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beta-heteroatom elimination (35) 35
chemistry, organic (21) 21
chemistry, multidisciplinary (15) 15
palladium (14) 14
cyclization (10) 10
catalysis (8) 8
complexes (8) 8
-4'-acetoxy-2'-butenyl 2-alkynoates (7) 7
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divalent palladium (3) 3
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molecular structure (3) 3
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stereoselective synthesis (3) 3
acids (2) 2
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alkylidene-gamma-butyrolactams (2) 2
analysis (2) 2
aryl bromides (2) 2
aryl iodides (2) 2
arylation (2) 2
bond activation (2) 2
bond formation (2) 2
bonds (2) 2
c-bond formation (2) 2
c-h activation (2) 2
catalyzed cyclization (2) 2
chemistry, inorganic & nuclear (2) 2
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functionalization (2) 2
furans - chemical synthesis (2) 2
furans - chemistry (2) 2
gamma-butyrolactones (2) 2
gold (2) 2
heck reaction (2) 2
heck-type reactions (2) 2
heteroatom elimination (2) 2
hydride elimination (2) 2
insertion (2) 2
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synthesis (2) 2
tandem intramolecular aminopalladation (2) 2
vinyl-acetate (2) 2
water (2) 2
β-hydride elimination (2) 2
1,2-allenyl ketones (1) 1
1,3-butadienes (1) 1
1,6-enyne (1) 1
1,6-enynes (1) 1
2,3 wittig rearrangement (1) 1
2,3-allenols (1) 1
2,5-dihydrofuran derivatives (1) 1
4-butenolide derivatives (1) 1
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Journal of the American Chemical Society, ISSN 0002-7863, 11/2016, Volume 138, Issue 43, pp. 14441 - 14448
We report a highly robust, general and stereoselective method for the synthesis of 3-(chloromethylene)oxindoles from alkyne-tethered carbamoyl chlorides using... 
CIS-CHLOROPALLADATION | MECHANISTIC INSIGHTS | CATALYZED CYCLIZATION REACTION | BETA-HETEROATOM ELIMINATION | STEREOSPECIFIC SYNTHESIS | PALLADIUM CATALYSIS | NUCLEOPHILIC-ADDITION | OXIDATIVE ADDITION | HALOGEN BOND FORMATION | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | Carbachol | Palladium | Chemical properties
Journal Article
Organic Letters, ISSN 1523-7060, 07/2013, Volume 15, Issue 14, pp. 3670 - 3673
Rh(III)-catalyzed direct olefination of arenes with allyl acetate via C-H bond activation is described using N,N-disubstituted aminocarbonyl as the directing... 
DIRECT ARYLATION | (Z)-4'-ACETOXY-2'-BUTENYL 2-ALKYNOATES | CROSS-COUPLING REACTION | PYRIDINE-N-OXIDES | AROMATIC KETONES | BETA-HETEROATOM ELIMINATION | CHEMISTRY, ORGANIC | BOND FORMATION | ARYL | REGIOSELECTIVE ARYLATION | ALKENYLATION
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2004, Volume 45, Issue 8, pp. 1785 - 1788
Journal Article
by Han, XL and Liu, GX and Lu, XY
CHINESE JOURNAL OF ORGANIC CHEMISTRY, ISSN 0253-2786, 10/2005, Volume 25, Issue 10, pp. 1182 - 1197
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2015, Volume 137, Issue 44, pp. 14208 - 14219
In the absence of H-2, reaction of [Rh(H) (CO)(2)(BDP)] [BDP = bis(diazaphospholane)] with hydroformylation substrates vinyl acetate, allyl cyanide, 1-octene,... 
ENOL ESTERS | PHOSPHINE | ASYMMETRIC HYDROFORMYLATION | LIGANDS | HYDRIDE ELIMINATION | COMPLEXES | BETA-HETEROATOM ELIMINATION | HIGHLY ENANTIOSELECTIVE HYDROFORMYLATION | REGIOSELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | C-H
Journal Article
by Shao, AL and Gao, M and Chen, ST and Wang, T and Lei, AW
CHEMICAL SCIENCE, ISSN 2041-6520, 03/2017, Volume 8, Issue 3, pp. 2175 - 2178
Selective carbon-carbon and carbon-heteroatom bond cleavage was achieved in a one reaction system. With this strategy a novel Pd/Cu-catalyzed aerobic oxidative... 
C-S BOND | PALLADIUM | ACTIVATION | AEROBIC OXYGENATION | MONONUCLEAR COPPER | ARYL HALIDES | COMPLEXES | CHEMISTRY | ELIMINATION | BETA-HETEROATOM | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2003, Volume 687, Issue 2, pp. 562 - 566
The palladium-catalyzed reaction of aryl iodides with tertiary propargylic amides affords highly substituted allenes. Best results have been obtained by using... 
Hydroarylation | Allenes | Palladium | Alkynes | ROUTE | ANNULATION | alkynes | BETA-HETEROATOM ELIMINATION | CHEMISTRY, ORGANIC | TANDEM CYCLIZATION | INTERNAL ALKYNES | ANION CAPTURE PROCESSES | CHEMISTRY, INORGANIC & NUCLEAR | allenes | DISUBSTITUTED ACETYLENES | ALLYLIC ALCOHOLS | palladium | hydroarylation | REDUCTIVE ADDITION
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 03/2016, Volume 81, Issue 6, pp. 2243 - 2251
The rhodium(III)-catalyzed mild and site selective C-H allylation of enol carbamates with 4-vinyl-1,3-dioxolan-2-one and allylic carbonates affords allylic... 
FUNCTIONALIZATION | ALKENES | ARENES | BETA-HETEROATOM ELIMINATION | ACETATES | CHEMISTRY, ORGANIC | BOND ACTIVATION | C-H ACTIVATION | EFFICIENT | DERIVATIVES | 1,3-BUTADIENES | Allylic compounds | Chemical properties | Rhodium | Chemical synthesis | Analysis
Journal Article
Organometallics, ISSN 0276-7333, 01/2014, Volume 33, Issue 1, pp. 402 - 420
A direct, regioselective alkenylation of aromatic C-H bonds of aryl- and heteroarylpyridines and related compounds with alkenyl esters was developed using... 
ORGANIC-SYNTHESIS | OXIDIZING DIRECTING GROUP | TRANSITION-METAL-COMPLEXES | CONJUGATED POLYMERS | VINYL-ACETATE | BETA-HETEROATOM ELIMINATION | DIRECT ORTHO ARYLATION | CHEMISTRY, ORGANIC | CARBON-CARBON BONDS | OXIDATIVE COUPLING REACTION | HYDROGEN BOND-CLEAVAGE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Tetrahedron, ISSN 0040-4020, 2009, Volume 65, Issue 44, pp. 8987 - 8994
Asymmetric hydrogenation of a vinyl fluoride derivative gives efficient access to enantioenriched 1,3,4-trisubstituted piperidine with a stereogenic alkyl... 
X-ELIMINATION | DIPHOSPHINE LIGANDS | RHODIUM | MECHANISM | COMPLEXES | BETA-HETEROATOM ELIMINATION | CHEMISTRY, ORGANIC | OLEFINS | BOND ACTIVATION | C-F ACTIVATION | IRIDIUM CATALYSTS | Enantiomers | Hydrogenation | Nitrites | Isomerization
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 02/2012, Volume 77, Issue 4, pp. 2029 - 2034
Palladium-catalyzed regio- and stereoselective intermolecular tandem reaction of electron-deficient alkynes, CuBr2, and allylic alcohol to synthesize... 
(Z)-4'-ACETOXY-2'-BUTENYL 2-ALKYNOATES | PALLADIUM(II)-CATALYZED CYCLIZATION | ALLYL ALCOHOLS | RECONSTITUTIVE CONDENSATION | AQUEOUS-MEDIA | BETA-HETEROATOM ELIMINATION | CHEMISTRY, ORGANIC | BOND FORMATION | PROPARGYL ALCOHOLS | ALKYNES | MOLECULAR-OXYGEN
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 05/2008, Volume 14, Issue 14, pp. 4263 - 4266
Transition-metal-catalyzed dimeric coupling-cyclization reactions of two different 2,3-allenols afforded 4-(1',3'-dien-2'-yl)-2,5-dihydrofuran derivatives 3.... 
Allenes | Palladium | Cyclization | Elimination | Alcohols | C-BOND FORMATION | ACIDS | BETA-HETEROATOM ELIMINATION | DIMERIZATION | alcohols | STEREOSELECTIVE SYNTHESES | cyclization | CHEMISTRY, MULTIDISCIPLINARY | allenes | 1,2-ALLENYL KETONES | PALLADIUM-CATALYZED REACTIONS | ALLYL ALCOHOLS | palladium | elimination | ALLENYL KETONES | 4-(3'-FURANYL)BUTENOLIDE DERIVATIVES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2015, Volume 54, Issue 13, pp. 4119 - 4123
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 11/2013, Volume 11, Issue 42, pp. 7427 - 7434
Journal Article
by Shen, K and Han, XL and Lu, XY and Hu, ZY
TETRAHEDRON LETTERS, ISSN 0040-4039, 09/2017, Volume 58, Issue 39, pp. 3768 - 3771
A cationic Pd(II)-catalyzed redox neutral arylative cyclization of enynes by using beta-acetoxy elimination as the quenching step has been developed. The... 
CATALYZED CYCLOISOMERIZATION | METAL-CATALYSTS | COMPLEXES | CHEMISTRY, ORGANIC | ALKYNES | GAMMA-BUTYROLACTONES | Carbopalladation | 1,6-Enyne | Cationic palladium | (Z)-4'-ACETOXY-2'-BUTENYL 2-ALKYNOATES | PALLADIUM(II)-CATALYZED CYCLIZATION | beta-Heteroatom elimination | Arylboronic acid | COUPLING REACTION | SYNTHETIC APPLICATIONS | ENONES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2005, Volume 127, Issue 14, pp. 5132 - 5146
Vinyl acetate (VA) and vinyl trifluoroacetate (VA(f)) react with [(N boolean AND N)Pd(Me)(Q][X] (M = Pd, Ni, (N boolean AND N) =... 
POLAR MONOMERS | OLEFIN POLYMERIZATION CATALYSTS | ALPHA-OLEFINS | MIGRATORY INSERTION | PALLADIUM COMPLEXES | LATE-METAL-CATALYSTS | KINETICS | BETA-HETEROATOM ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | CARBON-MONOXIDE INSERTION | HYDRIDE BONDS
Journal Article
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