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Journal of the American Chemical Society, ISSN 0002-7863, 10/2017, Volume 139, Issue 42, pp. 14893 - 14896
The first and asymmetric total synthesis of longeracinphyllin A, a hexacyclic Daphniphyllum alkaloid, has been accomplished. A tetracyclic intermediate was... 
BIOMIMETIC TOTAL-SYNTHESIS | CYCLOADDITION | CATALYSIS | KINETIC RESOLUTION | SILYL ENOL ETHERS | SILVER | DAPHNIPHYLLUM ALKALOIDS | HOMODAPHNIPHYLLATE | CALYCIPHYLLINE | CHEMISTRY, MULTIDISCIPLINARY | ELECTRON-DEFICIENT OLEFINS | Hamamelidae | Usage | Ring formation (Chemistry) | Research | Chemical synthesis
Journal Article
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2018, Volume 140, Issue 12, pp. 4227 - 4231
Hybridaphniphylline B (1) is a Daphniphyllum alkaloid possessing 11 rings and 19 stereocenters. Here we report the first total synthesis of 1 featuring a... 
RUBRIFLORDILACTONE | BIOMIMETIC TOTAL-SYNTHESIS | ABSOLUTE-CONFIGURATION | LONGERACEMOSUM | (-)-CALYCIPHYLLINE N | CONSTRUCTION | CHEMISTRY | DAPHNIPHYLLUM ALKALOIDS | HOMODAPHNIPHYLLATE | CALYCIPHYLLINE | CHEMISTRY, MULTIDISCIPLINARY | Chemical properties | Diels-Alder reaction | Cyclopentadiene | Alkadienes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2014, Volume 53, Issue 34, pp. 9012 - 9016
Journal Article
Nature Chemistry, ISSN 1755-4330, 08/2013, Volume 5, Issue 8, pp. 679 - 684
The Daphniphyllum alkaloids are a large class of natural products isolated from a genus of evergreen plants widely used in Chinese herbal medicine. They... 
BIOMIMETIC TOTAL-SYNTHESIS | (+/-)-METHYL HOMODAPHNIPHYLLATE | RAPID CONSTRUCTION | SILYL ENOL ETHERS | TETRACYCLIC CORE | PENTACYCLIC ALKALOIDS | RING-SYSTEM | CARBON TRICYCLIC CORE | ELECTROCYCLIZATIONS | CHEMISTRY, MULTIDISCIPLINARY | SKELETON | Alkaloids - chemical synthesis | Saxifragaceae - chemistry | Catalysis
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 02/2019, Volume 17, Issue 7, pp. 1698 - 1702
Synthetic studies into the origins of the alkaloid incargranine A have resulted in the development of a four-step (longest linear sequence) total synthesis.... 
Journal Article