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bis hydride complexes (19) 19
chemistry (11) 11
chemistry, inorganic & nuclear (8) 8
bis complexes (6) 6
chemistry, multidisciplinary (6) 6
oxidative addition (6) 6
c-h (5) 5
chemistry, organic (5) 5
cleavage (5) 5
ruthenium (4) 4
transition-metal complexes (4) 4
activation (3) 3
c-h activation (3) 3
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homogeneous catalysis (3) 3
ligands (3) 3
platinum (3) 3
1,2-bisethane ligands (2) 2
carbon-dioxide (2) 2
catalysis (2) 2
homogenous catalysis (2) 2
insertions (2) 2
k dy chemistry (2) 2
nonrigid 6-coordinate molecules (2) 2
oxidative addition-reactions (2) 2
phosphite complexes (2) 2
ray crystal-structures (2) 2
reactivity (2) 2
unsaturated iron complex (2) 2
zerovalent iron (2) 2
1,2-bisethane (1) 1
16-electron dihydrogen complexes (1) 1
1st examples (1) 1
ab-initio mo/mp4 (1) 1
absorption intensity calculations (1) 1
acetate (1) 1
acylations (1) 1
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alkyl (1) 1
alkylations (1) 1
analysis (1) 1
aryl halides (1) 1
bisphosphinoaryl ruthenium complexes (1) 1
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derivatives (1) 1
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diaryl ethers (1) 1
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dinitrogen complex (1) 1
dynamic stereochemistry (1) 1
electrophilic platinum complexes (1) 1
eta-2-dihydrogen (1) 1
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exchange-reactions (1) 1
excimer laser photolysis (1) 1
formic-acid (1) 1
forming reactions (1) 1
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hydrodeoxygenations (1) 1
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infrared-spectroscopy (1) 1
iron complex (1) 1
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kinetics (1) 1
ligand (1) 1
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low-temperature matrices (1) 1
manganese (1) 1
matrix-isolation (1) 1
metal polyhydrides (1) 1
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Journal of the American Chemical Society, ISSN 0002-7863, 03/2001, Volume 123, Issue 11, pp. 2576 - 2587
The platinum(IV) complexes fac-L2PtMe3(OR) (L2 = bis(diphenylphosphino)ethane, o-bis(diphenylphosphino)benzene, R = carboxyl, aryl; L = PMe3, R = aryl) undergo... 
ALKOXIDE COMPLEXES | BIS HYDRIDE COMPLEXES | MOLECULAR-STRUCTURE | C-O BOND | CRYSTAL-STRUCTURE | X-RAY | DIARYL ETHERS | OXIDATIVE ADDITION-REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | ELECTROPHILIC PLATINUM COMPLEXES | TETRAMETHYLPLATINUM(IV) COMPLEX | Hot Temperature | Kinetics | Oxidation-Reduction | Platinum - chemistry | Platinum | Oxidation-reduction reaction | Research
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/1998, Volume 120, Issue 26, pp. 6531 - 6541
Reaction of [RhCl(C8H14)2]2 (C8H14 = cyclooctene) with 2 equiv of the aryl methyl ether phosphine 1 in C6D6 results in an unprecedented metal insertion into... 
BIS HYDRIDE COMPLEXES | CARBON-CARBON BOND | PLATINUM(II) | CHEMISTRY | HOMOGENEOUS CATALYSIS | LIGAND | OXIDATIVE ADDITION | CLEAVAGE | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | C-H
Journal Article
Organometallics, ISSN 0276-7333, 04/2007, Volume 26, Issue 8, pp. 2005 - 2016
Treatment of Ru(η4-1,5-COD)(η6-1,3,5-COT) (1) (COD = cyclooctadiene (C8H12)) with a monosubstituted phenol HOC6H4(R1-2) (R1 = OMe, CHO, CO2Me) in the presence... 
SP C-H | ACTIVATION | BIS HYDRIDE COMPLEXES | CHEMISTRY | CHEMISTRY, ORGANIC | CRYSTAL-STRUCTURES | O-H | OXIDATIVE ADDITION | METAL-COMPLEXES | LIGAND DISPLACEMENT | EXCHANGE-REACTIONS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Bulletin of the Chemical Society of Japan, ISSN 0009-2673, 1/1995, Volume 68, Issue 1, pp. 62 - 83
Ruthenium complexes, e.g., Ru(H)2(CO)(PPh3)3, have been found to catalyze the addition of ortho C–H bonds of aromatic ketones to olefins with a high degree of... 
ORGANIC-SYNTHESIS | PHOTOCHEMICAL CARBONYLATION | PI-COMPLEX | TRANSITION-METAL COMPLEXES | BIS HYDRIDE COMPLEXES | SQUARE-PLANAR COMPLEXES | BIS(DIPHOSPHINE) COMPLEXES | OXIDATIVE ADDITION | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | STRUCTURAL CHARACTERIZATION
Journal Article
Angewandte Chemie International Edition in English, ISSN 0570-0833, 04/1997, Volume 36, Issue 6, pp. 625 - 626
An unprecedented metal insertion into the strong sp2sp3 arylO bond to form 2 is observed for the reaction of [{RhCl(C8H14)2}2] (C8H14 = cyclooctene) with two... 
palladium | homogeneous catalysis | insertions | CO activation | rhodium | Palladium | homogenous catalysis | Rhodium | Homogeneous catalysis | Insertions | C-O activation | CARBON-CARBON BOND | OXIDATIVE ADDITION | CLEAVAGE | BIS HYDRIDE COMPLEXES | CHEMISTRY | K DY CHEMISTRY | ACETATE | C-H
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/1999, Volume 38, Issue 15, pp. 2206 - 2208
Stable unsaturated heterocycles such as benzofuran are difficult to remove from petroleum by conventional catalytic hydrotreating. However, in a model system,... 
Hydrodeoxygenations | Metallacycles | Platinum | Insertions | Manganese | insertions | TRANSITION-METAL COMPLEXES | C-O | hydrodeoxygenations | REACTIVITY | OXIDATIVE ADDITION | CLEAVAGE | manganese | CHEMISTRY, MULTIDISCIPLINARY | platinum | BIS HYDRIDE COMPLEXES | HYDRODENITROGENATION CATALYSIS | DYNAMIC STEREOCHEMISTRY | DESULFURIZATION | HOMOGENEOUS HYDRODESULFURIZATION | metallacycles
Journal Article
JOURNAL OF ORGANOMETALLIC CHEMISTRY, ISSN 0022-328X, 04/1998, Volume 556, Issue 1-2, pp. 89 - 95
A zerovalent iron complex having an eta(6)-naphthalene ligand, Fe(eta(6)-C10H8)(dcype) (3) [dcype = 1,2-bis(dicyclohexylphosphino)ethane] has been prepared by... 
naphthalene complex | ZEROVALENT IRON | PHOSPHITE COMPLEXES | CHEMISTRY, ORGANIC | RUTHENIUM | reduction of 14e complex | TRANSITION-METALS | CHEMISTRY, INORGANIC & NUCLEAR | BIS HYDRIDE COMPLEXES | PI-COMPLEXES | 1,2-BIS(DIETHYLPHOSPHINO)ETHANE LIGANDS | crystal structure | CHEMISTRY | iron complex | CARBON-DIOXIDE | sodium-naphthalene | C-H
Journal Article
Angewandte Chemie International Edition in English, ISSN 0570-0833, 05/1997, Volume 36, Issue 10, pp. 1092 - 1095
An ususual migration of the alkyl group away from the CO bond of added formate leads to strictly stereospecific formation of the stable ehtyl complex 2 when... 
ruthenium | homogenous catalysis | alkylations | acylations | Alkylations | Ruthenium | Acylations | Homogeneous catalysis | FORMIC-ACID | OXIDATIVE ADDITION | CLEAVAGE | HYDROESTERIFICATION | homogeneous catalysis | BIS HYDRIDE COMPLEXES | CHEMISTRY | OXYGEN BOND | K DY CHEMISTRY | METHYL-FORMATE | X-RAY CRYSTAL | CARBON-DIOXIDE | C-H
Journal Article
Australian Journal of Chemistry, ISSN 0004-9425, 1999, Volume 52, Issue 11, pp. 1005 - 1012
Thermal elimination of methane from cis -FeH(CH 3 )(dprpe) 2 [dprpe = 1,2-bis(dipropylphosphino)ethane] or photochemical elimination of dihydrogen from FeH 2... 
UNSATURATED IRON COMPLEX | ACTIVATION | BIS HYDRIDE COMPLEXES | LIGANDS | ALKYL | CHEMISTRY | BIS(DIPHOSPHINE) COMPLEXES | CLEAVAGE | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/1993, Volume 115, Issue 19, pp. 8627 - 8637
The transient photochemistry in solution and low-temperature matrix photochemistry of Fe(dmpe)2H2 (dmpe = Me2PCH2CH2PMe2) are reported; this compound is... 
EXCIMER LASER PHOTOLYSIS | BIS HYDRIDE COMPLEXES | RESOLVED IR SPECTROSCOPY | UNSATURATED METAL CENTERS | OXIDATIVE-ADDITION | GAS-PHASE | CHEMISTRY | NONRIGID 6-COORDINATE MOLECULES | INFRARED-SPECTROSCOPY | BIS(DIPHOSPHINE) COMPLEXES | LOW-TEMPERATURE MATRICES
Journal Article
Organometallics, ISSN 0276-7333, 03/1993, Volume 12, Issue 3, pp. 906 - 916
The novel bulky and basic tetradentate ligand P(CH2CH2PCy2)3 (PP3Cy) is synthesized by the LiN(i-Pr)2-Catalyzed addition reaction of dicyclohexylphosphine... 
TRIHYDRIDE COMPLEXES | POLY(TERTIARY PHOSPHINES) | TRIMETHYLENE LINKAGES | BIS HYDRIDE COMPLEXES | R = PH | RAY CRYSTAL-STRUCTURES | POLYPHOSPHINE LIGANDS | CHEMISTRY, ORGANIC | H3B(CH3)2P GROUP | POLYTERTIARY PHOSPHINES | METAL POLYHYDRIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 07/1993, Volume 12, Issue 7, pp. 2505 - 2514
Thermolysis of [(triphos)Ir(H)2(C2H5)] (1) in various solvents (benzene, THF, MeCN, DMF) results in formation of the 16-electron fragment [(triphos)IrH] and... 
EXCELLENT PRECURSORS | CARBON-HYDROGEN-BOND | TRIPODAL POLYPHOSPHINE LIGANDS | TRANSITION-METAL COMPLEXES | BIS HYDRIDE COMPLEXES | ORGANOMETALLIC CHEMISTRY | CHEMISTRY, ORGANIC | VINYLIDENE | BIS(DIPHOSPHINE) COMPLEXES | MATRIX-ISOLATION | RAY CRYSTAL-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 1992, Volume 11, Issue 3, pp. 1263 - 1274
Journal Article
Canadian Journal of Chemistry, ISSN 0008-4042, 03/1994, Volume 72, Issue 3, pp. 547 - 560
The synthesis and properties of dihydrogen complexes trans-[MH(H 2 )L] + , M = Fe, Ru, Os, which contain the ligand meso-tetraphos-1, S,R-Ph 2 PCH 2 CH 2... 
BIS HYDRIDE COMPLEXES | CRYSTAL-STRUCTURE | STEREOCHEMICAL CONTROL | MOLECULAR-HYDROGEN COMPLEXES | 1ST EXAMPLES | CHEMISTRY | X = CL | POLYDENTATE PHOSPHINES | ETA-2-DIHYDROGEN
Journal Article
POLYHEDRON, ISSN 0277-5387, 02/1993, Volume 12, Issue 4, pp. 427 - 434
The title compounds have been studied by single-crystal X-ray diffraction. Both structures can be described as distorted octahedra. P-Ru-P angles between... 
CARBON | BIS HYDRIDE COMPLEXES | RAY CRYSTAL-STRUCTURES | N-H | CHEMISTRY | REACTIVITY | RUTHENIUM | CRYSTALLOGRAPHY | TRIMETHYLPHOSPHINE | BOND-CLEAVAGE | C-H ACTIVATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the Chemical Society, Dalton Transactions, ISSN 1470-479X, 2000, Issue 11, pp. 1733 - 1741
Routes to hydrido- and organo-iron complexes of the bidentate ligand o-phenylenebis(dimethylphosphine), o-C6H4(PMe2)(2) (pdmp), have been developed, starting... 
HIGHER OXIDATION-STATES | DINITROGEN COMPLEX | 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE | HYDROGEN COMPLEXES | BIS HYDRIDE COMPLEXES | LIGANDS | CHEMISTRY | BIS(DIPHOSPHINE) COMPLEXES | C-H BONDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the Chemical Society - Dalton Transactions, ISSN 0300-9246, 10/1997, Issue 19, pp. 3453 - 3458
Reduction of [FeCl2(depe)(2)] (depe = Et2PCH2CH2PEt2) by sodium-naphthalene under nitrogen gave a dinitrogen complex of iron(o), [Fe(N-2)(depe)(2)] 1, in 72%... 
NITROGEN-FIXATION | ACTIVATION | BIS HYDRIDE COMPLEXES | ZEROVALENT IRON | CRYSTAL-STRUCTURE | 1,2-BIS(DIETHYLPHOSPHINO)ETHANE LIGANDS | CHEMISTRY | RUTHENIUM | CARBON-DISULFIDE | K EC CHEMISTRY, INORGANIC & NUCLEAR | C-H | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
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