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by Jiao, YH and Chiou, MF and Li, YJ and Bao, HL
ACS CATALYSIS, ISSN 2155-5435, 06/2019, Volume 9, Issue 6, pp. 5191 - 5197
A copper-catalyzed radical acyl-cyanation of alkenes with aldehydes, employing TBHP as an initiator, has been developed and is reported in this study.... 
OXIDATION | beta-Me scission | ACYLATION | copper-catalyzed | CHEMISTRY, PHYSICAL | PHOTOCHEMICAL ADDITION | acyl-cyanation | tert-butoxy radical | ALCOHOLS | TBHP | DFT calculation | ACTIVATED ALKENES | C-C BOND | VICINAL DIFUNCTIONALIZATION | H BONDS | METAL-FREE | CYCLIZATION
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 06/2005, Volume 70, Issue 12, pp. 4629 - 4636
[GRAPHICS] 1,2-Dideuterio-cyclohexene, 1,2-dideuterio-cyclooctene, and trans-3,4-dideuterio-hex-3-ene were reacted with three > NO. radicals: 4-hydroxyTempo,... 
LASER FLASH-PHOTOLYSIS | HYDROGEN ABSTRACTION | ALKANE OXIDATION | CHEMISTRY, ORGANIC | AEROBIC OXIDATION | OXYL | T-BUTOXY RADICALS | O-H BOND | ACETIC-ACID | MOLECULAR-OXYGEN | BENZYL ALCOHOLS | Chemical properties | Olefins | Amino compounds | Cyclohexane
Journal Article
Polymer Journal, ISSN 0032-3896, 09/2010, Volume 42, Issue 9, pp. 716 - 721
Allyl monomers polymerize with difficulty and their polymerization yields polymers of medium molecular weight or oligomers. Matrix-assisted laser... 
methyl radical | alkoxy radical | MALDI-TOF-MS | initiation | allyl polymerization | organic peroxide initiator | POLYMER SCIENCE | MECHANISMS | ACETATE | TERT-BUTOXY RADICALS | OLIGOMERS | Oligomers | Methyl radicals | Organic peroxides | Initiators | Ionization | Polymerization | High temperature | Radicals
Journal Article
Journal Article
International Journal of Chemical Kinetics, ISSN 0538-8066, 09/2016, Volume 48, Issue 9, pp. 544 - 555
Presented here are computed rates for the thermal unimolecular decomposition of a variety of alkoxy radicals with four- and five-carbon length backbones. Three... 
OXIDATION | TEMPERATURE | BUTOXY RADICALS | KINETICS | RATE CONSTANTS | SET MODEL CHEMISTRY | CHEMISTRY, PHYSICAL | TORSIONAL ANHARMONICITY | ENTROPIES | ENERGIES | CHEMISTRY PROGRAM PACKAGE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2008, Volume 130, Issue 49, pp. 16572 - 16584
A comprehensive study of the ketone-photoinduced formation of gold nanoparticles (AuNPs) from gold ions in aqueous and micellar solution has been carried out.... 
LASER FLASH-PHOTOLYSIS | HYDROGEN ABSTRACTION | CONFORMATIONAL MOBILITY | COLLOIDAL GOLD | XANTHONE | NANOCRYSTALS | DIFFERENT SHAPES | ARYL KETONE | ALKYL KETONES | CHEMISTRY, MULTIDISCIPLINARY | TERT-BUTOXY RADICALS
Journal Article
Progress in Polymer Science, ISSN 0079-6700, 2002, Volume 27, Issue 6, pp. 1007 - 1038
Journal Article
Organic Letters, ISSN 1523-7060, 08/2010, Volume 12, Issue 16, pp. 3654 - 3657
A kinetic study of the H-atom abstraction reactions from 1,4-cyclohexadiene and triethylamine by the cumyloxyl radical has been carried out in different... 
CENTERED RADICALS | OXYGEN | ELECTRON-SPIN-RESONANCE | BETA-SCISSION | ARYLCARBINYLOXYL RADICALS | ATOM ABSTRACTIONS | REACTIVITY | CHEMISTRY, ORGANIC | ALKOXYL RADICALS | ABSOLUTE RATE CONSTANTS | TERT-BUTOXY RADICALS
Journal Article
Physical Chemistry Chemical Physics, ISSN 1463-9076, 11/2003, Volume 5, Issue 21, pp. 4828 - 4833
Thermochemical and kinetic parameters for 1,5-H isomerisation reactions of alkoxy radicals up to C-8 have been determined theoretically using density... 
NORMAL-BUTANE | CONSTANTS | SMOG | DETAILED MECHANISM | O-2 | BUTOXY RADICALS | ATMOSPHERIC CONDITIONS | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | THERMAL UNIMOLECULAR DECOMPOSITION | PHOTO-OXIDATION
Journal Article
Macromolecules, ISSN 0024-9297, 01/2014, Volume 47, Issue 2, pp. 544 - 551
Hydrogen atom abstraction from a series of homopolymers by cumyloxy radicals is examined under solvent-free conditions at temperatures that are relevant to... 
POLYMER SCIENCE | MOLECULAR-WEIGHT | ABSTRACTION REACTIONS | POLYPROPYLENE | GRAFT-COPOLYMERIZATION | CROSS-LINKING | POLYMERIZATION | ABSOLUTE RATE CONSTANTS | T-BUTOXY RADICALS | DICUMYL PEROXIDE | THERMAL-OXIDATION
Journal Article
Journal of Physical Chemistry A, ISSN 1089-5639, 01/2011, Volume 115, Issue 3, pp. 274 - 279
Alkoxy radicals are important intermediates in the formation of tropospheric ozone. The spectroscopic identification and characterization of these species are... 
ALKOXY RADICALS | O-2 | RINGS | RESOLVED ELECTRONIC-SPECTRA | NONRADIATIVE DECAY | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY | CHEMISTRY, PHYSICAL | BUTOXY | FLUORESCENCE EXCITATION-SPECTRA | CONFORMERS | VOLATILE ORGANIC-COMPOUNDS | Density functionals | Usage | Chemical properties | Spectrum analysis | Cyclohexane | Electric properties
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 09/2006, Volume 12, Issue 27, pp. 7084 - 7094
Persistent noncyclic phosphoranyl radicals have been prepared and observed by electron paramagnetic resonance (EPR) for the first time. They were obtained by... 
ELECTRON-SPIN-RESONANCE | BIS(TRIMETHYLSILYL) PEROXIDE | BETA-SCISSION | phosphoranyl radicals | ESR | radical reactions | REACTIVITY | reactive intermediates | TRIVALENT PHOSPHORUS | CHEMISTRY, MULTIDISCIPLINARY | TERT-BUTOXY RADICALS | LASER FLASH-PHOTOLYSIS | electron paramagnetic resonance | kinetics | ORGANOPHOSPHORUS COMPOUNDS | PHOSPHITES
Journal Article
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, ISSN 0538-8066, 04/2006, Volume 38, Issue 4, pp. 250 - 275
Rate coefficients for alkyl and alkoxy radical decomposition are important in combustion, biological, and atmospheric processes. In this paper, rate constant... 
METHYL RADICALS | ARRHENIUS PARAMETERS | MERCURY-PHOTOSENSITIZED DECOMPOSITION | HYDROGEN-ATOMS | BUTOXY RADICALS | T-BUTYL PEROXIDE | GAS-PHASE | CHEMISTRY, PHYSICAL | EVALUATED KINETIC DATA | THERMAL UNIMOLECULAR DECOMPOSITION | PHASE TROPOSPHERIC CHEMISTRY
Journal Article
Synlett, ISSN 0936-5214, 03/2016, Volume 27, Issue 5, pp. 741 - 744
Abstract Aryl halides are reduced into the corresponding arenes in high yields, using 2-propanol, cesium carbonate, and di- tert -butyl peroxide (or di- tert... 
cluster | anion radical | reduction | radical chain mechanism | ketyl | tert-butoxy radical | IODIDES | LITHIUM ALUMINUM-HYDRIDE | INDUCED DEIODINATION | DEHALOGENATION | CHEMISTRY, ORGANIC
Journal Article
Journal of Physical Chemistry A, ISSN 1089-5639, 03/2012, Volume 116, Issue 12, pp. 3156 - 3162
Journal Article
Organic Letters, ISSN 1523-7060, 12/2001, Volume 3, Issue 25, pp. 4059 - 4062
[GRAPHICS] Several lactones were examined to test the reactivity of carbon-centered radicals toward oxygen. Notably, the radical derived from 2-coumaranone (4)... 
RESONANCE | PHENOLS | RATE CONSTANTS | CHEMISTRY, ORGANIC | BIS(BENZOFURANONES) | TERT-BUTOXY RADICALS | LASER PHOTOLYSIS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2014, Volume 136, Issue 6, pp. 2555 - 2563
Journal Article
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