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Angewandte Chemie International Edition, ISSN 1433-7851, 03/2013, Volume 52, Issue 10, pp. 2963 - 2967
A trapped silicon atom: The compound (L:)2Si with low‐valent silicon was synthesized from its dichloride biradical precursor (L:)2SiCl2 by reduction with KC8.... 
low oxidation state | DFT calculation | silicon | biradicals | X‐ray structure | X-ray structure
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2019, Volume 25, Issue 71, pp. 16311 - 16319
The reactivity of the four‐membered NP3 ring system [RN(μ‐PCl)2PR] (R=Mes*=2,4,6‐tri‐tert‐butylphenyl) towards Lewis acids, Lewis bases, and reducing agents... 
ring systems | PN chemistry | biradicals | computational chemistry | phosphorus
Journal Article
Journal of Molecular Structure, ISSN 0022-2860, 11/2019, Volume 1196, pp. 653 - 657
A novel nitronyl nitroxide biradical-based Mn Dy compound [Dy Mn (hfac) (NITPhPybis) ] has been designed and assembled successfully, representing the first... 
Magnetism | MnII-DyIII | Biradical | Heterometallic
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 06/2017, Volume 139, Issue 22, pp. 7513 - 7521
Synthesis of antiaromatic polycyclic hydrocarbons (PHs) is challenging because the high energy of their highest occupied molecular orbital and low energy of... 
ACENES | AROMATICITY | GROUND-STATE | BIRADICALS | CRYSTAL-STRUCTURES | PENTACENE | ORGANIC SEMICONDUCTORS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | ELECTRONICS | MOLECULES
Journal Article
Organic & Biomolecular Chemistry, ISSN 1477-0520, 06/2014, Volume 12, Issue 25, pp. 4491 - 4502
Two comparative sets of mono-/dinitroxyl amides were designed and prepared. The novel TEMPO and/or PROXYL derivatives were fully characterised and their spin,... 
Journal Article
Chemical Science, ISSN 2041-6520, 11/2015, Volume 6, Issue 12, pp. 686 - 6812
We report a strategy to push the limits of solid-state NMR sensitivity far beyond its current state-of-the-art. The approach relies on the use of dynamic... 
SOLID-STATE NMR | TEMPERATURES | HIGH-FREQUENCY | SURFACE | GHZ | CROSS-POLARIZATION | LATTICE-RELAXATION | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | NITROXIDE BIRADICALS | CORRELATION SPECTROSCOPY | Polarization | Peptides | Dynamics | Sustainability | Nanostructure | Nuclear magnetic resonance | Helium | Spinning | Physics | Chemistry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2013, Volume 135, Issue 16, pp. 6363 - 6371
p-Quinodimethane (p-QDM) is a fundamental building block for the design of π-conjugated systems with low band gap and open-shell biradical character. However,... 
QUINOIDAL OLIGOTHIOPHENES | GRAPHENE NANORIBBONS | HYDROCARBONS | BIRADICALS | TERTHIOPHENE | TETRACYANODIPHENOQUINODIMETHANE TCNDQ | PHOTOPHYSICAL PROPERTIES | OPEN-SHELL | CLOSED-SHELL | CHEMISTRY, MULTIDISCIPLINARY | ELECTRON-ACCEPTORS
Journal Article
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2013, Volume 135, Issue 4, pp. 1430 - 1437
The characteristics of the edge state, which is a peculiar magnetic state in zigzag-edged graphene nanoribbons (ZGNRs) that originates from electron–electron... 
SPECTROSCOPY | NANOGRAPHENE | BIRADICALS | SYSTEMS | RADICALS | CHEMISTRY, MULTIDISCIPLINARY | CARBON NANOTUBES | Metal bonding | Molecular structure | Graphene | Analysis | Electron mobility | Chemical properties | Structure
Journal Article
Organic Letters, ISSN 1523-7060, 07/2013, Volume 15, Issue 13, pp. 3404 - 3407
Catenation of stable 1,3-diphopsphacyclobutane-2,4-diyl units with biphenyl-, diphenyl ether-, and diphenylmethane-based bridging groups were utilized for... 
CATENATION | CHEMISTRY, ORGANIC | ELEMENTS | BIRADICALS | BONDS
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 07/2015, Volume 51, Issue 57, pp. 11437 - 11440
The attempted preparation of the biradicaloid [E(μ-NTer)]2 (E = Sb, Bi) yielded salts of the anion [(TerN)2E](-). These heteroatom allyl analogues could be... 
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 2015, Volume 51, Issue 57, pp. 11437 - 11440
The attempted preparation of the biradicaloid [E(mu-NTer)](2) (E = Sb, Bi) yielded salts of the anion [(TerN)(2)E](-). These heteroatom allyl analogues could... 
ELEMENT COMPOUNDS | ANION | BIRADICALS | COMPLEXES | BONDS | CATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 10/2012, Volume 2012, Issue 29, pp. 5637 - 5653
Journal Article
Chemical Science, ISSN 2041-6520, 2016, Volume 7, Issue 10, pp. 6514 - 6518
Diradicals, molecules with two unpaired electrons, are reactive intermediates that play an important role in many fields. Their defining feature is the energy... 
TRANSITION | DICATION | PERSISTENT | RADICAL-CATION | BIRADICALS | ESR | CHEMISTRY | CHARACTER | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
by Li, SY and Yuan, NN and Fang, Y and Chen, C and Wang, L and Feng, R and Zhao, Y and Cui, HY and Wang, XP
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 04/2018, Volume 83, Issue 7, pp. 3651 - 3656
Three bis(triarylamine) dications bridged with 2,2'-bithienyl group (1(2+), biphenyl group (2(2+)) and [2,2]-paracydophane (3(2+)) have been successfully... 
SUBSTITUTION | ELECTRON-TRANSFER | THROUGH-SPACE | DONOR | BIRADICALS | RADICAL CATIONS | CHEMISTRY, ORGANIC | PATTERNS | TRANSITIONS | SOLID-STATE | SINGLET
Journal Article
Physical Chemistry Chemical Physics, ISSN 1463-9076, 04/2012, Volume 14, Issue 16, pp. 5729 - 5743
Proton Dynamic Nuclear Polarization (DNP) experiments were conducted on a 3.4 T homebuilt hybrid pulsed-EPR-NMR spectrometer, on static samples containing 10... 
SPECTROMETER | THEORETICAL ASPECTS | RESONANCE | TEMPERATURE | BIRADICALS | EPR | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CRYSTALS | CHEMISTRY, PHYSICAL | MODEL | C-13 NMR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2013, Volume 52, Issue 41, pp. 10858 - 10861
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 01/2019, Volume 84, Issue 1, pp. 140 - 149
Four weakly antiferromagnetic interacting biradicals of benzo[1,2-b:4,5-b']dithiophene (BDT) and BDT extended with two thiophenes (BDTTh2) linked with nitronyl... 
DESIGN | SPIN | BIRADICALS | BUILDING-BLOCKS | DIRADICALS | BENZODITHIOPHENE | CHEMISTRY, ORGANIC | RADICALS | BOSE-EINSTEIN CONDENSATION | EXCHANGE INTEGRALS | MOLECULES
Journal Article
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