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bromine trifluoride (65) 65
bromine (48) 48
chemistry, organic (48) 48
chemistry (46) 46
chemistry, inorganic & nuclear (33) 33
fluorine (30) 30
bromine fluorides (22) 22
fluorides (22) 22
fluorination (18) 18
temperature (12) 12
chlorine (11) 11
derivatives (11) 11
iodine (10) 10
measured values (10) 10
organic chemistry (10) 10
anions (9) 9
bromination (9) 9
chemical reactions (9) 9
chemistry, multidisciplinary (9) 9
complexes (9) 9
nmr spectroscopy (9) 9
ethers (8) 8
oxidation (8) 8
synthesis (8) 8
iodine pentafluoride (7) 7
molecules (7) 7
acids (6) 6
brf3 (6) 6
brom (6) 6
chemical engineering (6) 6
crystals (6) 6
gases (6) 6
index medicus (6) 6
liquids (6) 6
mixing (6) 6
reagents (6) 6
trifluoride (6) 6
uranium hexafluoride (6) 6
water (6) 6
calorimetry (5) 5
crystal structure (5) 5
crystal-structures (5) 5
elemental fluorine (5) 5
halides (5) 5
inorganic chemistry (5) 5
ions (5) 5
molecular structure (5) 5
pressure (5) 5
quantity ratio (5) 5
salts (5) 5
structure (5) 5
trifluoromethyl ethers (5) 5
acyl fluorides (4) 4
analysis (4) 4
bromine compounds - chemistry (4) 4
carbonyl (4) 4
catalyst (4) 4
chemistry, physical (4) 4
chromatography (4) 4
decomposition (4) 4
diarylbromonium salts (4) 4
diffraction (4) 4
fluorine compounds (4) 4
fluorine compounds - chemistry (4) 4
fluorohalogenates (4) 4
halogens (4) 4
hypervalent (4) 4
impurities (4) 4
ionic liquids (4) 4
low temperature (4) 4
molecular-structure (4) 4
oxides (4) 4
oxygen (4) 4
quantitative analysis (4) 4
quantum chemistry (4) 4
raman spectroscopy (4) 4
reaction kinetics (4) 4
reactivity (4) 4
rearrangement (4) 4
separation processes (4) 4
spectra (4) 4
spectrometry (4) 4
tetrafluorobromates (4) 4
trifluoromethyl (4) 4
uranium (4) 4
absorption (3) 3
alpha-trifluoromethylation (3) 3
anion (3) 3
antimony (3) 3
aromatic compounds (3) 3
bromine - chemistry (3) 3
bromine compounds (3) 3
bromine monofluoride (3) 3
bromine pentafluoride (3) 3
carbonyl-compounds (3) 3
cations (3) 3
chemical properties (3) 3
chemical synthesis (3) 3
chemistry, analytical (3) 3
chlorides (3) 3
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1. Full Text Synthesis and characterization of the pyridine—bromine trifluoride (1/1) complex, [py∙BrF3]
by Ivlev, Sergei I and Buchner, Magnus R and Karttunen, Antti J and Kraus, Florian
Journal of Fluorine Chemistry, ISSN 0022-1139, 11/2018, Volume 215, pp. 17 - 24
The pyridine—bromine trifluoride (1/1) complex was synthesized and characterized. It crystallizes in the monoclinic space group 2/ with  = 6.9044(9),  =... 
Bromine | fluoride | Pyridine | DFT | Complex | Crystal structure | BRF3 | MOLECULAR-STRUCTURE | REACTIVITY | CHEMISTRY, ORGANIC | CHEMISTRY, INORGANIC & NUCLEAR | VIBRATIONAL FREQUENCIES | FLUORIDE CRYSTAL-STRUCTURES | Alkaloids | Hydrogen | Crystals | Nuclear magnetic resonance spectroscopy | Fluorides | Structure | Pyridines | Molecular structure | Quantum chemistry | Vapor phases | Chemical compounds | Hydrogen bonding | Magnetic resonance spectroscopy | Organic chemistry | Hydrogen bonds | Mathematical analysis | Chemical synthesis | NMR spectroscopy | Quantum theory | Hydrogen ion concentration | Conformation
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2. Full Text Assignment of Raman spectra for trifluoride anions in solid argon
by Andrews, Lester and Wang, Xuefeng
Physical Chemistry Chemical Physics, ISSN 1463-9076, 9/2018, Volume 2, Issue 36, pp. 23378 - 23385
Cesium fluoride evaporated from a small stainless steel Knudsen cell at 495 °C was codeposited with F 2 in excess argon onto a copper wedge at 15 K and... 
BROMINE | POLYFLUORIDE ANIONS | COUNTERPARTS | COMPLEXES | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | FLUORINE | ION | VIBRATIONAL-SPECTRA | MATRIX-ISOLATION | THEORETICAL INVESTIGATIONS | MOLECULES | Raman spectra | Photosensitivity | Argon ions | Infrared absorption | Ions | Cesium | Reaction products | Luminous intensity | Anions | Cesium fluorides | Ionization | Lasers | Argon | Codeposition | Stretching
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3. Full Text Selective Reactions of Bromine Trifluoride in Organic Chemistry
by Rozen, Shlomo
Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2010, Volume 352, Issue 16, pp. 2691 - 2707
Although known for more than a century, bromine trifluoride is not a common reagent in day to day research work in organic chemistry. Its tendency to react... 
bromine trifluoride | trifluoromethyl species | naked fluoride | difluoromethylene species | fluorine | HALOGEN FLUORIDES | NUCLEOPHILIC TRIFLUOROMETHYLATION | ALPHA-TRIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | KETENE DITHIOACETALS | PERMUTATIONAL ISOMERIZATION | TRIFLUOROMETHYL ETHERS | ELEMENTAL FLUORINE | SYNTHETIC APPLICATIONS | CHEMISTRY, APPLIED | OXIDATIVE DESULFURIZATION-FLUORINATION | Bromine | Organic chemistry | Solvents | Exothermic reactions | Anesthetics | Ethers | Lewis base | Acetone
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4. Full Text From Alkyl Halides to Alkyltrifluoromethyls Using Bromine Trifluoride
by Hagooly, Aviv and Ben-David, Iris and Rozen, Shlomo
The Journal of Organic Chemistry, ISSN 0022-3263, 11/2002, Volume 67, Issue 24, pp. 8430 - 8434
Under the right conditions, bromine trifluoride can be a useful tool for generating new types of reactions and compounds. Thus, tris(methylthio)alkyl... 
CHEMISTRY | CHEMISTRY, ORGANIC | FLUORINE | BRF3 | SPECTROMETRY | Bromine | Chemistry, Organic | Research | Fluorides | Chemical tests and reagents | Halides
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5. Full Text Contributions to the chemistry of bromine trifluoride part 3. Electronic influences on the fluorine—aryl substitution reaction of bromine trifluoride with monosubstituted phenyltrifluorosilanes
by Frohn, H.J and Giesen, M
Journal of Fluorine Chemistry, ISSN 0022-1139, 1998, Volume 89, Issue 1, pp. 59 - 63
BrF3 reacts with monosubstituted phenyltrifluorosilanes X-C6H4SiF3 (X = H, p-Me, p-MeO, m-F, p-F, m-CF3, p-CF3) in equimolar reactions (CH2Cl2/MeCN solution,... 
Diarylbromonium salts | Fluorine—aryl substitution | Arylbromine dichloride | Bromine trifluoride | IR spectrometry | Arylbromine difluorides | NMR spectrometry | Iodine pentafluoride | Fluorine-aryl substitution | iodine pentafluoride | arylbromine difluorides | CHEMISTRY, ORGANIC | bromine trifluoride | arylbromine dichloride | fluorine-aryl substitution | diarylbromonium salts | CHEMISTRY, INORGANIC & NUCLEAR
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6. Full Text Sorption and desorption of BrF 3 on NaF: Studies on thermodynamics and kinetics
by Zherin, I.I and Rudnikov, A.I and Ostvald, R.V and Sobolev, V.I and Amelina, G.N
Journal of Fluorine Chemistry, ISSN 0022-1139, 05/2019, Volume 221, pp. 25 - 33
Temperature dependence of bromine trifluoride vapor pressure over its adduct with sodium fluoride has been determined; the adduct normal dissociation... 
Sorption | Bromine trifluoride | Desorption | Uranium hexafluoride | Iodine pentafluoride | Sodium fluoride
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7. Full Text Application of bromine trifluoride for pre-concentration and determination of rare-earth elements in fuel uranium dioxide
by Mitkin, V.N and Shavinsky, B.M
Journal of Fluorine Chemistry, ISSN 0022-1139, 2009, Volume 130, Issue 1, pp. 117 - 121
Radioactive indicator's ( Eu) method was used to study the behavior of rare-earth element (REE) micro-impurities at fluorination of fuel UO with bromine... 
Atomic emission spectral analysis | Method of radioactive indicators | Uranium matrix removal | Bromine trifluoride | Rare-earth elements pre-concentration | Fuel uranium dioxide | THORIUM | CHEMISTRY, ORGANIC | ANION-EXCHANGE | SEPARATION | CHEMISTRY, INORGANIC & NUCLEAR | Uranium ores | Radioactive tracers | Uranium | Fluorides
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8. Full Text Synthesis of Pentafluoroethyl Ethers by Silver-Mediated Oxidative Pentafluoroethylation of Alcohols and Phenols
by Fu, Mao-Lin and Liu, Jian-Bo and Xu, Xiu-Hua and Qing, Feng-Ling
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2017, Volume 82, Issue 7, pp. 3702 - 3709
A silver triflate (AgOTf)-mediated oxidative pentafluoroethylation of alcohols and phenols with nucleophilic (pentafluoroethyl)­trimethylsilane (TMSCF2CF3)... 
TRIFLUOROMETHYL ETHERS | COMPLEXES | CHEMISTRY | CHEMISTRY, ORGANIC | ALPHA-FLUORINATED ETHERS | SUBSTITUENT CONSTANTS | ARYL | PERFLUOROALKOXIDES | BROMINE TRIFLUORIDE | DERIVATIVES | THIOETHERS
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9. Full Text Borosilicate Activation of (Difluoroiodo)toluene in the gem‐Difluorination of Phenyldiazoacetate Derivatives
by Sinclair, Geoffrey S and Tran, Richard and Tao, Jason and Hopkins, W. Scott and Murphy, Graham K
European Journal of Organic Chemistry, ISSN 1434-193X, 09/2016, Volume 2016, Issue 27, pp. 4603 - 4606
A combined experimental and computational investigation was conducted to identify a mild and effective Lewis‐acidic activator for TolIF2 in the... 
Diazo compounds | Computational chemistry | Fluorine | Hypervalent compounds | Iodine | REAGENTS | ADAMANTANES | CHEMISTRY, ORGANIC | IODINE PENTAFLUORIDE | LEWIS ACIDITY | REARRANGEMENT | DIFLUORIDES | CHEMISTRY | FLUORINE-COMPOUNDS | BROMINE TRIFLUORIDE | SULFUR-TETRAFLUORIDE | Toluene
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10. Full Text Reactivity of alkali and alkaline earth metal tetrafluorobromates towards aromatic compounds and pyridine
by Sobolev, Vasily I and Filimonov, Victor D and Ostvald, Roman V and Radchenko, Vyacheslav B and Zherin, Ivan I
Journal of Fluorine Chemistry, ISSN 0022-1139, 12/2016, Volume 192, pp. 120 - 123
The bromination activity of tetrafluorobromates of alkali and alkali-earth metals increases in the order KBrF , CsBrF , RbBrF and Ba(BrF ) . The most active... 
Tetrafluorobromates | Arenes | Bromine trifluoride | Bromination | Fluorine | BRF3 | CHEMISTRY, ORGANIC | CATALYST | CHEMISTRY, INORGANIC & NUCLEAR | Pyridine
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11. Full Text [C(4)MPyr](2)[Br-20]: Ionic-Liquid-Based Synthesis of a Three-Dimensional Polybromide Network
by Wolff, M and Meyer, J and Feldmann, C
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 2011, Volume 50, Issue 21, pp. 4970 - 4973
GASES | COMPLEX | DIBROMINE | bromine | CRYSTAL-STRUCTURES | INITIO | TRIFLUORIDE ANION F-3(-) | SALTS | CHEMISTRY, MULTIDISCIPLINARY | PHASE | polyhalides | POLYIODIDE | ionic liquids | structure elucidation
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12. Full Text Recent Discoveries of Polyhalogen Anions – from Bromine to Fluorine
by Haller, Heike and Riedel, Sebastian
Zeitschrift für anorganische und allgemeine Chemie, ISSN 0044-2313, 06/2014, Volume 640, Issue 7, pp. 1281 - 1291
In this review we discuss the recent discoveries in polyhalide anion chemistry with the main focus on polybromide, ‐chloride, and ‐fluoride anions. Based on... 
Bromine | Interhalides | Halogen chemistry | Fluorine | Polyhalides | RAMAN-SPECTRA | VIBRATIONAL SPECTRA | POLYBROMIDE ANIONS | TRIFLUORIDE ANION | CRYSTAL-STRUCTURES | TETRAETHYLAMMONIUM TRICHLORIDE | SOLID-STATE | CHEMISTRY, INORGANIC & NUCLEAR | GAS-PHASE | IONIC LIQUIDS | MATRIX-ISOLATION
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13. Full Text Sorption and desorption of BrF3 on NaF: Studies on thermodynamics and kinetics
by Zherin, I.I and Rudnikov, A.I and Ostvald, R.V and Sobolev, V.I and Amelina, G.N
Journal of Fluorine Chemistry, ISSN 0022-1139, 05/2019, Volume 221, pp. 25 - 33
Temperature dependence of bromine trifluoride vapor pressure over its adduct with sodium fluoride has been determined; the adduct normal dissociation... 
Sorption | Uranium hexafluoride | Desorption | Iodine pentafluoride | Sodium fluoride | Bromine trifluoride | SODIUM-FLUORIDE | ALKALI | CHEMISTRY, ORGANIC | TETRAFLUOROBROMATES(III) | CHEMISTRY, INORGANIC & NUCLEAR
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14. Full Text Preparation of alkyl and aryl chlorodifluoromethyl ethers using BrF 3
by Hagooly, Youlia and Sasson, Revital and Welch, Michael J and Rozen, Shlomo
European Journal of Organic Chemistry, ISSN 1434-193X, 06/2008, Issue 17, pp. 2875 - 2880
Chlorothioformates | Chlorodifluoromethyl ethers | Bromine trifluoride | Fluorination
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15. Full Text Selective fluorination and separation of metals with NF3 for mass spectrometry
by Clark, Richard A and Clark, Richard A and Barinaga, Charles J and Barinaga, Charles J and McNamara, Bruce K and McNamara, Bruce K and Schwantes, Jon M and Schwantes, Jon M and Ballou, Nathan E and Ballou, Nathan E and Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Journal of Radioanalytical and Nuclear Chemistry, ISSN 0236-5731, 3/2016, Volume 307, Issue 3, pp. 1587 - 1590
We report recent progress on the development of a new methodology based on the generation of volatile metal fluorides through the use of nitrogen trifluoride... 
Chemistry | Nuclear Physics, Heavy Ions, Hadrons | Diagnostic Radiology | Physical Chemistry | Nuclear forensics | Inorganic Chemistry | Fluorination | Mass spectrometry | Nuclear Chemistry | Nitrogen trifluoride | U3O8 | DIFLUORIDE | CHEMISTRY, ANALYTICAL | ENVIRONMENTAL-SAMPLES | FLUORIDES | HEXAFLUORIDE | CHEMISTRY, INORGANIC & NUCLEAR | URANIUM TETRAFLUORIDE | NUCLEAR SCIENCE & TECHNOLOGY | OXIDES | THERMAL NF3 | BROMINE TRIFLUORIDE | TEMPERATURE FLUORINATION | Nuclear Forensics | Mass Spectrometry | Nitrogen Trifluoride
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16. Full Text The Interhalogen Cations [Br2F5]+ and [Br3F8]
by Ivlev, Sergei I and Karttunen, Antti J and Buchner, Magnus R and Conrad, Matthias and Kraus, Florian
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2018, Volume 57, Issue 44, pp. 14640 - 14644
The synthesis and characterization of unique polyhalogen cations containing μ‐bridging fluorine atoms are reported. The [Br2F5]+ cation features a symmetric... 
bromine trifluoride | structure elucidation | antimony pentafluoride | fluoronium ions | heteropolyhalogen cations | SYSTEM | ANIONS | COMPLEXES | BASIS-SETS | FLUORIDE CRYSTAL-STRUCTURES | CHEMISTRY, MULTIDISCIPLINARY | Nuclear magnetic resonance spectroscopy | Fluorides | Chemical properties | Analysis | Magnetic resonance spectroscopy | Organic chemistry | Salts | Quantum chemistry | Fluorine | X-ray diffraction | Cations | NMR spectroscopy
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17. Full Text Synthesis and Characterization of [Br3][MF6] (M=Sb, Ir), as well as Quantum Chemical Study of [Br3]+ Structure, Chemical Bonding, and Relativistic Effects Compared with [XBr2]+ (X=Br, I, At, Ts) and [TsZ2]+ (Z=F, Cl, Br, I, At, Ts)
by Ivlev, Sergei I and Gaul, Konstantin and Chen, Mengyi and Karttunen, Antti J and Berger, Robert and Kraus, Florian
Chemistry – A European Journal, ISSN 0947-6539, 04/2019, Volume 25, Issue 22, pp. 5793 - 5802
[Br3][SbF6] and [Br3][IrF6] were synthesized by interaction of BrF3 with Sb2O3 or iridium metal, respectively. The former compound crystallizes in the... 
density functional calculations | bromine trifluoride | antimony | tribromonium | crystal structures | X-RAY CRYSTALLOGRAPHY | IONIC-LIQUID | ELECTRONIC-STRUCTURE CALCULATIONS | VIBRATIONAL-SPECTRA | FORCE-CONSTANTS | CHEMISTRY, MULTIDISCIPLINARY | RAMAN-SPECTRUM | PEROXYDISULFURYL DIFLUORIDE | FLUORIDE CRYSTAL-STRUCTURES | MATRIX-ISOLATION | Fluorides | Comparative analysis | Structure | Crystals | Organic chemistry | Anions | Quantum chemistry | Mathematical analysis | Relativism | Chemical bonds | Cations | Iridium | Relativistic effects
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18. Full Text Attaching the fluorine atom to organic molecules using BrF3 and other reagents directly derived from F-2
by Rozen, S
ACCOUNTS OF CHEMICAL RESEARCH, ISSN 0001-4842, 10/2005, Volume 38, Issue 10, pp. 803 - 812
Elemental fluorine is a starting point for nucteophflic fluorinations (e.g., BrF3), radical fluorinations (e.g., F-2 under irradiation), and electrophilic... 
ETHERS | ALPHA-TRIFLUOROMETHYLATION | ACIDS | ELEMENTAL FLUORINE | SELECTIVE FLUORINATION | CHEMISTRY | ACETYL HYPOFLUORITE | BROMINE TRIFLUORIDE | CHEMISTRY, MULTIDISCIPLINARY | GENERAL-METHOD | ALKYL-HALIDES
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19. Full Text F‐bridged Anions of Bromine and Gold: Predictions of Unexpected Behavior
by Linnera, Jarno and Ivlev, Sergei I and Kraus, Florian and Karttunen, Antti J
Zeitschrift für anorganische und allgemeine Chemie, ISSN 0044-2313, 02/2019, Volume 645, Issue 3, pp. 284 - 291
The significant similarity between MF3, MF4–, and M2F7– (M = Au, Br) is studied using quantum chemical methods. It is expected that compounds containing... 
Bromine | Gold | Thermodynamics | Density functional calculations | Fluorine | MOLECULAR-STRUCTURE | CRYSTAL-STRUCTURE | COMPLEXES | SILVER | TRIFLUORIDE | TETRAFLUOROBROMATES(III) | FLUORIDES | CHEMISTRY, INORGANIC & NUCLEAR | DIFFRACTION
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