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bisborane (155) 155
chemistry (90) 90
chemistry, multidisciplinary (82) 82
chemistry, inorganic & nuclear (71) 71
chemistry, organic (57) 57
reactivity (53) 53
hydroboration (44) 44
activation (42) 42
frustrated lewis pairs (42) 42
boron (39) 39
borane (38) 38
complexes (34) 34
boranes (26) 26
trisborane (25) 25
reduction (24) 24
catalysts (21) 21
derivatives (21) 21
hydrogenation (21) 21
free catalytic-hydrogenation (20) 20
olefin polymerization (20) 20
imines (19) 19
ligands (19) 19
heterolytic dihydrogen activation (18) 18
zirconium (17) 17
catalysis (16) 16
zirconocene (15) 15
lewis acids (14) 14
b (13) 13
hydrogen (13) 13
index medicus (13) 13
lewis acid (13) 13
phosphines (13) 13
phosphorus (13) 13
hydrosilylation (12) 12
polymerization (12) 12
1,1-organoboration (11) 11
alkynes (11) 11
basis-sets (11) 11
mechanism (11) 11
metal-free hydrogenation (11) 11
adducts (10) 10
alkenes (10) 10
analysis (10) 10
dihydrogen activation (10) 10
ligand (10) 10
exchange (9) 9
frustrated lewis pair (9) 9
hydrides (9) 9
lewis-acid (9) 9
ray crystal-structure (9) 9
coordination (8) 8
crystal-structure (8) 8
crystal-structures (8) 8
route (8) 8
addition-reactions (7) 7
alcohols (7) 7
anions (7) 7
bond activation (7) 7
bor (7) 7
borine carbonyl (7) 7
chemical properties (7) 7
diffraction (7) 7
enantioselective hydrogenation (7) 7
h-2 (7) 7
homogeneous catalysis (7) 7
hydride (7) 7
ketones (7) 7
metal-free (7) 7
olefin polymerization catalysts (7) 7
structural-characterization (7) 7
1,1-carboboration (6) 6
asymmetric catalysis (6) 6
bisborinic acid (6) 6
carbene (6) 6
carbon (6) 6
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chemistry, physical (6) 6
enamines (6) 6
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hb (6) 6
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insertion (6) 6
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acid (5) 5
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boranes - chemistry (5) 5
carbon monoxide (5) 5
catalytic-hydrogenation (5) 5
cation (5) 5
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co2 (5) 5
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Chemical communications (Cambridge, England), ISSN 1359-7345, 02/2014, Volume 50, Issue 11, pp. 1295 - 1298
The perfluorinated boraindene was synthesized and fully characterized. Both computational and crystallographic data show that is antiaromatic. Compound was... 
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 1/2020, Volume 56, Issue 6, pp. 841 - 853
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 07/2005, Volume 44, Issue 14, pp. 5030 - 5041
The previously known anion [(C6F5)3B(μ-OH)B(C6F5)3]- (2) has been prepared by a two-step procedure, involving deprotonation of (C6F5)3BOH2 to give... 
BIS(PENTAFLUOROPHENYL)BORINIC ACID | POLYMERIZATION CATALYSTS | (C6F5)B-N-HETEROCYCLE COMPLEXES | OLEFIN POLYMERIZATION | CRYSTAL-STRUCTURES | ADDUCTS | ACIDIC SP CARBONS | F-C | SOLID-STATE | HYDROGEN-BONDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organic Letters, ISSN 1523-7060, 10/2016, Volume 18, Issue 20, pp. 5189 - 5191
With the use of ammonia borane as a hydrogen source, a borane catalyzed metal-free transfer hydrogenation of pyridines was successfully realized for the first... 
REDUCTION | LIGANDS | IMINES | ENANTIOSELECTIVE HYDROGENATION | HYDROSILYLATION | CHEMISTRY, ORGANIC | METAL-FREE HYDROGENATION | FRUSTRATED LEWIS PAIRS | FREE ASYMMETRIC HYDROGENATION | CHIRAL DIENES | BIS(PENTAFLUOROPHENYL)BORANE
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2017, Volume 56, Issue 44, pp. 13757 - 13761
Described herein is the selective reduction of sugars with hydrosilanes catalyzed by using Piers’ borane [(C6F5)2BH] generated in situ. The hydrosilylative C−O... 
chemoselectivity | sugars | bond cleavage | hydrosilylative reduction | Piers’ borane | BIS(PENTAFLUOROPHENYL)BORINIC ACID | H-H | HYDROGENATION | Piers' borane | B(C6F5)-CATALYZED HYDROSILATION | HYDROSILYLATION CATALYSTS | CHEMISTRY, MULTIDISCIPLINARY | REDUCTION | ALKYL ETHERS | DEOXYGENATION | ALKENE HYDROSILYLATION | TERTIARY SILANES | Chemotherapy | Polyols | Sugars | Cancer
Journal Article
Organic Letters, ISSN 1523-7060, 05/2017, Volume 19, Issue 10, pp. 2604 - 2606
An asymmetric transfer hydrogenation of 2,3-disubstituted quinoxalines using a chiral frustrated Lewis pair of Piers’ borane and (R)-tert-butylsulfinamide as... 
HIGHLY ENANTIOSELECTIVE HYDROGENATION | REDUCTION | LIGANDS | IMINES | HYDROSILYLATION | CHEMISTRY, ORGANIC | METAL-FREE HYDROGENATION | FRUSTRATED LEWIS PAIRS | INHIBITORS | EFFICIENT | BIS(PENTAFLUOROPHENYL)BORANE
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2011, Volume 17, Issue 35, pp. 9640 - 9650
The reaction of a solution of B(C6F4H)3 and either iPr3P or tBu3P with CO2 afforded the species R3P(CO2)B(C6F4H)3 (R=iPr (1), tBu (2)). In a similar fashion... 
boranes | phosphines | formate | carbon dioxide fixation | frustrated Lewis pairs | ACTIVATION | BORANE | CHEMISTRY, MULTIDISCIPLINARY | HOMOGENEOUS HYDROGENATION | NITROUS-OXIDE | ZETA VALENCE QUALITY | CHEMISTRY | GAS | BASIS-SETS | CARBON-DIOXIDE | BIS(PENTAFLUOROPHENYL)BORANE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2013, Volume 135, Issue 35, pp. 12968 - 12971
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2016, Volume 138, Issue 39, pp. 12956 - 12962
Inspired by the zwitterion species generated from the splitting of H2 by frustrated Lewis pairs, we put forward a novel frustrated Lewis pair by the... 
DENSITY FUNCTIONALS | BIS(SULFINYL)IMIDOAMIDINE LIGANDS | MOLECULAR-ORBITAL METHODS | ENANTIOSELECTIVE HYDROGENATION | GAUSSIAN-TYPE BASIS | METAL-FREE HYDROGENATION | BASIS-SETS | OLEFIN LIGANDS | CHIRAL DIENES | CHEMISTRY, MULTIDISCIPLINARY | BIS(PENTAFLUOROPHENYL)BORANE | Schiff bases | Catalysis | Research | Chemical properties
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2013, Volume 52, Issue 8, pp. 2243 - 2246
A new reaction pathway: Carbon monoxide is readily reduced by Piers' borane at a frustrated Lewis pair (FLP) to yield a formylborane stabilized by the FLP (see... 
carbon monoxide | reduction | boron | frustrated Lewis pairs | phosphorus | TRIALKYLBORANES | ACTIVATION | COMPLEXES | CO | CHEMISTRY, MULTIDISCIPLINARY | ORGANOBORANES | CARBONYLATION | BASIS-SETS | BINDING | BIS(PENTAFLUOROPHENYL)BORANE | Carbon monoxide | Pictures | Reduction | Pathways | Piers | Boranes | Activation
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 04/2013, Volume 730, pp. 44 - 48
The dimethylsulfide adduct of bis(pentafluorophenyl)borane HB(C6F5)2·SMe2 reacts on mixing with alkenes such as 1-hexene and styrene, with selectivities... 
Boranes | Hydroboration | Alkenes | Lewis adduct | 11B NMR spectroscopy | B NMR spectroscopy | ACTIVATION | HB(C6F5) | COMPLEX | ACID | CRYSTAL-STRUCTURE | CHEMISTRY, ORGANIC | CYCLIC HYDROBORATION | LEWIS PAIRS | CHEMISTRY, INORGANIC & NUCLEAR | 1,5-CYCLOOCTADIENE | CHEMISTRY | B-11 NMR spectroscopy | BIS(PENTAFLUOROPHENYL)BORANE | Chemical tests and reagents | Olefins
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 49, pp. 6344 - 6347
The intramolecular 1-PMes(2)/8-B(C6F5)(2) substituted biphenylene frustrated Lewis pair 4 shows some behavior reminiscent of intermolecular FLP systems. It... 
HYDROGEN | ACTIVATION | HYDROBORATION | PHOSPHINE | ELECTRONIC CONTROL | COMPLEXES | CHEMISTRY | REACTIVITY | BORANE | CHEMISTRY, MULTIDISCIPLINARY | BIS(PENTAFLUOROPHENYL)BORANE
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2006, Volume 45, Issue 10, pp. 1611 - 1614
Journal Article
Dalton Transactions, ISSN 1477-9226, 07/2012, Volume 41, Issue 28, pp. 8609 - 8614
The reaction of the Grignard reagent (p-C6F4H) MgBr with Me2SnCl2 afforded the p-C6F4H transfer reagent Me2Sn(p-C6F4H)(2) (1). Subsequent reaction of 1 with... 
FREE HYDROGEN ACTIVATION | HYDROBORATION | TRIS(PENTAFLUOROPHENYL)BORANE | DIHYDROGEN ACTIVATION | OLEFIN POLYMERIZATION | FRUSTRATED LEWIS PAIRS | H-2 | CARBON-DIOXIDE | METAL-FREE | BIS(PENTAFLUOROPHENYL)BORANE | CHEMISTRY, INORGANIC & NUCLEAR | Single crystals | Diffraction | X-rays | Boranes | Hydrides | NMR spectroscopy | Crystal structure
Journal Article
Chemical science, ISSN 2041-6520, 02/2017, Volume 8, Issue 2, pp. 1097 - 1104
Cyclopropylacetylene reacts with two molar equivalents of Piers' borane [HB(C F ) ] under mild conditions by an addition/rearrangement sequence with... 
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 01/2017, Volume 2017, Issue 2, pp. 368 - 371
The α‐phosphanylferrocenecarbaldehyde (pS)‐1 was converted into the β‐styryl derivative (pS)‐4 by Wittig–Horner olefination. Subsequent hydroboration with... 
Phosphorus | Boron | Metallocenes | Asymmetric catalysis | Hydrogenation | Frustrated Lewis pairs | ACTIVATION | ACID | CARBON | FREE CATALYTIC-HYDROGENATION | QUINOLINES | BORANE | CHEMISTRY, INORGANIC & NUCLEAR | HIGHLY ENANTIOSELECTIVE HYDROGENATION | SILYL ENOL ETHERS | CHEMISTRY | BIS(PENTAFLUOROPHENYL)BORANE | Iron compounds | Splitting | Asymmetry | Imines | Catalysts | Crystallization | Boranes | Derivatives
Journal Article