENZYNE | BERGMAN CYCLIZATION | Molecular simulation | Density functionals | Gold | Usage | Chemical properties | Ring formation (Chemistry) | INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 02/2016, Volume 2016, Issue 4, pp. 739 - 747
The synthesis of enediynes fused to an isocoumarin core was achieved through the electrophilic cyclization of o‐(buta‐1,3‐diynyl)benzoates as a key step,... 
Enediynes | Cyclization | Oxygen heterocycles | Cross‐coupling | Alkynes | Cross-coupling | HALOCYCLIZATION | HETEROCYCLES | ALPHA-PYRONES | CHEMISTRY, ORGANIC | Crosscoupling | DERIVATIVES | BERGMAN CYCLIZATION | Forest reserves
Journal Article
The Journal of Physical Chemistry B, ISSN 1520-6106, 02/2016, Volume 120, Issue 5, pp. 945 - 950
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 08/2018, Volume 59, Issue 32, pp. 3033 - 3051
Journal Article
ACS Nano, ISSN 1936-0851, 2019, Volume 13, Issue 2, pp. 2379 - 2388
We present an atomic level study of reversible cyclization processes in suspended nanoconstricted regions of graphene that form linear carbon chains (LCCs).... 
carbon chains, Bergman rearrangement | aberration-corrected TEM | graphene constrictions | CARBON | Bergman rearrangement | STABILITY | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY | CHEMISTRY, MULTIDISCIPLINARY | carbon chains | ODD
Journal Article
Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 12/2011, Volume 49, Issue 24, pp. 5330 - 5338
Journal Article
Organic Letters, ISSN 1523-7060, 03/2012, Volume 14, Issue 5, pp. 1334 - 1337
The Schmittel cyclization was achieved at room temperature through triazole–gold (TA–Au) catalyzed propargyl vinyl ether rearrangement. Other tested [L–Au]+... 
MYERS-SAITO | COMPLEXES | ESTERS | MODE | REACTIVITY | CHEMISTRY | CHEMISTRY, ORGANIC | ENEDIYNE | GENERATION | ENYNE-ALLENES | BERGMAN CYCLIZATION | Gold - chemistry | Models, Molecular | Molecular Structure | Catalysis | Cyclization | Triazoles - chemistry
Journal Article
Tetrahedron, ISSN 0040-4020, 11/2018, Volume 74, Issue 44, pp. 6419 - 6425
Enediyne cytotoxic drugs have attracted much attention because of their unique structure and potent anticancer activity. However, acyclic enediynes are long... 
Bergman cyclization | Cytotoxicity | DNA cleavage | Anticancer agents | Enediyne | DRUG | ANTITUMOR ANTIBIOTICS | DNA-DAMAGE | CHEMISTRY, ORGANIC | C-1027 | POLYMERIC MICELLES | CANCER | CYCLIC CONJUGATED ENEDIYNES | CISPLATIN | METALLOENEDIYNES | AGENTS | Antimitotic agents | Care and treatment | Antineoplastic agents | Analysis | Cancer
Journal Article
Journal of the Iranian Chemical Society, ISSN 1735-207X, 9/2019, Volume 16, Issue 9, pp. 1965 - 1976
(Z)-enediynes equipped with aliphatic n-membered ring undergo a thermal rearrangement known as the Bergman cyclization. The rearrangement of these molecules... 
Biochemistry, general | Chemistry | Analytical Chemistry | DFT | Physical Chemistry | Reaction kinetic | Bergman cyclization | para -Benzyne | Enediynes | Inorganic Chemistry | Ring size effect | Organic Chemistry | MECHANISM | para-Benzyne | DECOMPOSITION | CHEMISTRY, MULTIDISCIPLINARY | BENZYNE
Journal Article
Advances in Polymer Science, ISSN 0065-3195, 2017, Volume 278, pp. 147 - 171
Journal Article
Macromolecular Rapid Communications, ISSN 1022-1336, 11/2011, Volume 32, Issue 21, pp. 1688 - 1698
Journal Article
Polymer, ISSN 0032-3861, 06/2017, Volume 119, pp. 245 - 252
A series of AB2 type monomers with terminal alkyne (A) and iodine (B) were synthesized from dichloromaleic anhydride by amidation with terminal alkynylamine... 
Bergman cyclization | Sonogashira cross coupling polymerization | Enediyne | Persistent radicals | Hyperbranched polymers | POLYMERS | DESIGN | POLYPHENYLENES | POLYMER SCIENCE | DRUG-DELIVERY | THIOL-YNE CHEMISTRY | CLICK POLYMERIZATION | BIRADICALS | Polymerization | Nuclear magnetic resonance spectroscopy | Polymers | Free radicals (Chemistry)
Journal Article
Polymer, ISSN 0032-3861, 06/2017, Volume 118, pp. 249 - 255
Three different monomers have been used to prepare novel Bergman cyclization-based porous organic polymers (BCPOPs). The synthesis route to BCPOPs is facile... 
Bergman cyclization | Gas storage | Porous organic polymers | Gas selectivity | POLYMER SCIENCE | SURFACE-AREA | HYDROGEN ADSORPTION | NETWORKS | CO2 CAPTURE | FRAMEWORKS | METHANE | CARBON-DIOXIDE CAPTURE | NITROGEN | SEPARATION | LOW-PRESSURE | Polymers | Polymer industry | Porosity | Carbon dioxide
Journal Article
Organic Letters, ISSN 1523-7060, 07/2004, Volume 6, Issue 14, pp. 2457 - 2460
Bu3Sn-mediated 5-exo-dig radical cyclization of diaryl enediynes provides a mild and efficient approach to tin-substituted fulvenes. Further synthetic... 
ROUTES | RING | COMPLEXES | REACTIVITY | CHEMISTRY, ORGANIC | INTERMEDIATE | POLYMERIZATION | METALLOCENES | BERGMAN CYCLIZATION | POLYNAPHTHALENES
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2011, Volume 17, Issue 52, pp. 14907 - 14915
The intramolecular electrophilic or thermal cyclization of arylene ethynylene precursors recently became a powerful method for the synthesis of new polycyclic... 
fluoranthenes | domino reactions | hydrocarbons | cyclization | polycycles | ACENES | ALUMINUM-CHLORIDE | PARALLEL TRIPLE BONDS | NEAR-INFRARED DYES | CHEMISTRY, MULTIDISCIPLINARY | BERGMAN CYCLIZATION | DIELS-ALDER REACTION | ORGANIC ELECTRONICS | FUSED POLYCYCLIC AROMATICS | DERIVATIVES | Polycyclic aromatic hydrocarbons | Oligomers | Naphthalene | Synthesis | Precursors | Amphoterics | Derivatives | Radicals
Journal Article