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Chemical Reviews, ISSN 0009-2665, 09/2016, Volume 116, Issue 17, pp. 9850 - 9913
The present review offers an overview of the current approaches for the photochemical and photocatalytic generation of reactive intermediates and their... 
PHENYL VINYL ETHER | DE-NOVO SYNTHESIS | PHOTOINDUCED ELECTRON-TRANSFER | DIELS-ALDER CYCLOADDITIONS | VISIBLE-LIGHT PHOTOREDOX | ALPHA-AMINO-ACIDS | SUNLIGHT-INDUCED FUNCTIONALIZATION | TRANSFER RADICAL-ADDITION | BIOMOLECULE-COMPATIBLE CONDITIONS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS
Journal Article
Organic Letters, ISSN 1523-7060, 06/2015, Volume 17, Issue 12, pp. 3054 - 3057
A mild K2S2O8 promoted decarboxylative alkynylation of alpha-keto acids and oxamic acids has been developed. This process features mild reaction conditions, a... 
ROOM-TEMPERATURE | OXIDATIVE DECARBOXYLATION | CROSS-COUPLING REACTION | CHEMISTRY, ORGANIC | OXOCARBOXYLIC ACIDS | BOND FORMATION | BIOMOLECULE-COMPATIBLE CONDITIONS | METAL-FREE ALKYNYLATION | ORTHO-ACYLATION | C-H ALKYNYLATION | CARBOXYLIC-ACIDS
Journal Article
Chemical Communications, ISSN 1359-7345, 2016, Volume 52, Issue 45, pp. 7292 - 7294
A novel and efficient visible-light photoredox method for the synthesis of internal alkynes containing quaternary carbons has been developed via coupling... 
ROOM-TEMPERATURE | CATALYSIS | PALLADIUM | ARYL HALIDES | TERMINAL ALKYNES | BIOMOLECULE-COMPATIBLE CONDITIONS | ALPHA-KETO ACIDS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | SONOGASHIRA COUPLING REACTION | DECARBOXYLATIVE ALKYNYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 06/2017, Volume 19, Issue 12, pp. 3291 - 3294
Synthetically useful radical thiol–ene reactions can be initiated by visible-light irradiation in the presence of an organic photocatalyst,... 
CLICK-BASED HYDROGELS | S-LINKED GLYCOPEPTIDES | HYDROFUNCTIONALIZATION REACTIONS | CHEMISTRY, ORGANIC | ANTI-MARKOVNIKOV HYDROAMINATION | MECHANISTIC INSIGHT | BIOMOLECULE-COMPATIBLE CONDITIONS | PROTEIN GLYCOCONJUGATION | RADICAL-CROSSOVER CYCLOADDITIONS | CARBOXYLIC-ACIDS | AQUEOUS-SOLUTION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2015, Volume 54, Issue 38, pp. 11200 - 11204
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 05/2016, Volume 52, Issue 45, pp. 7292 - 7294
A novel and efficient visible-light photoredox method for the synthesis of internal alkynes containing quaternary carbons has been developed viacoupling... 
Synthesis (chemistry) | Synthesis | Oxalates | Carbon | Functional groups | Alkynes
Journal Article
Organic Letters, ISSN 1523-7060, 09/2018, Volume 20, Issue 18, pp. 5817 - 5820
A method for remote radical C–H alkynylation at unactivated sites is reported. C–H functionalization proceeds via 1,5-hydrogen atom transfer (HAT) to amidyl... 
FUNCTIONALIZATION | VISIBLE-LIGHT | C(SP)-H BONDS | COUPLED ELECTRON-TRANSFER | AMIDYL RADICALS | LIGHT PHOTOREDOX CATALYSIS | ATOM-TRANSFER | CHEMISTRY, ORGANIC | BIOMOLECULE-COMPATIBLE CONDITIONS | DECARBOXYLATIVE ALKYNYLATION | CARBOXYLIC-ACIDS
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 03/2018, Volume 20, Issue 5, pp. 1400 - 1403
A copper-catalyzed C(sp)-C(sp(3)) coupling reaction between terminal alkynes and alkylsilyl peroxides is reported. In the presence of a copper catalyst and... 
ROOM-TEMPERATURE | VINYL SULFONES | CHEMISTRY, ORGANIC | BIOMOLECULE-COMPATIBLE CONDITIONS | SONOGASHIRA REACTIONS | ACETYLENIC TRIFLONES | CATALYZED DECARBOXYLATIVE ALKYNYLATION | C-H BONDS | CARBOXYLIC-ACIDS | PHOTOREDOX CATALYSIS | DIRECT ALKYLATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2018, Volume 57, Issue 19, pp. 5492 - 5496
Journal Article
Synthesis, ISSN 0039-7881, 01/2016, Volume 48, Issue 2, pp. 223 - 230
Abstract A new silver-promoted oxidative ring opening/alkynylation of cyclopropanols with ethynylbenziodoxolones (EBX) is described. This method enables the... 
paper | alkyne | cyclopropanol | silver | ring opening | alkynylation | C BOND-CLEAVAGE | CHEMISTRY, ORGANIC | BIOMOLECULE-COMPATIBLE CONDITIONS | NONACTIVATED ALKYL-HALIDES | CATALYZED DECARBOXYLATIVE ALKYNYLATION | ARYLBORONIC ACIDS | RADICAL CYCLIZATION | SONOGASHIRA REACTIONS | ALIPHATIC CARBOXYLIC-ACIDS | CONJUGATED ENYNES | GRIGNARD-REAGENTS
Journal Article
Green Chemistry, ISSN 1463-9262, 2016, Volume 18, Issue 15, pp. 4185 - 4188
A general and efficient method for the direct alkynylation of unactivated C(sp(3))-H bonds under metal-free conditions is described. The reaction performs... 
GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | VINYL SULFONES | BROMO CARBONYL-COMPOUNDS | COUPLING REACTIONS | BIOMOLECULE-COMPATIBLE CONDITIONS | SONOGASHIRA REACTIONS | ACETYLENIC TRIFLONES | SECONDARY ALKYL-HALIDES | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | CATALYZED DECARBOXYLATIVE ALKYNYLATION | GRIGNARD-REAGENTS
Journal Article
Green Chemistry, ISSN 1463-9262, 07/2016, Volume 18, Issue 15, pp. 4185 - 4188
A general and efficient method for the direct alkynylation of unactivated C(sp3)-H bonds under metal-free conditions is described. The reaction performs... 
Chemical bonds | Tolerances | Pathways | Radicals
Journal Article
by Zhou, QQ and Liu, D and Xiao, WJ and Lu, LQ
ACTA CHIMICA SINICA, ISSN 0567-7351, 01/2017, Volume 75, Issue 1, pp. 110 - 114
Visible-light photoredox catalysis, a novel and green catalytic strategy, has recently received increasing attention from chemists and been widely applied to... 
ANODIC CYANATION | BIOMOLECULE-COMPATIBLE CONDITIONS | CHEMISTRY, MULTIDISCIPLINARY | alpha-amino nitrile | DECARBOXYLATIVE ALKYNYLATION | FUNCTIONALIZATION | cyanation | visible-light photoredox catalysis | decarboxylative transformation | COUPLING REACTIONS | NITRILES | CHEMISTRY | ALIPHATIC CARBOXYLIC-ACIDS | DERIVATIVES | tertiary amine | METAL-FREE
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 02/2015, Volume 56, Issue 7, pp. 884 - 888
Journal Article
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