X
Search Filters
Format Format
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
chemistry, multidisciplinary (64) 64
boron (49) 49
reactivity (45) 45
boryl radicals (33) 33
chemistry (26) 26
chemistry, organic (25) 25
complexes (23) 23
radicals (23) 23
homolytic reactions (19) 19
bor (18) 18
ligated boranes (17) 17
anions (16) 16
boryl anion (15) 15
carbenes (15) 15
reduction (15) 15
n-heterocyclic carbenes (14) 14
anion (13) 13
boranes (13) 13
chemistry, inorganic & nuclear (13) 13
electron-spin-resonance (13) 13
index medicus (13) 13
hydrogen-atom abstraction (12) 12
borane (11) 11
organic chemistry (11) 11
organic-synthesis (11) 11
catalysis (10) 10
electrons (10) 10
alkenes (9) 9
bond-dissociation energies (9) 9
boryllithium (9) 9
generation (9) 9
hydrogen (9) 9
ligand (9) 9
ligands (9) 9
activation (8) 8
amine-boryl radicals (8) 8
carben (8) 8
cations (8) 8
chemical properties (8) 8
chemistry, physical (8) 8
derivatives (8) 8
elektron (8) 8
lithium (8) 8
bond (7) 7
boryl (7) 7
boryl complexes (7) 7
electron-spin resonance (7) 7
gallium (7) 7
hydroboration (7) 7
research (7) 7
umpolung (7) 7
aluminum (6) 6
boryl anions (6) 6
carbon (6) 6
chemical sciences (6) 6
chemisches reaktionsvermögen (6) 6
halides (6) 6
main-group elements (6) 6
molecular structure (6) 6
nucleophiles (6) 6
organoboron compounds (6) 6
usage (6) 6
alkynes (5) 5
chemical tests and reagents (5) 5
coordination (5) 5
coupling reactions (5) 5
density (5) 5
diborane (5) 5
esters (5) 5
heterocyclic carbene-boranes (5) 5
initiators (5) 5
mathematical analysis (5) 5
oxidative addition (5) 5
polymerization (5) 5
substitution-reactions (5) 5
absolute rate constants (4) 4
alkyl (4) 4
alkyl amino carbenes (4) 4
analysis (4) 4
bonds (4) 4
boronic esters (4) 4
catalysts (4) 4
chemical synthesis (4) 4
chemical-radical (4) 4
chemisches radikal (4) 4
crystal-structure (4) 4
crystal-structures (4) 4
form (4) 4
frustrated lewis pairs (4) 4
halogenid (4) 4
heterocyclic carbene boranes (4) 4
heterocyclic compounds (4) 4
hydrogen-atom donors (4) 4
indium (4) 4
kation (4) 4
lewis base (4) 4
multiple bonds (4) 4
nitrogen (4) 4
nucleophilic substitution (4) 4
oxidation (4) 4
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


Coordination Chemistry Reviews, ISSN 0010-8545, 12/2017, Volume 352, pp. 346 - 378
[Display omitted] •Synthesis and property of boron-containing radicals are outlined.•Anionic, neutral, and cationic species are sequentially described.•The 11B... 
Main group chemistry | Radical | Boron | CARBENE | ACTIVATION | SINGLE-ELECTRON-TRANSFER | VALENCY PROBLEM | ANION | BORYL RADICALS | REACTIVITY | FRUSTRATED LEWIS PAIRS | CHEMISTRY, INORGANIC & NUCLEAR | CHEMISTRY | CATION | Superconductors | Surface active agents | Hydrogen | Polymerization | Density functionals | Chemical properties | Metallocenes | Sensors
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2015, Volume 54, Issue 1, pp. 359 - 362
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2017, Volume 56, Issue 4, pp. 1135 - 1140
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2014, Volume 53, Issue 28, pp. 7360 - 7363
Utilizing a cyclic (alkyl)(amino)carbene (CAAC) as a ligand, neutral CAAC‐stabilized radicals containing a boryl functionality could be prepared by reduction... 
carbenes | structure elucidation | radicals | reduction | boron | ELECTRON SIGMA-BOND | ANION | BORYL RADICALS | DIBORENES | REACTIVITY | COORDINATION | BORANES | CHEMISTRY, MULTIDISCIPLINARY | REDUCTIONS | ALKYL AMINO CARBENES | GENERATION | Reduction | Boron | Mathematical analysis | X-rays | Inert | Derivatives | Density | Radicals | Adducts
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2015, Volume 54, Issue 32, pp. 9198 - 9202
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2016, Volume 55, Issue 30, pp. 8736 - 8739
High‐level ab initio calculations show that the formation of radicals, by the homolytic bond fission of Y−R (Y=F, OH, NH2; R=CH3, NH2, OH, F, SiH3, PH2, SH,... 
beryllium | spontaneous radical formation | ab initio calculations | gas-phase reactions | noncovalent interactions | BORYL RADICALS | COMPLEXES | HYDROGEN-ATOM DONORS | COOPERATIVITY | DISSOCIATION ENERGIES | BORANE | CHEMISTRY, MULTIDISCIPLINARY | Bonds | Beryllium
Journal Article
Synthesis, ISSN 0039-7881, 08/2017, Volume 49, Issue 16, pp. 3511 - 3534
Abstract Heteroatom-centered radicals show versatile reactivity and offer useful synthetic methods in organic chemistry. The development of new approaches for... 
review | radicals | cascade reaction | radical reaction | catalysis | C-H functionalization | cyclization | heteroatoms | HETEROCYCLIC CARBENE-BORANES | METAL-FREE CONDITIONS | HYDROXAMIC ACIDS | BORYL RADICALS | CHEMISTRY, ORGANIC | N-HYDROXYPHTHALIMIDE | C-H BONDS | VISIBLE-LIGHT | COUPLED ELECTRON-TRANSFER | SILYL ENOL ETHERS | TERT-BUTYL NITRITE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2010, Volume 132, Issue 7, pp. 2350 - 2358
N-Heterocyclic carbene boranes (NHC−boranes) are a new “clean” class of reagents suitable for reductive radical chain transformations. Their structures are... 
ELECTRON-SPIN-RESONANCE | HOMOLYTIC REACTIONS | GALLIUM-HYDRIDE | HYDROGEN-ATOM ABSTRACTION | TERT-BUTYL RADICALS | ALKYL | LIGATED BORANES | BORYL RADICALS | ABSOLUTE RATE CONSTANTS | CHEMISTRY, MULTIDISCIPLINARY | BIMOLECULAR SELF-REACTION | Borane | Usage | Electron paramagnetic resonance spectroscopy | Olefins | Chemical properties | Structure | Carbenes
Journal Article
Synthesis, ISSN 0039-7881, 09/2018, Volume 50, Issue 18, pp. 3671 - 3678
Abstract Two new P-stabilized boryl radicals [Ph 2 P(naph)BAr] (Ar = Tip and Ter) have been prepared and characterized by electron paramagnetic resonance... 
feature | boryl radicals | m -terphenyl | radicals | Gomberg-type dimerization | X-ray diffraction | boron | EPR spectroscopy | phosphorus | CARBENE | m-terphenyl | REACTIVITY | CHEMISTRY, ORGANIC | SALTS | HEXAPHENYLETHANE | REDUCTION | BONDS | CHEMISTRY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2016, Volume 55, Issue 9, pp. 3166 - 3170
A visible‐light‐mediated in situ generation of a boron‐centered carboranyl radical (o‐C2B10H11.) has been described. With eosin Y as a photoredox catalyst,... 
radicals | carborane | photocatalysis | heterocycles | arylation | ELECTRON-SPIN-RESONANCE | ORGANIC-MOLECULES | DIAZONIUM SALTS | BORYL RADICALS | COMPLEXES | REACTIVITY | N-HETEROCYCLIC CARBENES | SUBSTITUTION-REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | CHEMISTRY | DERIVATIVES | Substitution reactions | Catalysis | Boron | Catalysts | Aromatic compounds | Photocatalysis | Metals | Carborane | Coupling | Light effects
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2011, Volume 133, Issue 26, pp. 10312 - 10321
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2017, Volume 139, Issue 17, pp. 6050 - 6053
A synthetic method to construct boron-handled cyclic molecules was developed based on a radical borylation/cyclization cascade of 1,6-enynes. The process was... 
ORGANIC-SYNTHESIS | HYDROGEN | HYDROBORATION | CARBENE-BORYL RADICALS | RATE CONSTANTS | PHOTOPOLYMERIZATIONS | SUBSTITUTION-REACTIONS | BORANES | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | POLARITY-REVERSAL CATALYSIS | Usage | Chemical properties | Ring formation (Chemistry) | Chemical synthesis | Carbenes
Journal Article
The Journal of Physical Chemistry A, ISSN 1089-5639, 06/2018, Volume 122, Issue 24, pp. 5464 - 5476
Computational studies on five-membered heterocycles with single heteroatom and their isomeric dehydro-borole 1a–1c, cyclopentadiene 2a–2c, pyrrole 3a–3c, furan... 
TRACELESS DIRECTING GROUPS | CHEMICAL-SHIFTS NICS | BOND-DISSOCIATION ENERGIES | CORRELATED MOLECULAR CALCULATIONS | BORYL RADICALS | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | STABILIZATION ENERGY | DENSITY-FUNCTIONAL THEORY | THERMAL-DECOMPOSITION | GAUSSIAN-BASIS SETS | ELECTRONIC-STRUCTURE
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2014, Volume 20, Issue 6, pp. 1630 - 1637
Boryl radicals have the potential for the development of new molecular entities and for application in new radical reactions. However, the effects of the... 
boryl radicals | substituent effects | synergistic effects | boron | Lewis bases | spin density | SPIN-RESONANCE | COORDINATION | N-HETEROCYCLIC CARBENES | BORANE | CHEMISTRY, MULTIDISCIPLINARY | Pyridine | Boron | Electronic structure | Stabilization | Synergistic effect | Lewis base | Carbon | Density | Radicals
Journal Article