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Chemistry Letters, ISSN 0366-7022, 9/2017, Volume 46, Issue 9, pp. 1296 - 1299
A catalytic method for the synthesis of dibenzophosphole derivatives using bisphosphines as the starting material is developed. The reaction proceeds through... 
Palladium catalyst | Phosphole | Carbon–phosphorus bond cleavage | Phosphorus | Cleavage | Palladium | Catalysis | Chemical synthesis | Carbon | Substrates
Journal Article
01/2019, ISBN 3039212044
The amide bond represents a privileged motif in chemistry. The recent years have witnessed an explosion of interest in the development of new chemical... 
N-heterocyclic carbene | non planar amide | ruthenium (Ru) | physical organic chemistry | gemcitabine prodrug | pyramidal amides | bridged sultams | catalysis | dipeptides | N-(1-naphthyl)acetamide | C-N ? bond cleavage | steric effects | peptide bond cleavage | transition-metal-free | palladium | N bond cleavage | N-heterocyclic carbenes (NHCs) | addition reaction | rhodium | metal complexes | carbanions | thioamidation | amide bond | intramolecular catalysis | antiviral activity | additivity principle | pre-catalysts | bridged lactams | arynes | twisted amides | organic synthesis | amination | Suzuki-Miyaura | tert-butyl | cyclopentadienyl complexes | C-S formation | enzymes | DFT study | sulfonamide bond | HERON reaction | primaquine | entropy | amide activation | amidation | synthesis | amide hydrolysis | carbonylicity | amide bond activation | amide bond resonance | aminosulfonylation | molecular dynamics | model compound | in situ | amide | homogeneous catalysis | heterocycles | anomeric effect | multi-component coupling reaction | kinetic | excited state | H acidity | palladium catalysis | amides | thiourea | formylation | alkynes | cis/trans isomerization | intein | C-H functionalization | succindiamide | amide C | amide bonds | O activation | crown ether | aminoacylation | directing groups | cytostatic activity | reaction thermodynamics | acyl transfer | transition metals | N-dimethylformamide | DMAc | acylative cross-coupling | C activation | C-H/C-N activation | nickel catalysis | antibacterial screening | sodium | aryl thioamides | Winkler-Dunitz parameters | catalyst | N-dimethylacetamide | base-catalyed hydrolysis | nitrogen heterocycles | cross-coupling | insertion | amidicity | nitro-aci tautomerism | activation | carbonylation | transamidation | amine | distortion | Pd-catalysis | rotational barrier energy | hypersensitivity | metabolic stability | [2+2+2] annulation | H bond cleavage | twisted amide | protease | cyanation | amide resonance | trialkylborane | catalysts | biofilm eradication | pharmacokinetics | N bond activation | pancreatic cancer cells | DMF | aryl esters | Michael acceptor | fumardiamide | water solvation | ester bond activation | cyclization | nuclear magnetic resonance | secondary amides | reaction mechanism | density functional theory | density-functional theory | amino acid transporters
eBook
Angewandte Chemie (International ed.), ISSN 1433-7851, 11/2013, Volume 52, Issue 45, pp. 11892 - 11895
(Phosp)hole in one: A palladium‐catalyzed synthesis for directly assembling phosphole skeletons from triarylphosphines through CH and CP bond cleavage was... 
carbon‐hydrogen bond cleavage | palladium | phosphole | homogeneous catalysis | carbon‐phosphorus bond cleavage | carbon-phosphorus bond cleavage | carbon-hydrogen bond cleavage | Hydrogen | Analysis | Palladium | Synthesis | Assembling | Pyrroles | Cleavage | Furans | Derivatives | Arrays | Bearing
Journal Article
Synthesis (Stuttgart), ISSN 0039-7881, 10/2010, Volume 2010, Issue 20, pp. 3395 - 3409
Abstract Arene and heteroarene carboxylic acids undergo regioselective arylation and vinylation reactions at the positions ORTHO (CINE) and IPSO to their... 
review | decarboxylation | C-H bond cleavage | carboxylic acids | arylation | olefination | Physical Sciences | Chemistry | Chemistry, Organic | Science & Technology
Journal Article
Biological & pharmaceutical bulletin, ISSN 0918-6158, 2013, Volume 36, Issue 4, pp. 635 - 640
We previously isolated the human intestinal bacterium, strain PUE, which can cleave the C-glucosidic bond of puerarin to yield its aglycone daidzein and... 
glycosidase | puerarin | enzyme purification | C–C bond cleavage | C-glucoside | Glycosidase | C-C bond cleavage | Enzyme purification | Puerarin | Life Sciences & Biomedicine | Pharmacology & Pharmacy | Science & Technology
Journal Article
Journal of Saudi Chemical Society, ISSN 1319-6103, 01/2019, Volume 23, Issue 1, pp. 7 - 12
A tandem Pd2(dba)3 participated C–C bond cleavage of O-bromophenyl cyclobutanone derivatives/Michael addition reaction sequence was realized. We disclosed the... 
Palladium | Cyclobutanone | Benzospirone | C–C bond cleavage
Journal Article
Coordination chemistry reviews, ISSN 0010-8545, 01/2016, Volume 306, Issue 2, pp. 510 - 532
•Summary of recent efforts in the selective catalytic depolymerization of lignin.•From detailed studies on model compound to actual applications.•Focus on... 
Aromatic chemicals | C[sbnd]O bond cleavage | Lignin depolymerization | Homogeneous catalysis | CO bond cleavage | Physical Sciences | Chemistry, Inorganic & Nuclear | Chemistry | Science & Technology | Transition metal compounds | Lignin | Catalysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2016, Volume 138, Issue 28, pp. 8900 - 8911
The development of fundamentally new approaches for lignin depolymerization is challenged by the complexity of this aromatic biopolymer. While overly... 
SELECTIVE OXIDATION | ENANTIOSELECTIVE SYNTHESIS | BETA-O-4 BOND-CLEAVAGE | PRODUCTS | CONVERSION | C-O BONDS | DEGRADATION | IONIC LIQUID | ACIDOLYSIS | MOLECULAR-WEIGHT PHENOLS | To be checked by Faculty | Polymerization | Lignin | Research | Chemical properties | Catalysis | Index Medicus
Journal Article
2016, ISBN 9783527336326, xii, 278 pages
Edited by leading experts and pioneers in the field, this is the first up-to-date book on this hot topic. The authors provide synthetic chemists with different... 
Scission (Chemistry) | Carbon compounds | Transition metals | Transition metal catalysts | Organometallic compounds
Book
Current Organic Chemistry, ISSN 1385-2728, 05/2012, Volume 16, Issue 10, pp. 1170 - 1214
The catalytic C-C bond activation by rhodium complexes has found a wide application in organic synthesis. The course of the reaction is usually controlled by... 
C-C bond cleavage | Synthesis | Catalysis | Rhodium | Physical Sciences | Chemistry | Chemistry, Organic | Science & Technology
Journal Article