X
Search Filters
Format Format
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
chemistry, multidisciplinary (85) 85
boron (83) 83
reactivity (68) 68
chemistry (50) 50
chemistry, inorganic & nuclear (40) 40
boryl anion (33) 33
complexes (32) 32
anions (31) 31
anion (26) 26
boryllithium (26) 26
chemistry, organic (20) 20
bor (19) 19
boryl complexes (19) 19
ligands (19) 19
boranes (18) 18
carbenes (16) 16
ligand (16) 16
oxidative addition (15) 15
reduction (15) 15
boryl (13) 13
boryl anions (13) 13
catalysis (13) 13
transition-metal-boryl (13) 13
n-heterocyclic carbenes (12) 12
activation (11) 11
crystal-structure (11) 11
organic chemistry (11) 11
structural-characterization (11) 11
transition-metal-complexes (11) 11
umpolung (11) 11
carben (10) 10
chemical properties (10) 10
electrons (10) 10
functionalization (10) 10
gallium (10) 10
molecular structure (10) 10
substitution (10) 10
adducts (9) 9
alpha,beta-unsaturated carbonyl-compounds (9) 9
boryl radicals (9) 9
derivatives (9) 9
iron (9) 9
molecular-structures (9) 9
nucleophilic boron (9) 9
platinum (9) 9
radicals (9) 9
bonding (8) 8
cations (8) 8
copper boryl complexes (8) 8
generation (8) 8
halides (8) 8
hydroboration (8) 8
hydrogen (8) 8
lithium (8) 8
transition metals (8) 8
aluminum (7) 7
analysis (7) 7
borane (7) 7
chemical bonds (7) 7
chemisches reaktionsvermögen (7) 7
chemistry, physical (7) 7
coordination (7) 7
diborane (7) 7
elektron (7) 7
form (7) 7
magnesium (7) 7
nucleophiles (7) 7
chemical tests and reagents (6) 6
homolytic reactions (6) 6
mathematical analysis (6) 6
organic-synthesis (6) 6
reagents (6) 6
synthesis (6) 6
alkenes (5) 5
alkynes (5) 5
allylic carbonates (5) 5
beta-boration (5) 5
bond (5) 5
bond-dissociation energies (5) 5
boron compounds (5) 5
boryl ligands (5) 5
carbon-monoxide (5) 5
crystal-structures (5) 5
crystallography (5) 5
density (5) 5
density functional theory (5) 5
deprotonation (5) 5
diboration (5) 5
electron-spin-resonance (5) 5
halogenid (5) 5
halogenides (5) 5
heterocyclic compounds (5) 5
lewis acid (5) 5
main-group elements (5) 5
molecular-structure (5) 5
nucleophilic substitution (5) 5
phosphorus (5) 5
research (5) 5
salts (5) 5
spectroscopy (5) 5
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 46, pp. 15272 - 15275
...‐2‐ylidene) yields a hydride‐shift isomer of the corresponding tetrahydrodiborane, a further reversible reduction leads to the first stable parent boryl anion, [(CAACMe)BH2... 
cyclic (alkyl)(amino)carbene | nucleophilic boron | diborane | boryl anion | reduction | BORON | BORYLENE | cyclic (alkyl)(amino) carbene | REACTIVITY | BORANE | CHEMISTRY, MULTIDISCIPLINARY | Chemical tests and reagents | Boron | Reduction | Anions
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 20, pp. 5885 - 5887
...‐heterocyclic indyl anion [In(NONAr)]−, which crystallizes with a non‐contacted [K([2.2.2]crypt)]+ cation. The indyl anion can also be isolated as the indyllithium compound... 
indyl anions | indium | main-group chemistry | diindanes | N-heterocyclic carbenes | BISMUTH COMPOUNDS | COMPLEXES | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | ALUMINUM | BORYL ANION | INDIUM-INDIUM | BOND | GALLIUM | Density functionals | Indium | Specific gravity | Heterocyclic compounds | Reduction | Anions | Sodium | Lithium | Density functional theory | Carbenes | Potassium
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2007, Volume 46, Issue 12, pp. 1946 - 1948
...‐workers have obtained the first three‐coordinate boryl anion (see formula), which provides an unprecedented and synthetically highly useful source for a nucleophilic... 
organoboranes | boryl compounds | boron | Boron | Boryl compounds | Organoboranes | SUBSTITUTION | TRANSITION-METAL-COMPLEXES | HYDROBORATIONS | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | ALUMINUM | CARBENE ANALOGS | CHEMISTRY | LIGAND | GALLIUM
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 2018, Volume 47, Issue 3, pp. 734 - 741
The reactions of 1-bora-7a-azaindenide anions, prepared in moderate to excellent yields by reduction of the appropriate 1-bora-7a-azaindenyl chlorides with KC in THF, with alkyl halides and carbon dioxide were studied... 
BN ISOSTERES | BORYL ANION | BORON | ANALOGS | C-C | CHEMISTRY | FRUSTRATED LEWIS PAIRS | PHOTOPHYSICAL PROPERTIES | AROMATIC-SUBSTITUTION REACTIONS | MOLECULES | CHEMISTRY, INORGANIC & NUCLEAR | Carboxylation | Boron | Anions | Halides | Alkylation | Carbon dioxide
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 10, pp. 2795 - 2799
The first deprotonation of a borohydride anion was achieved by treatment of [BH(CN)3]− with strong non‐nucleophilic bases, which resulted in the formation of alkali... 
cyanoborates | borohydrides | boron-centered nucleophiles | carboxyborates | umpolung | BORON | CYANOBOROHYDRIDE | REACTIVITY | CHEMISTRY | BORYL ANIONS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | Chemical tests and reagents | Boron | Salts | Anions | Ketones | Alkali metals | Reagents | Carbon dioxide
Journal Article
Nature, ISSN 0028-0836, 04/2010, Volume 464, Issue 7292, pp. 1136 - 1137
... describe their preparation of a borole anion. The compound takes part in a surprising chemical reaction, and might open up routes to the preparation of other borole... 
BORYL ANION | PENTAARYLBOROLES | MULTIDISCIPLINARY SCIENCES | REACTIVITY | GENERATION | BORANES | BORYLLITHIUM | Anions
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2014, Volume 53, Issue 24, pp. 6259 - 6262
Treatment of toluene or p‐xylene with diaminoboryllithium results in consecutive reactions, involving boryl‐anion... 
methylated benzenes | diaminoboryl anions | basicity | hydrogen | boryllithium | ENERGY | POLARIZABLE CONTINUUM MODEL | HYDROCARBONS | FORM | CHEMISTRY, MULTIDISCIPLINARY | DENSITY | EXCHANGE | TETRAHYDROFURAN | BORYL COMPLEXES | ACIDITY
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2019, Volume 58, Issue 34, pp. 11806 - 11810
...+ cation, as judged by UV/Vis spectroscopy and DFT calculations. The lithium salt of the dianion reacted as two equivalents of a diarylboryl anion with CH2Cl2 or S8 to give boryl... 
boryl anions | diborane dianions | nucleophilic substitution | boron | ACTIVATION | INSECT PHEROMONES | ANALOG | BORONIC ESTERS | DIBORENE | CHEMISTRY, MULTIDISCIPLINARY | DIBORANE | REDUCTION | CHEMISTRY | HOMOLOGATION | ACCESS | Spectroscopy | Diborane | Salts | Anions | Equivalence | Dichloromethane | Molecular orbitals | Lithium | Magnesium | Methylene chloride
Journal Article
Angewandte Chemie (International ed.), ISSN 1521-3773, 2020, Volume 59, Issue 20, pp. 7726 - 7731
The tetraaryl μ‐hydridodiborane(4) anion [2H]− possesses nucleophilic B−B and B−H bonds. Treatment of K[2H] with the electrophilic 9... 
Umpolung | nucleophilic B−B bonds | organoboron clusters | boryl anions | cycloaddition reactions | Propylene | Boron | Anions | Hydroboration | Substitution reactions | Dienes | Room temperature | Communications | Communication
Journal Article
Chemical communications (Cambridge, England), ISSN 1364-548X, 2018, Volume 54, Issue 11, pp. 1291 - 1302
Journal Article
Catalysis Communications, ISSN 1566-7367, 11/2016, Volume 86, pp. 133 - 138
A series of potential metathesis catalyst based on Hoveyda-Grubbs ruthenium system with the N-heterocyclic carbene replaced by N-heterocyclic carbene boryl anion were investigated using the M06... 
Density functional | Catalysis | Boryl anions | Metathesis | N-heterocyclic carbenes | Chemicals
Journal Article
Nature chemistry, ISSN 1755-4349, 2019, Volume 12, Issue 1, pp. 36 - 39
Aluminium anions with an unoccupied orbital are generally considered as highly difficult synthetic targets, as aluminium is the most electropositive element in the p block... 
DEPROTONATION | BORON | REDUCTION | ANALOG | CHEMISTRY | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | BORYL | Potassium salts | Anions | Electronic structure | Aluminum | Benzene | P elements | X-ray diffraction | Visible spectrum | Density functional theory | Lewis base | Basicity | Electropositivity
Journal Article