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by Wang, XS and Mei, TS and Yu, JQ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 06/2009, Volume 131, Issue 22, pp. 7520 - 7520
Pd(OTf)(2)center dot 2H(2)O-catalyzed ortho-fluorination of triflamide-protected benzylamines is reported. The use of N-fluoro-2,4,6-trimethylpyridinium... 
PALLADIUM FLUORIDE | BETA-KETOESTERS | ENANTIOSELECTIVE FLUORINATION | COMPLEXES | BONDS | REACTIVITY | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 03/2019, Volume 141, Issue 10, pp. 4199 - 4203
An efficient and highly enantioselective Conia-ene-type process has been developed. Reactions are catalyzed by a combination of B(C6F5)(3), an N-alkylamine and... 
ACTIVATION | BETA-KETOESTERS | DIRECT MANNICH | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2016, Volume 138, Issue 27, pp. 8360 - 8363
The first copper-catalyzed asymmetric decarboxylative [4 + 1] cycloaddition of propargylic carbamates and sulfur ylides was successfully developed. This... 
ALCOHOLS | CASCADE REACTIONS | BETA-KETOESTERS | ENANTIOSELECTIVE SYNTHESIS | ALKYLATION | PROPARGYLIC SUBSTITUTION-REACTIONS | ESTERS | CYCLOPROPANATION | CHEMISTRY, MULTIDISCIPLINARY | 3+2 CYCLOADDITION | INDOLES
Journal Article
Organic Letters, ISSN 1523-7060, 03/2016, Volume 18, Issue 5, pp. 1190 - 1193
The first copper-catalyzed asymmetric formal [4 + 2] cycloaddition of o-aminophenol derivatives with propargylic esters as the bis-electrophilic C2 synthons... 
AMINATION | BETA-KETOESTERS | ACID | AMINES | ALKYLATION | COMPLEXES | ACETATES | CHEMISTRY, ORGANIC | ASYMMETRIC HYDROGENATION | 3-SUBSTITUTED 2H-1,4-BENZOXAZINES | SUBSTITUTION-REACTIONS
Journal Article
Organic Letters, ISSN 1523-7060, 03/2017, Volume 19, Issue 5, pp. 1036 - 1039
A novel bifunctional squaramide-catalyzed one-pot electrophilic trifluoromethylthiolation–sulfur–Michael/aldol cascade reaction for the construction of... 
DOMINO REACTIONS | BETA-KETOESTERS | HYPERVALENT IODINE REAGENT | CHEMISTRY, ORGANIC | ALDOL REACTIONS | ASYMMETRIC ORGANOCATALYSIS | STRATEGIES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2015, Volume 137, Issue 2, pp. 964 - 973
The addition of a variety of radicals to the double bond of N-(arylsulfonyl)­acrylamides can trigger cyclization/​aryl migration/​desulfonylation cascades via... 
MIGRATION | SP C-H | ACTIVATED ALKENES | BETA-KETOESTERS | C(SP3)H BOND | 1,3-DICARBONYL COMPOUNDS | COUPLING REACTION | CATALYZED TRIFLUOROMETHYLATION | BOND FORMATION | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE | Amides | Chemical synthesis | Carbon compounds | Analysis | Electric properties
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2010, Volume 132, Issue 44, pp. 15534 - 15536
Herein we report palladium-catalyzed asymmetric benzylic alkylation with 3-aryl oxindoles as prochiral nucleophiles. Proceeding analogously to asymmetric... 
BETA-KETOESTERS | (-)-PHYSOSTIGMINE | NUCLEOPHILIC-SUBSTITUTION | 1-NAPHTHYLETHYL ESTERS | ALLYLATION | ALLYLIC ALKYLATIONS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2013, Volume 49, Issue 81, pp. 9263 - 9265
The air and moisture stable fluoroiodane 8, readily prepared on a 6 g scale by nucleophilic fluorination of the hydroxyiodane 7 with TREAT-HF, has been used as... 
BETA-KETOESTERS | BIS(TETRAFLUOROBORATE) | SELECTIVE FLUORINATION | AGENTS | SELECTFLUOR | SALTS | CHEMISTRY, MULTIDISCIPLINARY | TRIFLUOROMETHYLATION | FAMILY | Fluorides
Journal Article
Organic Process Research & Development, ISSN 1083-6160, 03/2008, Volume 12, Issue 2, pp. 305 - 321
Methods for introducing fluorine into organic molecules are reviewed, with an emphasis on preparation of compounds designed for biomedicinal applications.... 
ORGANIC-SYNTHESIS | CATALYTIC ENANTIOSELECTIVE FLUORINATION | BETA-KETOESTERS | ORGANOCATALYTIC ALPHA-FLUORINATION | ELECTROPHILIC FLUORINATION | SOLID-PHASE SYNTHESIS | ELEMENTAL FLUORINE | FLUOROPYRIDINIUM SALT SYSTEM | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | CHEMISTRY, APPLIED | ACETYL HYPOFLUORITE
Journal Article
Organic Letters, ISSN 1523-7060, 06/2018, Volume 20, Issue 12, pp. 3710 - 3713
A copper-catalyzed asymmetric formal [4 + 2]-cycloaddition of copper–allenylidenes and hexahydro-1,3,5-triazines has been developed, providing chiral... 
DONOR-ACCEPTOR CYCLOPROPANES | PROPARGYLIC ESTERS | BETA-KETOESTERS | ANNULATION | ENANTIOSELECTIVE PROPARGYLATION | IMINES | COMPLEXES | CHEMISTRY, ORGANIC | 1,3,5-TRIAZINANES | 3+2 CYCLOADDITION | DEAROMATIZATION
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 10/2018, Volume 54, Issue 85, pp. 12033 - 12036
A copper-catalyzed asymmetric propargylic [3+3] cycloaddition with 1H-pyrazol-5(4H)-ones as C,O-bisnucleophiles through the desilylation-activated strategy has... 
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 85, pp. 12033 - 12036
A copper-catalyzed asymmetric propargylic [3+3] cycloaddition with 1H-pyrazol-5(4H)-ones as C,O-bisnucleophiles through the desilylation-activated strategy has... 
AMINATION | BETA-KETOESTERS | AMINES | SYNERGISTIC CATALYSIS | ALKYLATION | ESTERS | ACETATES | SUBSTITUTION-REACTIONS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | INDOLES
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 10/2011, Volume 40, Issue 10, pp. 4912 - 4924
The formation of oxygen-carbon bonds is one of the fundamental transformations in organic synthesis. In this regard the application of palladium-based... 
BETA-KETOESTERS | ALPHA-HYDROXYLATION | COUPLING REACTIONS | C-O BOND | ARYL HALIDES | ASYMMETRIC DIHYDROXYLATION | BUTYL ETHERS | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | DIRECT OXIDATION | MOLECULAR-OXYGEN | Benzene - chemistry | Alcohols - chemistry | Alkenes - chemistry | Catalysis | Hydroxylation | Palladium - chemistry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2015, Volume 137, Issue 7, pp. 2472 - 2475
Enantioselective propargylic etherification of propargylic esters with not only aliphatic alcohols but also phenols in the presence of a catalytic amount of... 
CYCLOADDITION | AMINATION | BETA-KETOESTERS | AMINES | CLICK CHEMISTRY | ALKYLATION | COMPLEXES | ACETATES | ENAMINES | SUBSTITUTION-REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | Metal catalysts | Esters | Chemical properties | Research | Chemical synthesis | Enantiomers | Alcohols
Journal Article
Organic Letters, ISSN 1523-7060, 09/2018, Volume 20, Issue 17, pp. 5278 - 5281
The copper-catalyzed asymmetric [3 + 3] annulation of ethynyl benzoxazinanones with pyrazolones has been achieved, providing simple access to... 
CYCLOADDITION | BETA-KETOESTERS | ENANTIOSELECTIVE SYNTHESIS | ESTERS | COMPLEXES | ACETATES | CHEMISTRY, ORGANIC | CATALYZED PROPARGYLIC SUBSTITUTION | INDOLES | PHENOL DERIVATIVES | DEAROMATIZATION
Journal Article
by Li, CQ and Long, PL and Wu, HP and Yin, HQ and Chen, FX
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 08/2019, Volume 17, Issue 30, pp. 7131 - 7134
A novel electrophilic thiocyanating reagent, N-thiocyanato-dibenzenesulfonimide, was prepared and exhibited enhanced electrophilicity with a wide scope of... 
BETA-KETOESTERS | ACID | TRIFLUOROMETHYLTHIOCYANATION | HYPERVALENT IODINE REAGENT | ALPHA-THIOCYANATION | CHEMISTRY, ORGANIC | CYANATION | ACCESS
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 08/2018, Volume 54, Issue 64, pp. 8881 - 8884
The highly C-selective difluoromethylation of -ketoesters was achieved by combining TMSCF2Br/LiOH/N,N,N-trimethylhexadecan-1-ammonium bromide. Compared to... 
BETA-KETOESTERS | ALKYLATION | O-DIFLUOROMETHYLATION | DIAZO-COMPOUNDS | SOFT ACIDS | INHIBITORS | FLUOROALKYLATION REACTIONS | DIFLUOROCARBENE REAGENT | EFFICIENT DIFLUOROMETHYLATION | CHEMISTRY, MULTIDISCIPLINARY | 1,3-DIONES
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 04/2006, Volume 128, Issue 16, pp. 5475 - 5479
The development of the organocatalytic asymmetric one-pot Michael-Darzens condensation giving highly functionalized complex epoxycyclohexanone derivatives with... 
REARRANGEMENT | MULTICOMPONENT REACTIONS | KETONES | BETA-KETOESTERS | ROBINSON ANNULATION | DARZENS REACTION | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 02/2016, Volume 18, Issue 3, pp. 576 - 579
The first catalytic α-fluoroallenoate synthesis is described. With a suitable combination of N-heterocyclic carbene precatalyst, base, and fluorine reagent,... 
ASYMMETRIC FLUORINATION | BETA-KETOESTERS | ENANTIOSELECTIVE FLUORINATION | EFFICIENT SYNTHESIS | ORGANOCATALYSIS | CHEMISTRY, ORGANIC | GENERATION | ALDEHYDES | ALLENES | UMPOLUNG | TRIFLUOROMETHYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 04/2018, Volume 20, Issue 7, pp. 1760 - 1763
A decarboxylative formal [4 + 2] cycloaddition reaction between ethynyl benzoxazinanones and 5-substituted 2-silyloxyfurans catalyzed by chiral Cu–Pybox... 
BETA-KETOESTERS | ENANTIOSELECTIVE SYNTHESIS | BUTENOLIDES | MUKAIYAMA 1,6-MICHAEL/MICHAEL ADDITION | ALDOL REACTION | PROPARGYLIC SUBSTITUTION-REACTIONS | ESTERS | CONSTRUCTION | CHEMISTRY, ORGANIC | VINYLOGOUS MANNICH REACTIONS | INDOLES
Journal Article
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