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Organic Letters, ISSN 1523-7060, 11/2016, Volume 18, Issue 21, pp. 5520 - 5523
Lithiation reactions of tertiary benzylic esters and carbamates have been studied. Kinetic methodology revealed that a two-step reaction pathway should be... 
SEC-BUTYLLITHIUM | ALPHA-OXY-ORGANOLITHIUM | MECHANISM | AB-INITIO | CHEMISTRY, ORGANIC | DYNAMIC-BEHAVIOR | HIGH-FIELD | N-BUTYLLITHIUM | IR SPECTROSCOPY | LI-6 NMR | AGGREGATION
Journal Article
Macromolecules, ISSN 0024-9297, 02/2015, Volume 48, Issue 3, pp. 610 - 628
Diphenylethylene (DPE) is a monomer which has attracted significant interest from both academia and industry. DPE can undergo (co)polymerization by living... 
1,1-DIPHENYLETHYLENE | HYPERMACS | POLYMER SCIENCE | HYPERBRANCHED POLYMERS | AMINE-FUNCTIONALIZED POLYSTYRENES | LABELED POLYSTYRENE | SELECTIVE RADICAL-ADDITION | N-BUTYLLITHIUM | STYRENE | POLYCONDENSATION | RAFT POLYMERIZATION
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 03/2019, Volume 58, Issue 12, pp. 3819 - 3823
Heterasumanenes 4-6 containing chalcogen (S, Se, and Te) and phosphorus atoms have been synthesized in a onepot reaction from trichalcogenasumanenes 1-3 by... 
DESIGN | phosphole | BUCKYBOWLS | HYDROCARBONS | CHEMISTRY, MULTIDISCIPLINARY | TRICHALCOGENASUMANENE | MOLECULES | heterasumanene | sensors | FLUORESCENCE | CHEMISTRY | BUTYLLITHIUM | silver | chalcogens | BOWL | PI-CONJUGATED SYSTEMS
Journal Article
Russian Journal of General Chemistry, ISSN 1070-3632, 10/2016, Volume 86, Issue 10, pp. 2307 - 2311
The reaction of gem-dichloro- and gem-dibromocyclopropanes with n-butyllithium in THF under argon at–78°С followed by purging the reaction mixture with dry CO2... 
2-substituted 1-halocyclopropanecarboxylic acids | gem -dihalocyclopropanes | Chemistry | Chemistry/Food Science, general | 1-halo-1-lithiocyclopropanes | n -butyllithium | carboxylation | salt effect | n-butyllithium | gem-dihalocyclopropanes | CYCLOPROPANATION | CHEMISTRY, MULTIDISCIPLINARY | Chemical tests and reagents | Organic acids | Lithium compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2014, Volume 136, Issue 8, pp. 3246 - 3255
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 03/2015, Volume 51, Issue 25, pp. 5452 - 5455
1-Lithio-2-butyl-1,2-dihydropyridines, typically formed as intermediates in the nucleophilic substitution (addition/elimination) of pyridine with (n- or... 
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 03/2019, Volume 48, Issue 9, pp. 2948 - 2952
The reactivity of the sterically demanding triazene Dmp-N?N-N(H)-Dmp (Dmp(2)N(3)H, Dmp = 2,6-bis(2,4,6-trimethylphenyl)phenyl) with alkali metal bases and... 
AMIDINATE | MOLECULAR-STRUCTURES | X-RAY | CHEMISTRY | CRYSTAL-STRUCTURES | BUTYLLITHIUM | LIGAND | POTASSIUM | LITHIUM | DERIVATIVES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 12/2010, Volume 39, Issue 46, pp. 11129 - 11131
Reaction of pyridine with well defined magnesium hydride species results in heterocycle dearomatisation by a hydride transfer which occurs with the formation... 
COMPLEXES | BETA-DIKETIMINATE LIGAND | BUTYLLITHIUM | SYSTEMS | METAL | ADDUCT | N-HETEROCYCLES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2007, Volume 48, Issue 38, pp. 6648 - 6650
Asymmetric intramolecular cyclization of aminoalkenes was catalyzed by a catalytic amount of n-butyllithium, diisopropylamine, and a newly designed chiral... 
ROUTE | LITHIUM AMIDES | ENANTIOSELECTIVE SYNTHESIS | AMINES | ALKENE HYDROAMINATION | CHEMISTRY, ORGANIC | OLEFINS | BUTYLLITHIUM | 1,4-ADDITION | CONJUGATE ADDITION | PROTONATION
Journal Article
Macromolecular Chemistry and Physics, ISSN 1022-1352, 01/2018, Volume 219, Issue 1
Anionic polymerization of a novel [alpha]-methylstyrene derivative para-substituted with a bulky and rigid adamantyl group,... 
Surface active agents | Polymerization | Depolymerization | Tetrahydrofuran | Anionic polymerization | Glass transition temperature | Butyllithium
Journal Article
Chemical Communications, ISSN 1359-7345, 2009, Issue 37, pp. 5558 - 5560
tert-Butyllithium deprotonates bis(3-methyl-1,3-diazacyclohex-1-yl)-methane and its five-ring analogue regioselectively at both endocyclic NCH2N units; a... 
DEPROTONATION | BUTYLLITHIUM | COMPLEX | TMEDA | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2016, Volume 22, Issue 33, pp. 11477 - 11477
Invited for the cover of this issue is the group of P. Merino at the University of Zaragoza. The image depicts the central role of the lithium ion, the... 
Oxazoles | Schiff bases | Usage | Lithium | Catalysis | Chemical synthesis | Conversion | Butyllithium | Water chemistry | Synthesis | Catalysts | Images | Texts
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2007, Volume 46, Issue 24, pp. 4566 - 4569
A commonly used deprotonation agent is the combination of n‐butyllithium and N,N,N′,N′′,N′′‐pentamethyldiethylenetriamine (PMDTA). The highly reactive... 
N ligands | aggregation | lithiation | alkyllithium compounds | butyllithium | Aggregation | Alkyllithium compounds | Lithiation | Butyllithium | MOLECULAR-STRUCTURE | BUILDING-BLOCKS | COMPOUND | COMPLEXES | CRYSTAL-STRUCTURES | TMEDA | ALKYL-LITHIUM | CHEMISTRY, MULTIDISCIPLINARY | BENZYLLITHIUM | N-BUTYLLITHIUM | METHYLLITHIUM
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 2, pp. 324 - 327
After isolating an unusual binuclear, but monosolvated NaHMDS complex [{(R,R)-TMCDA}center dot(NaHMDS)(2)](infinity) which polymerises via intermolecular... 
ASYMMETRIC CATALYSIS | DIISOPROPYLAMIDE | DONOR | BROMINE-LITHIUM EXCHANGE | COMPLEXES | CRYSTAL-STRUCTURES | N-BUTYLLITHIUM | TMEDA | LIGAND | HEXAMETHYLDISILAZIDES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2019, Volume 58, Issue 12, pp. 4027 - 4030
Flash chemistry based on flow microreactor systems allowed alkyllithiums bearing electrophilic functional groups to be successfully generated and used for... 
lithium | nucleophilic addition | microreactors | synthetic methods | flow chemistry | REACTORS | ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | TEMPERATURE | INTEGRATION | ETHER | BUTYLLITHIUM | GENERATION | TETRAHYDROFURAN | Organic chemistry | Functional groups | Bearing
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 03/2013, Volume 78, Issue 6, pp. 2726 - 2730
The novel selective synthesis of symmetrical and unsymmetrical dithienoheteroaromatic rings (DTHAs) has been developed via intramolecular cyclization of... 
DITHIENOSILOLE | SENSITIZED SOLAR-CELLS | CYCLOPENTADITHIOPHENE | REAGENTS | STABILITY | POLYMER | SILICON | CHEMISTRY, ORGANIC | N-BUTYLLITHIUM | FIELD-EFFECT TRANSISTORS | TERT-BUTYLLITHIUM | Measurement | Diffraction | Analysis | X-rays | Ring formation (Chemistry) | Chemical properties | Structure | Lithium compounds | Surface energy | Methods
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 03/2017, Volume 82, Issue 6, pp. 2843 - 2854
Kinetic studies are a suitable tool to disclose the role of tiny reagent fractions. The title compound 2 reacted in a kinetic reaction order of 0.5 (square... 
REAGENTS | MECHANISM | MICROSOLVATION | EQUILIBRIUM | REACTIVITY | CHEMISTRY, ORGANIC | BUTYLLITHIUM | RINMR | LEWIS-BASE COMPLEXATION | SP-STEREOINVERSION | AGGREGATION | Ketones | Chemical properties
Journal Article
Organic Letters, ISSN 1523-7060, 10/2010, Volume 12, Issue 20, pp. 4600 - 4603
Employing a chiral oxazoline as an ortholithiation directing group allows the synthesis of inherently chiral calix[4]arenes suitable for elaboration into... 
MECHANISM | BEHAVIOR | LITHIUM DIISOPROPYLAMIDE | COMPLEXES | HEXAMETHYLPHOSPHORAMIDE HMPA | CHEMISTRY, ORGANIC | BUTYLLITHIUM | LITHIATION | DIMERS | SOLVENT
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 14, pp. 5925 - 5928
Reactions between magnesium 1,4-dihydropyridide or 1,2-dihydroiso-quinolide derivatives and carbodiimides, RN=C=NR, generally result in Mg-N insertion and... 
BUTYLLITHIUM-PYRIDINE ADDUCT | REDUCTION | HETEROCYCLES | HYDROSILYLATION | DECOMPOSITION | CHEMISTRY | BIS(PYRIDINE) COMPLEX | DEAROMATIZATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Tetrahedron, ISSN 0040-4020, 08/2018, Volume 74, Issue 33, pp. 4445 - 4455
The structures of α-lithiated vinyl ethers were explored on the basis of a combined computational and NMR study. Calculations (M06/6-31 + G(d)) on free... 
Lithium | NMR | Synthesis | Aggregate | Computational | ORGANIC-SYNTHESIS | ENOL ETHERS | BUILDING-BLOCKS | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | LITHIUM DIALKYLAMIDES | GAS-PHASE | DYNAMIC-BEHAVIOR | N-BUTYLLITHIUM | NMR-SPECTROSCOPY DOSY | CONJUGATE ADDITION
Journal Article
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