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Current Organic Chemistry, ISSN 1385-2728, 09/2011, Volume 15, Issue 18, pp. 3214 - 3232
This review aims at providing synthetic organic chemists with enough background for research in the palladium-catalyzed chemistry of highly reactive aryne... 
Arene | Cyclization | Aryne | Trimerization | Palladium | Catalysis | Annulation | Benzyne | ORGANIC-SYNTHESIS | POLYCYCLIC AROMATIC-HYDROCARBONS | CHEMISTRY, ORGANIC | PALLADIUM COMPLEX | DISCOTIC LIQUID-CRYSTALS | DIMETHYL ACETYLENEDICARBOXYLATE | CROSS-COUPLING REACTIONS | HIGHLY EFFICIENT ROUTE | ARYL HALIDES | CARBON TRIPLE BONDS | INTRAMOLECULAR BIS-SILYLATION
Journal Article
JOURNAL OF CHEMICAL RESEARCH, ISSN 1747-5198, 03/2019, Volume 43, Issue 3-4, pp. 112 - 114
Treatment of acridine with I-aminobenzotriazole and lead tetraacetate gives N-phenylacridone by a non-concerted benzyne reaction. A mechanism is proposed by... 
OXIDATION | benzyne | phenazine | MOLECULAR-STRUCTURE | lead tetraacetate | CRYSTAL | CHEMISTRY, MULTIDISCIPLINARY | I-aminobenzotriazole | acridine | Lead acetates | Alcohol | Nuclear magnetic resonance--NMR | Authorship | Crystal structure
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 2005, Issue 26, pp. 3292 - 3294
The carbon-carbon sigma-bond of various beta-dicarbonyl compounds was found to add to the triple bond of arynes under extremely mild conditions, leading to... 
TRIFLATE | TRIPLE BONDS | PALLADIUM COMPLEX | CHEMISTRY, MULTIDISCIPLINARY | STRAIGHTFORWARD SYNTHESIS | BENZYNE | DISULFIDES | Hydrocarbons, Aromatic - chemistry | Molecular Structure | Hydrocarbons, Aromatic - chemical synthesis | Carbon - chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2004, Volume 43, Issue 30, pp. 3935 - 3938
Mix the components, stir, and …︁ voilà! A variety of benzoannulated iminofurans can be obtained in this straightforward manner from an aryne, an isocyanide,... 
oxygen heterocycles | regioselectivity | arynes | multicomponent reactions | isocyanides | Multicomponent reactions | Oxygen heterocycles | Regioselectivity | Isocyanides | Arynes | BENZYNES | RELATIVE REACTIVITIES | isocyanicles | ION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | DISULFIDES | OXAZOLINES
Journal Article
中国化学快报:英文版, ISSN 1001-8417, 2014, Volume 25, Issue 12, pp. 1535 - 1539
Some novel cycloaddition reactions based on benzyne and olefins have been developed.These reactions were performed in the absence of a transition metal... 
苯并环丁烯 | 苯炔 | 化合物 | 衍生物 | 烯烃 | 反应合成 | 环加成反应 | 过渡金属催化剂 | Benzocyclobutenes | Cycloaddition | 9,10-Dihydrophenanthrene | Benzyne | Olefins | Biaryl | ARYNES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Science, ISSN 2041-6520, 2018, Volume 9, Issue 39, pp. 7688 - 7693
This article describes an experimental and computational investigation on the possible aryne reactivity modes in the course of the reaction of two highly... 
DIELS-ALDER REACTIONS | NUCLEOPHILIC ADDITIONS | HETEROCYCLES | INDOLYNE | CHEMISTRY | DISTORTIONS | CHEMISTRY, MULTIDISCIPLINARY | BENZYNE | REGIOSELECTIVITIES
Journal Article
Synthesis, ISSN 0039-7881, 12/2016, Volume 48, Issue 23, pp. 4099 - 4109
Abstract The efficient generation of 3-triflyloxyarynes, including those bearing a transformable group, through an iodine–magnesium exchange reaction of... 
paper | arynes | benzyne | Grignard reagent | halogen-metal exchange | thia-Fries rearrangement | ARYNE REACTIONS | REGIOSELECTIVE DIELS-ALDER | EXCHANGE-REACTION | ACTIVATION | SELECTIVE NUCLEOPHILIC-ADDITION | CHEMISTRY, ORGANIC | BOND FORMATION | HETEROCYCLES | CYCLOADDITIONS | CONCISE SYNTHESIS | PRECURSORS
Journal Article
ACS Catalysis, ISSN 2155-5435, 12/2018, Volume 8, Issue 12, pp. 11029 - 11034
A palladium(0)-catalyzed dearomatizing [3+2] spiroannulation of naphthalene-based biaryls with arynes has been developed for the rapid construction of... 
spirofluorene | arynes | palladium | spiroannulation | dearomatization | ASYMMETRIC DEAROMATIZATION | O-ARYLATION | BENZYNES | ANNULATION | EFFICIENT ROUTE | ALLYLIC ALKYLATION | CHEMISTRY, PHYSICAL | TERMINAL ALKYNES | C-H ACTIVATION | SELECTIVE SYNTHESIS | BOND ACTIVATION
Journal Article
Chemistry Letters, ISSN 0366-7022, 5/2020, Volume 49, Issue 5, pp. 446 - 449
An operationally simple one-pot protocol for the synthesis of a variety of trichloromethylated tertiary amines from anthranilic acid, imines, and chloroform... 
Multicomponent reaction | CARBON | ACTIVE METHINES | EMPLOYING ARYNES | ANILINES | ALDEHYDES | GENERATION | Imine | CYCLIC ETHERS | Benzyne | CHEMISTRY, MULTIDISCIPLINARY | TRANSITION-METAL-FREE
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 10, pp. 1708 - 1711
With 2-(trimethylsilyl) aryl triflates as aryne precursors, an unprecedented three-component carboarylation reaction of unactivated imines with arynes and... 
ORGANIC-SYNTHESIS | CYCLOADDITION | TRICHLOROALKYL PHENYL ETHERS | AMINES | DIELS-ALDER REACTION | N-HETEROAROMATICS | OXYGEN HETEROCYCLES | CHLOROFORM | CHEMISTRY, MULTIDISCIPLINARY | STRAIGHTFORWARD ACCESS | BENZYNE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2015, Volume 137, Issue 1, pp. 74 - 77
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2008, Volume 130, Issue 5, pp. 1558 - 1559
Journal Article
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 12/2012, Volume 77, Issue 24, pp. 11232 - 11256
A novel, efficient route to biologically and pharmaceutically important o-(dimethylamino)aryl ketones, acridones, acridinium salts, and 1H-indazoles has been... 
FACILE N-ARYLATION | 3-SUBSTITUTED INDAZOLES | ELECTRON-TRANSFER | REDUCTION | ONE-POT SYNTHESIS | AMINES | CHEMISTRY | CHEMISTRY, ORGANIC | DERIVATIVES | BENZYNE | ALKALOIDS
Journal Article
YAKUGAKU ZASSHI, ISSN 0031-6903, 2015, Volume 135, Issue 11, pp. 1255 - 1264
Arynes, such as benzyne, are highly strained and kinetically unstable intermediates that have been widely employed in organic synthesis. In particular, since... 
benzyne | aryne | π-bond insertion | unstable intermediate | [2+2] reaction | multi-component coupling reaction
Journal Article
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