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1. Full Text Complementary Strategies for Directed C(sp3)−H Functionalization: A Comparison of Transition‐Metal‐Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer
by Chu, John C. K and Rovis, Tomislav
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2018, Volume 57, Issue 1, pp. 62 - 101
The functionalization of C(sp3)−H bonds streamlines chemical synthesis by allowing the use of simple molecules and providing novel synthetic disconnections.... 
C−H functionalization | carbenes | hydrogen atom transfer | nitrenes | transition metals | RADICAL TRANSLOCATION REACTIONS | INTERMOLECULAR AMINATION | ENANTIOSELECTIVE SYNTHESIS | ALPHA-AMINO-ACIDS | UNACTIVATED C(SP)-H | INTRAMOLECULAR FUNCTIONALIZATION | C-H functionalization | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | INSERTION REACTIONS | ALIPHATIC-AMINES | LATE-STAGE FUNCTIONALIZATION | Comparative analysis | Hydrogen | Chemical bonds | Activation | Chemical synthesis | Metals | Hydrogen ion concentration
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2. Full Text Tertiary‐Alcohol‐Directed Functionalization of Remote C(sp3)−H Bonds by Sequential Hydrogen Atom and Heteroaryl Migrations
by Wu, Xinxin and Wang, Mingyang and Huan, Leitao and Wang, Dongping and Wang, Jinwei and Zhu, Chen
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2018, Volume 57, Issue 6, pp. 1640 - 1644
Reported for the first time is a tertiary‐alcohol‐guided heteroarylation of remote C(sp3)−H bonds. The mild and direct generation of alkoxyl radicals from... 
C−H activation | electron transfer | radicals | heteroaryls | photocatalysis | VISIBLE-LIGHT PHOTOCATALYSIS | PHOTOCHEMICAL-REACTION | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS | ALKOXY RADICALS | C-H activation | TETRAHYDROFURANS | COUPLED ELECTRON-TRANSFER | HYPOCHLORITES | H BONDS | GENERATION | Hydrogen | Catalysis | Alcohols | Alcohol | Ketones | Migration | Hydrogen ion concentration
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3. Full Text Metal‐Free Radical [2+2+1] Carbocyclization of Benzene‐Linked 1,n‐Enynes: Dual C(sp3)H Functionalization Adjacent to a Heteroatom
by Hu, Ming and Fan, Jian‐Hong and Liu, Yu and Ouyang, Xuan‐Hui and Song, Ren‐Jie and Li, Jin‐Heng
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2015, Volume 54, Issue 33, pp. 9577 - 9580
A new metal‐free oxidative radical [2+2+1] carbocyclization of benzene‐linked 1,n‐enynes with two C(sp3)H bonds adjacent to the same heteroatom is described.... 
carbocycles | radicals | enynes | peroxides | heterocycles | ROCAGLAMIDE DERIVATIVES | PAUSON-KHAND REACTION | CYCLOADDITION REACTIONS | CASCADE REACTIONS | 1,3-DICARBONYL COMPOUNDS | BOND FUNCTIONALIZATION | HIGHLY EFFICIENT ACCESS | CHEMISTRY, MULTIDISCIPLINARY | ACTIVATED ALKENES | CATALYZED OXIDATIVE ARYLALKYLATION | COMPLEX POLYCYCLIC MOLECULES | Cyclization | Heterocyclic Compounds - chemistry | Oxidation-Reduction | Free Radicals - chemistry | Peroxides - chemistry | Catalysis | Benzene Derivatives - chemistry | Hydrocarbons | Free radicals | Organic chemistry | Chemical reactions | Radicals
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4. Full Text Transition‐Metal‐Catalyzed Selective Functionalization of C(sp3)−H Bonds in Natural Products
by Karimov, Rashad R and Hartwig, John F
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2018, Volume 57, Issue 16, pp. 4234 - 4241
Direct functionalization of natural products is important for studying the structure–activity and structure–property relationships of these molecules. Recent... 
regioselectivity | oxidation | catalysis | amination | C−H bond functionalization | COMPLEX | CARBON | DRUG DISCOVERY | HYDROXYLATIONS | METHYL-GROUPS | CYCLOPALLADATION | FLUORINATION | C-H bond functionalization | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | CHALLENGES | AZIDATION | Chemical bonds | Transformation | Molecular structure | Natural products | Metals
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5. Full Text Functionalization of Organic Molecules by Transition‐Metal‐Catalyzed C(sp3)H Activation
by Jazzar, Rodolphe and Hitce, Julien and Renaudat, Alice and Sofack‐Kreutzer, Julien and Baudoin, Olivier
Chemistry – A European Journal, ISSN 0947-6539, 03/2010, Volume 16, Issue 9, pp. 2654 - 2672
Transition‐metal‐catalyzed CH activation has recently emerged as a powerful tool for the functionalization of organic molecules. While many efforts have... 
CH functionalization | CH activation | alkanes | C-H functionalization | Alkanes | C-H activation | IRIDIUM POLYHYDRIDE SYSTEM | AEROBIC OXIDATIVE AMINATION | THERMOCHEMICAL ALKANE DEHYDROGENATION | PD(OAC)-CATALYZED DOMINO REACTIONS | CARBON-HYDROGEN BONDS | FORMING REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | CROSS-COUPLING REACTIONS | HINDERED GRIGNARD-REAGENTS | PROTON-ABSTRACTION MECHANISM | Organic chemistry | Synthesis (chemistry) | Aromatic compounds | Breaking | Strategy | Activation | Functional groups | Chemical Sciences
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6. Full Text Dual C(sp3)−H Bond Functionalization of N‐Heterocycles through Sequential Visible‐Light Photocatalyzed Dehydrogenation/[2+2] Cycloaddition Reactions
by Xu, Guo‐Qiang and Xu, Ji‐Tao and Feng, Zhi‐Tao and Liang, Hui and Wang, Zhu‐Yin and Qin, Yong and Xu, Peng‐Fei
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2018, Volume 57, Issue 18, pp. 5110 - 5114
Herein we describe a mild method for the dual C(sp3)−H bond functionalization of saturated nitrogen‐containing heterocycles through a sequential visible‐light... 
C−H functionalization | [2+2] cycloaddition | dehydrogenation | visible-light photocatalysis | synthetic methods | ORGANIC-CHEMISTRY | ACTIVATION | NITROGEN-HETEROCYCLES | PHARMACEUTICALS | C-H functionalization | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | PHOTOREDOX CATALYSIS | METHODOLOGY | AMINES | DIELS-ALDER REACTION | Amino acids | Catalysis | Dehydrogenation | Acetylene | Cycloaddition | Hydrogen bonds | Esters | Nitrogen | Amino radical | Intermediates
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7. Full Text Cooperative Polar/Steric Strategy in Achieving Site‐Selective Photocatalyzed C(sp3)−H Functionalization
by Yamada, Keiichi and Fukuyama, Takahide and Fujii, Saki and Ravelli, Davide and Fagnoni, Maurizio and Ryu, Ilhyong
Chemistry – A European Journal, ISSN 0947-6539, 06/2017, Volume 23, Issue 36, pp. 8615 - 8618
Synergistic control over the SH2 transition states of hydrogen ion exploiting polar and steric effects provides a promising cooperative strategy for... 
C−H functionalization | steric effects | decatungstate | site-selectivity | photocatalysis | HYDROGEN-ATOM TRANSFER | ALKYLATION | BENZYLATION | ALIPHATIC NITRILES | C-H functionalization | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | CHALLENGES | PHOTOREDOX CATALYSIS | BROMINE | DECATUNGSTATE PHOTOCATALYSIS | RADICALS | Catalysis | Lactones | Ketones | Hydrogen bonds | Cyclohexanone | Hydrogen | Photocatalysis | Chemical bonds | Strategy | Steric effects | Bearing | Methylene
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