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1. Full Text Synthesis, solvatochromism, aggregation-induced emission and cell imaging of tetraphenylethene-containing BODIPY derivatives with large Stokes shifts
by Hu, Rongrong and Gómez-Durán, C. F. Azael and Lam, Jacky W. Y and Belmonte-Vázquez, José L and Deng, Chunmei and Chen, Sijie and Ye, Ruquan and Peña-Cabrera, Eduardo and Zhong, Yongchun and Wong, Kam Sing and Tang, Ben Zhong
Chemical Communications, ISSN 1359-7345, 10/2012, Volume 48, Issue 81, pp. 10099 - 10101
A series of tetraphenylethene-containing BODIPYs with emissions from visible to near-IR and large Stokes shifts up to 142 nm have been designed and... 
FLUORESCENCE | CHEMISTRY, MULTIDISCIPLINARY | DESIGN | Fluorescent Dyes - chemical synthesis | Benzene Derivatives - chemical synthesis | Humans | Fluorescent Dyes - analysis | Luminescence | Ethylenes - analysis | Models, Molecular | Ethylenes - chemical synthesis | Benzene Derivatives - analysis | Boron Compounds - analysis | Boron Compounds - chemical synthesis | HeLa Cells | Microscopy, Fluorescence
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2. Full Text Silver-mediated oxidative C-H/P-H functionalization: An efficient route for the synthesis of benzo[b]phosphole oxides
by Chen, Yun-Rong and Duan, Wei-Liang
Journal of the American Chemical Society, ISSN 0002-7863, 11/2013, Volume 135, Issue 45, pp. 16754 - 16757
A Ag-mediated C-H/P-H functionalization reaction of arylphosphine oxides with internal alkynes was described for the direct preparation of benzo[b]phosphole... 
ACTIVATION | O BOND | MANGANESE(III) ACETATE | DIALKYL PHOSPHITES | INTRAMOLECULAR RADICAL TRANSFER | N BOND FORMATION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | ARYL ENAMINES | INDOLES | DEHYDROGENATIVE CYCLIZATION | Oxides - chemical synthesis | Phosphines - chemical synthesis | Benzene Derivatives - chemical synthesis | Phosphines - chemistry | Oxidation-Reduction | Oxides - chemistry | Silver - chemistry | Benzene Derivatives - chemistry | Silver | Oxides | Chemical properties | Research | Chemical synthesis
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3. Full Text Palladium(III)-catalyzed fluorination of arylboronic acid derivatives
by Mazzotti, Anthony R and Campbell, Michael G and Tang, Pingping and Murphy, Jennifer M and Ritter, Tobias
Journal of the American Chemical Society, ISSN 0002-7863, 09/2013, Volume 135, Issue 38, pp. 14012 - 14015
A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is presented. The reaction is operationally simple and amenable... 
PALLADIUM | COPPER-MEDIATED FLUORINATION | ELECTROPHILIC FLUORINATION | C-H FLUORINATION | CONVERSION | DEOXYFLUORINATION | BOND FORMATION | PD(III) COMPLEXES | ARYL FLUORIDES | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | Benzene Derivatives - chemical synthesis | Palladium | Catalysis | Boronic Acids - chemical synthesis | Fluorine - chemistry | Halogenation | Thermal properties | Chemical reaction, Rate of | Analysis | Chemical properties | Electron transport | Methods
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4. Full Text Catalytic and highly regioselective cross-coupling of aromatic C-H substrates
by Hull, Kami L and Sanford, Melanie S
Journal of the American Chemical Society, ISSN 0002-7863, 10/2007, Volume 129, Issue 39, pp. 11904 - 11905
This communication describes a new Pd-catalyzed reaction for the highly chemo- and regioselective oxidative cross-coupling of aromatic C-H bonds. This... 
OXIDATION | MECHANISM | BOND FORMATION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE ARENES | BORYLATION | Benzene Derivatives - chemical synthesis | Oxidation-Reduction | Pyrazoles - chemical synthesis | Pyridines - chemistry | Pyrimidines - chemical synthesis | Quinolines - chemistry | Pyridines - chemical synthesis | Heterocyclic Compounds - chemical synthesis | Pyrimidines - chemistry | Quinolines - chemical synthesis | Pyrazoles - chemistry | Heterocyclic Compounds - chemistry | Catalysis | Benzene Derivatives - chemistry | Palladium - chemistry | Palladium | Chemical properties | Hydrogen | Carbon compounds | Electric properties
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5. Full Text Synthesis, characterization, and theory of [9]-, [12]-, and [18]Cycloparaphenylene: Carbon nanohoop structures
by Jasti, Ramesh and Bhattacharjee, Joydeep and Neaton, Jeffrey B and Bertozzi, Carolyn R
Journal of the American Chemical Society, ISSN 0002-7863, 12/2008, Volume 130, Issue 52, pp. 17646 - 17647
The first synthesis and characterization of [9]-, (12]-, and [18]cycloparaphenylene was demonstrated utilizing a novel aromatization reaction. We refer to... 
ETHERS | 3,6-DIMETHOXY-3,6-DIMETHYLCYCLOHEXA-1,4-DIENE | ARYLATION | REACTIVITY | BELTS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | Thermodynamics | Benzene Derivatives - chemical synthesis | Macrocyclic Compounds - chemistry | Nanotubes, Carbon - chemistry | Models, Molecular | Spectrometry, Fluorescence | Benzene Derivatives - chemistry | Macrocyclic Compounds - chemical synthesis | Solvation | Chemical properties | Analysis | Nanotubes | Communication
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6. Full Text Palladium-catalyzed C(sp3)-H arylation of diarylmethanes at room temperature: Synthesis of triarylmethanes via deprotonative-cross-coupling processes
by Zhang, Jiadi and Bellomo, Ana and Creamer, Andrea D and Dreher, Spencer D and Walsh, Patrick J
Journal of the American Chemical Society, ISSN 0002-7863, 08/2012, Volume 134, Issue 33, pp. 13765 - 13772
Although metal-catalyzed direct arylation reactions of non- or weakly acidic C-H bonds have recently received much attention, chemists have relied heavily on... 
C-H BOND | PRACTICAL SYNTHESIS | FRIEDEL-CRAFTS REACTIONS | ARYL HALIDES | DIARYLCARBENIUM ION POOLS | EQUILIBRIUM ACIDITIES | CARBON-HYDROGEN BONDS | AROMATIC-ALDEHYDES | ELECTRON-RICH ARENES | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | Protons | Benzene Derivatives - chemical synthesis | Bromides - chemical synthesis | Bromides - chemistry | Catalysis | Benzene Derivatives - chemistry | Benzhydryl Compounds - chemical synthesis | Palladium - chemistry | Benzhydryl Compounds - chemistry | Methane | Palladium catalysts | Arylation | Analysis | Bromides | Chemical properties
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7. Full Text Selective synthesis of [7]- and [8]cycloparaphenylenes
by Sibbel, Friederike and Matsui, Katsuma and Segawa, Yasutomo and Studer, Armido and Itami, Kenichiro
Chemical communications (Cambridge, England), ISSN 1359-7345, 01/2014, Volume 50, Issue 8, pp. 954 - 956
Cycloparaphenylenes (CPPs) are a remarkable class of hoop-shaped conjugated macrocycles with inimitable properties. Herein we describe a divergent synthesis of... 
Crystallography, X-Ray | Benzene Derivatives - chemical synthesis | Macrocyclic Compounds - chemistry | Benzene Derivatives - chemistry | Macrocyclic Compounds - chemical synthesis | Molecular Conformation
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8. Full Text Selective syntheses of [7]-[12]cycloparaphenylenes using orthogonal Suzuki-Miyaura cross-coupling reactions
by Darzi, Evan R and Sisto, Thomas J and Jasti, Ramesh
Journal of Organic Chemistry, ISSN 0022-3263, 08/2012, Volume 77, Issue 15, pp. 6624 - 6628
The divergent, selective syntheses of [7]-[12]cycloparaphenylenes have been accomplished utilizing sequential, orthogonal Suzuki-Miyaura cross-coupling... 
CARBON NANORINGS | CHEMISTRY, ORGANIC | STEP | Benzene Derivatives - chemistry | Benzene Derivatives - chemical synthesis | Molecular Structure | Chemical bonds | Analysis | Ring formation (Chemistry)
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9. Full Text Ureido-substituted benzenesulfonamides potently inhibit carbonic anhydrase IX and show antimetastatic activity in a model of breast cancer metastasis
by Pacchiano, Fabio and Carta, Fabrizio and McDonald, Paul C and Lou, Yuanmei and Vullo, Daniela and Scozzafava, Andrea and Dedhar, Shoukat and Supuran, Claudiu T
Journal of Medicinal Chemistry, ISSN 0022-2623, 03/2011, Volume 54, Issue 6, pp. 1896 - 1902
A series of ureido-substituted benzenesulfonamides was prepared that showed a very interesting profile for the inhibition of several human carbonic anhydrases... 
CA-IX | CHEMISTRY, MEDICINAL | CRYSTAL-STRUCTURE | CATALYTIC DOMAIN | INTRACELLULAR PH | TUMOR | SULFONAMIDES | ISOZYME I | HYPOXIA | EXPRESSION | DERIVATIVES | Benzene Derivatives - chemical synthesis | Antineoplastic Agents - chemical synthesis | Humans | Structure-Activity Relationship | Nitrobenzenes - pharmacology | Urea - chemical synthesis | Carbonic Anhydrases - metabolism | Neoplasm Metastasis | Isoenzymes - metabolism | Urea - analogs & derivatives | Mammary Neoplasms, Experimental - pathology | Antigens, Neoplasm - metabolism | Female | Antineoplastic Agents - pharmacology | Benzene Derivatives - pharmacology | Carbonic Anhydrase IX | Catalytic Domain | Models, Molecular | Nitrobenzenes - chemical synthesis | Sulfonamides - pharmacology | Sulfonamides - chemical synthesis | Animals | Protein Binding | Mice | Isoenzymes - antagonists & inhibitors | Urea - pharmacology
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10. Full Text Rhodium(III)-catalyzed C-C coupling of arenes with 2-vinyloxiranes: Synthesis of allylic alcohols
by Yu, Songjie and Li, Xingwei
Organic Letters, ISSN 1523-7060, 02/2014, Volume 16, Issue 4, pp. 1200 - 1203
A rhodium(III)-catalyzed C-C coupling between 2-vinyloxiranes and arenes directed by different chelating groups has been realized via a C-H activation Rh(III),... 
ALKENES | ACTIVATION | ORGANOCOPPER REAGENTS | H OLEFINATION | VERSATILE | CHEMISTRY, ORGANIC | BOND FORMATION | CARBON-CARBON | CLEAVAGE | ALKYNES | CYCLIZATION | Alkenes - chemistry | Propanols - chemistry | Benzene Derivatives - chemical synthesis | Molecular Structure | Catalysis | Benzene Derivatives - chemistry | Propanols - chemical synthesis | Rhodium - chemistry
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11. Full Text Tris(triazolo)benzene and its derivatives: High-density energetic materials
by Thottempudi, Venugopal and Forohor, Farhad and Parrish, Damon A and Shreeve, Jean'Ne M
Angewandte Chemie - International Edition, ISSN 1433-7851, 09/2012, Volume 51, Issue 39, pp. 9881 - 9885
High-performance explosives: Tris(triazolo)benzene was synthesized and converted to its trinitro and trichloro derivatives (see scheme; R=NO(2), Cl). The heats... 
triazoles | nitrogen-rich compounds | energetic materials | detonation properties | CHEMISTRY | IONIC LIQUIDS | SALTS | CHEMISTRY, MULTIDISCIPLINARY | DETONATIONS | Benzene Derivatives - chemical synthesis | Triazoles - chemistry | Explosive Agents - chemical synthesis | Explosive Agents - chemistry | Models, Molecular | Crystallography, X-Ray | Triazoles - chemical synthesis | Hot Temperature | Benzene Derivatives - chemistry | Detonation | High density | Mathematical analysis | Energetic materials | Explosives | Derivatives | Density | Heat of formation | Thermal stability
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12. Full Text Enantioselective copper-catalyzed construction of aryl pyrroloindolines via an arylation-cyclization cascade
by Zhu, Shaolin and MacMillan, David W. C
Journal of the American Chemical Society, ISSN 0002-7863, 07/2012, Volume 134, Issue 26, pp. 10815 - 10818
An enantioselective arylation-cyclization cascade has been accomplished using a combination of diaryliodonium salts and asymmetric copper catalysis. These mild... 
EPIDITHIODIOXOPIPERAZINES | MICHAEL | CONCISE TOTAL-SYNTHESIS | ONE-POT SYNTHESIS | ALPHA-ARYLATION | HODGKINSINE-B | CYCLOTRYPTAMINE ALKALOIDS | COMPLEXES | H BOND ARYLATION | DIARYLIODONIUM SALTS | CHEMISTRY, MULTIDISCIPLINARY | Benzene Derivatives - chemical synthesis | Copper - chemistry | Pyrroles - chemical synthesis | Cyclization | Indoles - chemical synthesis | Alkaloids - chemical synthesis | Catalysis | Onium Compounds - chemistry | Arylation | Usage | Analysis | Pyrrole | Chemical properties | Ring formation (Chemistry) | Copper
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13. Full Text Copper-catalyzed aerobic oxidative functionalization of an arene C-H bond: Evidence for an aryl-copper(III) intermediate
by King, Amanda E and Huffman, Lauren M and Casitas, Alicia and Costas, Miquel and Ribas, Xavi and Stahl, Shannon S
Journal of the American Chemical Society, ISSN 0002-7863, 09/2010, Volume 132, Issue 34, pp. 12068 - 12073
Recent studies have highlighted the ability of Cu-II to catalyze the aerobic oxidative functionalization of C-H bonds; however, very little is known about the... 
CUPRIC ACETATE | CROSS-COUPLING REACTIONS | ACTIVATION | OXIDASE | ARYLATION | COMPLEXES | AMIDATION | TERMINAL ALKYNES | ARYL | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | Benzene Derivatives - chemical synthesis | Oxidation-Reduction | Stereoisomerism | Heterocyclic Compounds - chemical synthesis | Copper - chemistry | Heterocyclic Compounds - chemistry | Organometallic Compounds - chemical synthesis | Oxygen - chemistry | Organometallic Compounds - chemistry | Molecular Structure | Catalysis | Kinetics | Benzene Derivatives - chemistry | Usage | Organocuprates | Analysis | Spectrum analysis | Oxidation-reduction reaction | Chemical properties | Structure
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14. Full Text Discovery of an α-Amino C-H Arylation Reaction Using the Strategy of Accelerated Serendipity
by Andrew McNally and Christopher K. Prier and David W. C. MacMillan
Science, ISSN 0036-8075, 11/2011, Volume 334, Issue 6059, pp. 1114 - 1117
Serendipity has long been a welcome yet elusive phenomenon in the advancement of chemistry. We sought to exploit serendipity as a means of rapidly identifying... 
Serendipity | Pharmaceutical preparations | Amines | Catalysts | REPORTS | Chemical reactions | Catalysis | Pharmaceutical chemistry | Functional groups | Chemicals | COORDINATION-COMPOUNDS | CATION RADICALS | CHEMICAL-REACTIONS | DEPROTONATION | PHOTOINDUCED ELECTRON-TRANSFER | MULTIDISCIPLINARY SCIENCES | TRANSFER PET | ALIPHATIC-AMINES | BOND ACTIVATION | GENERATION | PHOTOCHEMICAL-REACTIONS | Amines - chemistry | Benzene Derivatives - chemical synthesis | Gas Chromatography-Mass Spectrometry | Oxidation-Reduction | Organic Chemistry Phenomena | Amines - chemical synthesis | Hydrogen - chemistry | Carbon - chemistry | Photochemical Processes | High-Throughput Screening Assays | Amination | Heterocyclic Compounds - chemistry | Benzene Derivatives - chemistry
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15. Full Text Stereoselective synthesis and antifungal activities of (E)-α- (methoxyimino)benzeneacetate derivatives containing 1,3,5-substituted pyrazole ring
by Li, Yan and Zhang, Hong-Quan and Liu, Jie and Yang, Xiang-Ping and Liu, Zhao-Jie
Journal of Agricultural and Food Chemistry, ISSN 0021-8561, 05/2006, Volume 54, Issue 10, pp. 3636 - 3640
Thirteen novel ( E)- R-( methoxyimino) benzeneacetate derivatives, the analogues of strobilurins, which contain two pharmacophoric substructures of the methyl... 
(E)-α-(methoxyimino)benzeneacetates | 1,3,5-substituled pyrazoles | Fungicidal | Strobilurins | 1,3,5-substituted pyrazoles | fungicidal | FOOD SCIENCE & TECHNOLOGY | AGRICULTURE, MULTIDISCIPLINARY | (E)-alpha-(methoxyimino)benzeneacetates | strobilurins | INHIBITORS | CHEMISTRY, APPLIED | ANTITUMOR-ACTIVITY | Phenylacetates - analysis | Benzene Derivatives - chemical synthesis | Fungi - drug effects | Stereoisomerism | Crystallography, X-Ray | Structure-Activity Relationship | Imines - analysis | Fungicides, Industrial - chemical synthesis | Imines - pharmacology | Fungicides, Industrial - pharmacology | Pyrazoles - chemistry | Benzene Derivatives - pharmacology | Phenylacetates - pharmacology
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16. Full Text Metal-free oxidative cross-coupling of unfunctionalized aromatic compounds
by Kita, Yasuyuki and Morimoto, Koji and Ito, Motoki and Ogawa, Chieko and Goto, Akihiro and Dohi, Toshifumi
Journal of the American Chemical Society, ISSN 0002-7863, 02/2009, Volume 131, Issue 5, pp. 1668 - 1669
A new strategy for mixed biaryl synthesis has been developed using the hypervalent iodine(III) reagents. The unique reactivities of the sigma-heteroaryl... 
ARENES | POLYTHIOPHENES | BOND FORMATION | C-H ACTIVATIONS | DERIVATIVES | THIOPHENE | CHEMISTRY, MULTIDISCIPLINARY | BIARYLS | Naphthalenes - chemical synthesis | Naphthalenes - chemistry | Iodine - chemistry | Thiophenes - chemical synthesis | Benzene Derivatives - chemical synthesis | Pyrroles - chemical synthesis | Oxidation-Reduction | Pyrroles - chemistry | Benzene Derivatives - chemistry | Thiophenes - chemistry | Onium Compounds - chemistry | Oxidation-reduction reaction | Chemical properties | Thiophene | Structure | Analysis | Pyrrole
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17. Full Text A general method for copper-catalyzed arylation of arene C-H bonds
by Do, Hien-Quang and Khan, Rana M. Kashif and Daugulis, Olafs
Journal of the American Chemical Society, ISSN 0002-7863, 11/2008, Volume 130, Issue 45, pp. 15185 - 15192
A general method for copper-catalyzed arylation of sp(2) C-H bonds with pK(a)'s below 35 has been developed. The method employs aryl halide as the coupling... 
ORGANIC-SYNTHESIS | ROOM-TEMPERATURE | CROSS-COUPLING REACTIONS | NITROGEN-HETEROCYCLES | DIRECTED ORTHO-METALATION | ARYL HALIDES | BIARYL SYNTHESIS | TERMINAL ALKYNES | UNACTIVATED ARENES | N-ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | Heterocyclic Compounds - chemical synthesis | Benzene Derivatives - chemical synthesis | Copper - chemistry | Catalysis | Heterocyclic Compounds - chemistry | Benzene Derivatives - chemistry | Arylation | Organocuprates | Analysis | Chemical properties | Copper | Electric properties
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18. Full Text Formal Asymmetric Catalytic Thiolation with a Bifunctional Catalyst at a Water–Oil Interface: Synthesis of Benzyl Thiols
by Guo, Wengang and Wu, Bo and Zhou, Xin and Chen, Ping and Wang, Xu and Zhou, Yong‐Gui and Liu, Yan and Li, Can
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2015, Volume 54, Issue 15, pp. 4522 - 4526
The enantioselective conjugated addition of tritylthiol to in situ generated ortho ‐quinone methides ( o ‐QMs) is catalyzed by an acid–base bifunctional... 
organocatalysis | ortho | asymmetric catalysis | quinone methides | thiol addition | ortho-quinone methides | Asymmetric catalysis | Organocatalysis | Thiol addition | Amines - chemistry | Benzene Derivatives - chemical synthesis | Stereoisomerism | Indolequinones - chemical synthesis | Water - chemistry | Sulfhydryl Compounds - chemistry | Indolequinones - chemistry | Amines - chemical synthesis | Catalysis | Oils - chemistry | Sulfhydryl Compounds - chemical synthesis | Benzene Derivatives - chemistry | Thiols | Enantiomers | Quinone | Stereoselectivity | Solvents | Synthesis | Asymmetry | Catalysts | Mercaptans | Optical activity | Strategy | Transformations
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19. Full Text Selective synthesis and crystal structure of [10]cycloparaphenylene
by Kayahara, Eiichi and Sakamoto, Yoichi and Suzuki, Toshiyasu and Yamago, Shigeru
Organic Letters, ISSN 1523-7060, 07/2012, Volume 14, Issue 13, pp. 3284 - 3287
[10]Cycloparaphenylene ([10]CPP) was selectively synthesized in four steps in 13% overall yield from commercially available 4,4'-diiodobiphenyl by using... 
ARYLPALLADIUM | PALLADIUM | TRANSMETALATION | COMPLEXES | CHEMISTRY, ORGANIC | NANOTUBES | CHIRAL CARBON NANORINGS | STRAIN | BOTTOM-UP SYNTHESIS | Benzene Derivatives - chemical synthesis | Macrocyclic Compounds - chemistry | Models, Molecular | Crystallography, X-Ray | Molecular Structure | Benzene Derivatives - chemistry | Macrocyclic Compounds - chemical synthesis
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20. Full Text Silver-Mediated Fluorination of Functionalized Aryl Stannanes
by Furuya, T and Strom, AE and Ritter, T
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 02/2009, Volume 131, Issue 5, pp. 1662 - 1662
We report a regiospecific silver-mediated fluorination of aryl stannanes. The presented reaction can afford complex fluoroarenes from readily available phenols... 
XENON DIFLUORIDE | ELEMENTAL FLUORINE | ORGANIC-COMPOUNDS | VINYL STANNANES | CHEMISTRY | REPRESENTATION | ELECTROPHILIC FLUORINATIONS | TIN BONDS | ORGANOSTANNANES | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | Hydrocarbons, Fluorinated - chemical synthesis | Benzene Derivatives - chemical synthesis | Tin Compounds - chemical synthesis | Silver - chemistry | Hydrocarbons, Fluorinated - chemistry | Phenols - chemistry | Tin Compounds - chemistry | Benzene Derivatives - chemistry | Tin | Arylation | Silver | Chemical properties | Fluorination | Analysis
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