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Science, ISSN 0036-8075, 6/2012, Volume 336, Issue 6087, pp. 1394 - 1395
Although carbon readily forms double and even triple bonds, such bonds are much rarer between the heavier elements of the same group or between atoms of other... 
Molecules | Chemistry | Reactivity | PERSPECTIVES | Atoms | Ligands | Ground state | Molecular orbitals | Chemical bonding | MOLECULE | MULTIDISCIPLINARY SCIENCES | HETEROCYCLIC CARBENE | Chemical bonds | Boron | Chemical synthesis | Chemical compounds | Silicon compounds | Synthesis (chemistry) | Chemists | Carbon | Bonding
Journal Article
Science, ISSN 0036-8075, 6/2012, Volume 336, Issue 6087, pp. 1420 - 1422
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2013, Volume 52, Issue 13, pp. 3574 - 3583
The construction of boron–boron bonds, despite the intense synthetic interest in diboranes and the high BB bond enthalpy, is still difficult, uncontrollable,... 
boron‐centered ligands | boron–boron bonds | boron | multiple bonding | transition metals | boron-boron bonds | boron-centered ligands | Construction | Diborane | Boron | Formations | Synthesis | Enthalpy
Journal Article
by Xu, B and Li, WJ and Yu, WJ and Pu, Z and Tan, ZY and Cheng, JJ and Wang, XF and Andrews, L
INORGANIC CHEMISTRY, ISSN 0020-1669, 10/2019, Volume 58, Issue 19, pp. 13418 - 13425
The boron-transition-metal triple-bond complexes FB MF2 (M= Ir, Os, Re, W, Ta) were trapped in excess solid neon and argon through metal atom reactions with... 
INFRARED-SPECTRA | METHYLIDYNE COMPLEXES | LIGANDS ER E | STATE PERTURBATION-THEORY | MATRIX PREPARATION | ATOMS | TERMINAL BORYLENE COMPLEXES | REACTION CHEMISTRY | LASER-ABLATED BORON | B-TL | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Nature Chemistry, ISSN 1755-4330, 2013, Volume 5, Issue 12, pp. 1025 - 1028
Many metal-containing compounds, and some metal-free compounds, will bind carbon monoxide. However, only a handful of metal-containing compounds have been... 
ACIDS | CARBENES | COMPLEXES | REACTIVITY | CHEMISTRY | AGENTS | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE | REDUCTIVE HOMOLOGATION | Models, Molecular | Crystallography, X-Ray | Carbon Monoxide - chemistry | Boron - chemistry | Electrochemical Techniques | Magnetic Resonance Spectroscopy
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 2013, Volume 52, Issue 13, pp. 3574 - 3583
The construction of boronboron bonds, despite the intense synthetic interest in diboranes and the high BB bond enthalpy, is still difficult, uncontrollable,... 
HETEROCYCLIC CARBENE | MOLECULAR-STRUCTURE | multiple bonding | transition metals | DIBORENE | CHEMISTRY, MULTIDISCIPLINARY | boronboron bonds | AMINE-BORANE | REDUCTION | boron-centered ligands | BORYLENE TRANSFER | THERMAL CONDITIONS | CHEMISTRY | boron | RADICAL-ANION
Journal Article
Chemical Science, ISSN 2041-6520, 01/2018, Volume 9, Issue 24, pp. 5354 - 5359
B≡N and B≡B triple bonds induce C–H activation of acetone to yield a (2-propenyloxy)aminoborane and an unsymmetrical 1-(2-propenyloxy)-2-hydrodiborene,... 
Chemical bonds | Activation | Mathematical analysis | Bonding | Acetone
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2015, Volume 137, Issue 5, pp. 1766 - 1769
Diborynes, molecules containing homo­atomic boron–boron triple bonds, have been investigated by Raman spectroscopy in order to determine the stretching... 
RAMAN-SPECTRA | SPECTROSCOPY | COMPOUND | IDENTIFICATION | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | BULKY | Models, Molecular | Spectrum Analysis, Raman | Boron - chemistry | Molecular Conformation | Raman spectroscopy | Usage
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2011, Volume 50, Issue 12, pp. 2778 - 2782
Hooray for hydroboration! The products afforded by the title reaction depend on the substitution pattern on the double bond moiety of 1,3‐enyne substrates (see... 
copper | asymmetric catalysis | hydroboration | enynes | boron | ROOM-TEMPERATURE | DIELS-ALDER REACTIONS | ALLYLIC CARBONATES | EFFICIENT ROUTE | STEREOSPECIFIC SYNTHESIS | NICKEL(II) CHLORIDE | CHEMISTRY, MULTIDISCIPLINARY | ORGANOBORANES | MONOHYDROBORATION | DIBORON
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 10/2018, Volume 57, Issue 43, pp. 14060 - 14064
The discovery of homodinuclear multiple bonds composed of Group13 elements represents one of the most challenging frontiers in modern chemistry. A classical... 
photoelectron spectroscopy | ACTIVATION | HETEROCYCLIC CARBENE | BORON | MOLECULE | AB-INITIO | COMPOUND | abinitio calculations | CHEMISTRY, MULTIDISCIPLINARY | COMPLIANCE CONSTANTS | FORCE | gas-phase clusters | double electronic transmutation | AlAl triple bonds | MULTIPLE BONDS | GALLIUM
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 05/2018, Volume 57, Issue 21, pp. 6109 - 6114
The reaction of highly Lewis acidic tetra(o-tolyl) diborane(4) with CO afforded a mixture of boraindane and boroxine by the cleavage of the C O triple bond.... 
triple bonds | IRIDIUM-CATALYZED BORYLATION | ORGANOBORON COMPOUNDS | ORGANODIBORANE COMPOUNDS | bond cleavage | carbon monoxide | diborane | UNSYMMETRICAL DIBORANE | CHEMISTRY, MULTIDISCIPLINARY | isocyanide | BORON-COMPOUNDS | MULTICOMPONENT REACTIONS | CARBON-MONOXIDE | DIBORON TETRACHLORIDE | TERT-BUTYLAZADIBORIRIDINE | LEWIS PAIR TEMPLATES
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 06/2018, Volume 9, Issue 24, pp. 5354 - 5359
B N and B?B triple bonds induce C-H activation of acetone to yield a (2-propenyloxy)aminoborane and an unsymmetrical 1-(2-propenyloxy)-2-hydrodiborene,... 
AMINO-IMINO-BORANES | BORON | ORGANYL | CHEMISTRY | REACTIVITY | ADDUCTS | MULTIPLE BONDS | IMINOBORANES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Science, ISSN 0036-8075, 4/2010, Volume 328, Issue 5976, pp. 345 - 347
Monomeric oxoboranes have hitherto been detected only as short-lived species in gas-phase or low-temperature matrix experiments. Here, we report formation of... 
Spectroscopy | Boron | Oxygen | Platinum | Atoms | Bromides | Ligands | Infrared radiation | Reports | Chemical bonding | Ellipsoids | INFRARED-SPECTRA | SOLID ARGON | HBO | MOLECULE | MULTIDISCIPLINARY SCIENCES | REACTIVITY | INTERMEDIATE | BORANES | MATRIX-ISOLATION | IMINOBORYL COMPLEXES | Oxides | Platinum compounds | Chemical properties | Chemical bonds | Molecular chemistry | Chemical compounds
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 07/2017, Volume 23, Issue 41, pp. 9746 - 9751
The electronic structure of (eta(5)-Cp)(2)Zr( NH2-BBNH2) (3b) suggests that it could be a candidate for having a boron-boron triple bond in the cyclic system;... 
CARBENE | COMPLEXES | CIS-CONFIGURATION | REACTIVITY | DIBORENE | URANIUM METALLACYCLOCUMULENE | CHEMISTRY, MULTIDISCIPLINARY | 1-ZIRCONACYCLOPENT-3-YNE | donor-acceptor systems | GROUP-4 METALS | BORYL ANION | B-B triple bond | MULTIPLE BONDS | boron | EDA-NOCV | metallacycles
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2017, Volume 23, Issue 41, pp. 9746 - 9751
The electronic structure of (η5‐Cp)2Zr(NH2‐BB‐NH2) (3 b) suggests that it could be a candidate for having a boron–boron triple bond in the cyclic system;... 
donor–acceptor systems | B-B triple bond | boron | EDA-NOCV | metallacycles
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 08/2019, Volume 10, Issue 31, pp. 7375 - 7378
A set of diboryldiborenes are prepared by the mild, catalyst-free, room-temperature diboration of the B-B triple bonds of doubly base-stabilized diborynes. Two... 
HYDROBORATION | BORON | SINGLE | REACTIVITY | CHEMISTRY | CARBORANES | BORANES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical science, ISSN 2041-6520, 08/2019, Volume 10, Issue 31, pp. 7375 - 7378
A set of diboryldiborenes are prepared by the mild, catalyst-free, room-temperature diboration of the B-B triple bonds of doubly base-stabilized diborynes. Two... 
Journal Article