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1. Full Text Arylboronic Acid Chemistry under Electrospray Conditions
by Wang, Lifang and Dai, Chaofeng and Burroughs, Sarah Kathryn and Wang, Siming Liu and Wang, Binghe
Chemistry – A European Journal, ISSN 0947-6539, 06/2013, Volume 19, Issue 23, pp. 7587 - 7594
Boronic acids are important in the organic and biological arenas. Thus, their identification and characterization are important. ESI‐MS is a well‐known tool... 
reaction mechanisms | mass spectrometry | electrospray ionization | gas‐phase reactions | boronic acids | gas-phase reactions | BORONIC ACID | DESIGN | RECOGNITION | SENSOR | BORTEZOMIB | CHEMISTRY, MULTIDISCIPLINARY | PROBES | DIOLS | BINDING | Boronic Acids - chemistry | Molecular Structure | Macromolecular Substances - chemistry | Spectrometry, Mass, Electrospray Ionization - methods | Ionization | Mass spectrometry | Analysis | Acids | Conjugates | Mass spectrometers | Ion sources | Tools | Biological | Arenas | Chambers
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2. Full Text Palladium‐Catalyzed Difluoroalkylation of Aryl Boronic Acids: A New Method for the Synthesis of Aryldifluoromethylated Phosphonates and Carboxylic Acid Derivatives
by Feng, Zhang and Min, Qiao‐Qiao and Xiao, Yu‐Lan and Zhang, Bo and Zhang, Xingang
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2014, Volume 53, Issue 6, pp. 1669 - 1673
The palladium‐catalyzed difluoroalkylation of aryl boronic acids with bromodifluoromethylphosphonate, bromodifluoroacetate, and further derivatives has been... 
difluoroalkylation | palladium | aryl boronic acids | cross‐coupling | fluorine | cross-coupling | HALIDES | COPPER-MEDIATED DIFLUOROMETHYLATION | FLUOROALKYLATION | BOND FORMATION | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | PROTEIN-TYROSINE | CROSS-COUPLING REACTIONS | FACILE | Electron Transport | Carboxylic Acids - chemistry | Organophosphonates - chemistry | Boronic Acids - chemistry | Catalysis | Palladium - chemistry | Boronic Acids - chemical synthesis | Fluorine - chemistry | Electrons | Palladium | Fluorides | Analysis | Methods | Phosphonates | Acids | Synthesis | Pathways | Catalysts | Aromatic compounds | Derivatives | Carboxylic acids | Single electrons
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3. Full Text Direct Catalytic Trifluoromethylthiolation of Boronic Acids and Alkynes Employing Electrophilic Shelf‐Stable N‐(trifluoromethylthio)phthalimide
by Pluta, Roman and Nikolaienko, Pavlo and Rueping, Magnus
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2014, Volume 53, Issue 6, pp. 1650 - 1653
A new and safe method for the synthesis of N‐(trifluoromethylthio)phthalimide, a convenient and shelf‐stable reagent for the direct trifluoromethylthiolation,... 
copper | homogeneous catalysis | boron | synthetic methods | alkynes | REAGENT | OXIDATIVE TRIFLUOROMETHYLTHIOLATION | ROOM-TEMPERATURE | TRIFLUOROMETHANESULFENYL CHLORIDE | ARYL SULFIDES | CHEMISTRY, MULTIDISCIPLINARY | ELEMENTAL SULFUR | NUCLEOPHILIC TRIFLUOROMETHYLTHIOLATION | MEDICINAL CHEMISTRY | ALPHA-FLUORINATED ETHERS | THIOETHERS | Copper - chemistry | Oxidation-Reduction | Phthalimides - chemistry | Sulfhydryl Compounds - chemistry | Alkynes - chemistry | Boronic Acids - chemistry | Catalysis | Fluorine - chemistry | Acids | Research & development--R&D | Utilities | Synthesis | Tolerances | Shelf life | Research and development | Functional groups | Alkynes
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4. Full Text Exploiting the Reversible Covalent Bonding of Boronic Acids: Recognition, Sensing, and Assembly
by Bull, Steven D and Davidson, Matthew G and van den Elsen, Jean M. H and Fossey, John S and Jenkins, A. Toby A and Jiang, Yun-Bao and Kubo, Yuji and Marken, Frank and Sakurai, Kazuo and Zhao, Jianzhang and James, Tony D
Accounts of Chemical Research, ISSN 0001-4842, 02/2013, Volume 46, Issue 2, pp. 312 - 326
Boronic acids can interact with Lewis bases to generate boronate anions, and they can also bind with diol units to form cyclic boronate esters. Boronic acid... 
SACCHARIDE DETECTION | CHEMOSENSORS | ELECTROPHORESIS | STRATEGY | FLUORESCENCE TRANSDUCTION | ENANTIOMERIC PURITY | ESTERIFICATION | SENSORS | NMR ANALYSIS | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE PROTOCOLS | Dopamine - chemistry | Fluorescent Dyes - chemistry | Cyclization | Oxidation-Reduction | Esters - chemistry | Electrophoresis | Boronic Acids - chemistry | Molecular Structure | Chemical bonds | Boric acid | Lewis structures | Research | Chemical properties | Anions | Receptors | Separation | Constants | Esters | Lewis base | Recognition | Diols
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5. Full Text Palladium‐Catalyzed Synthesis of (Hetero)Aryl Alkyl Sulfones from (Hetero)Aryl Boronic Acids, Unactivated Alkyl Halides, and Potassium Metabisulfite
by Shavnya, Andre and Hesp, Kevin D and Mascitti, Vincent and Smith, Aaron C
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2015, Volume 54, Issue 46, pp. 13571 - 13575
A palladium‐catalyzed one‐step synthesis of (hetero)aryl alkyl sulfones from (hetero)arylboronic acids, potassium metabisulfite, and unactivated or activated... 
alkylation | palladium | homogeneous catalysis | sulfones | boronic acids | SELECTIVE OXIDATION | INSERTION | SULFIDES | SULFUR-DIOXIDE | SULFONYLATION | COMPLEXES | ARYL SULFONES | CHEMISTRY, MULTIDISCIPLINARY | HYDROGEN-PEROXIDE | DERIVATIVES | EFFICIENT | Sulfones - chemistry | Models, Molecular | Crystallography, X-Ray | Organometallic Compounds - chemistry | Boronic Acids - chemistry | Molecular Structure | Catalysis | Palladium - chemistry | Hydrocarbons, Halogenated - chemistry | Sulfites - chemistry | Sulfones - chemical synthesis | Sulfites | Palladium | Organosulfur compounds | Acids | Potassium | Diffraction | Synthesis | Halides | Transformations | Sulfones
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6. Full Text Primary Alkylboronic Acids as Highly Active Catalysts for the Dehydrative Amide Condensation of α‑Hydroxycarboxylic Acids
by Yamashita, Risa and Sakakura, Akira and Ishihara, Kazuaki
Organic Letters, ISSN 1523-7060, 07/2013, Volume 15, Issue 14, pp. 3654 - 3657
Primary alkylboronic acids such as methylboronic acid and butylboronic acid are highly active catalysts for the dehydrative amide condensation of... 
ENANTIOSELECTIVE SYNTHESIS | AFFINITY | AMINES | CARDIOTONIC AGENT | AMIDATION | CHEMISTRY, ORGANIC | BORIC-ACID | BOND FORMATION | BETA-ADRENERGIC RECEPTORS | DENOPAMINE TA-064 | CARBOXYLIC-ACIDS | Boron Compounds - chemistry | Stereoisomerism | Carboxylic Acids - chemistry | Amides - chemistry | Boronic Acids - chemistry | Molecular Structure | Catalysis
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7. Full Text Enantioselective amine α-functionalization via palladium-catalysed C-H arylation of thioamides
by Jain, Pankaj and Verma, Pritha and Xia, Guoqin and Yu, Jin-Quan
Nature Chemistry, ISSN 1755-4330, 02/2017, Volume 9, Issue 2, pp. 140 - 144
Saturated aza-heterocycles are highly privileged building blocks that are commonly encountered in bioactive compounds and approved therapeutic agents. These... 
TRANSITION-METAL CATALYSIS | ACTIVATION | N-BOC-PYRROLIDINE | HETEROCYCLES | LITHIATION-ELECTROPHILIC SUBSTITUTION | INDOLINES | CHIRAL BRONSTED ACID | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | Amines - chemistry | Thioamides - chemistry | Stereoisomerism | Phosphoric Acids - chemistry | Ligands | Boronic Acids - chemistry | Catalysis | Coordination Complexes - chemistry | Hydrogen - chemistry | Palladium - chemistry | Carbon - chemistry
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8. Full Text Direct Amidation of Carboxylic Acids Catalyzed by ortho-Iodo Arylboronic Acids: Catalyst Optimization, Scope, and Preliminary Mechanistic Study Supporting a Peculiar Halogen Acceleration Effect
by Gernigon, Nicolas and Al-Zoubi, Raed M and Hall, Dennis G
The Journal of Organic Chemistry, ISSN 0022-3263, 10/2012, Volume 77, Issue 19, pp. 8386 - 8400
The importance of amides as a component of biomolecules and synthetic products motivates the development of catalytic, direct amidation methods employing free... 
CONVENIENT SYNTHESIS | ALCOHOLS | SOLVENT-FREE CONDITIONS | AMINES | CHEMISTRY | CHEMISTRY, ORGANIC | COUPLING REAGENTS | BORIC-ACID | AMIDE BOND FORMATION | EFFICIENT | DERIVATIVES | Boron Compounds - chemistry | Hydrogen Bonding | Iodobenzenes - chemistry | Carboxylic Acids - chemistry | Halogens - chemistry | Molecular Structure | Catalysis | Thermal properties | Usage | Analysis | Carboxylic acids | Chemical properties | Hydrogen bonding | Mathematical optimization
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9. Full Text A Universal Procedure for the [F-18]Trifluoromethylation of Aryl Iodides and Aryl Boronic Acids with Highly Improved Specific Activity
by van der Born, D and Sewing, C and Herscheid, J.D.M and Windhorst, A.D and Orru, R.V.A and Vugts, D.J
Angewandte Chemie International Edition in English, ISSN 1433-7851, 2014, Volume 53, Issue 41, pp. 11046 - 11050
Herein, we describe a valuable method for the introduction of the [ 
fluorine‐18 | trifluoromethylation | isotopic labeling | specific activity | radiochemistry | Specific activity | Fluorine-18 | Trifluoromethylation | Radiochemistry | Isotopic labeling | fluorine-18 | Chlorofluorocarbons, Methane - chemistry | Radiopharmaceuticals - chemistry | Humans | Isotope Labeling | Boronic Acids - chemistry | Iodides - chemistry | Neoplasms - diagnosis | Positron-Emission Tomography | Fluorine Radioisotopes - chemistry | FUTURE | CHEMISTRY, MULTIDISCIPLINARY | HISTORICAL-PERSPECTIVE | F-18 | EFFICIENT PRECURSOR | MEDICINAL CHEMISTRY | POSITRON-EMISSION-TOMOGRAPHY | DRUG DEVELOPMENT | FLUORINE | FLUOROFORM | PET | Trihalomethanes | Fluorides | Acids | Iodides | Aromatic compounds | Precursors | Positron emission | Tomography | Halogenated | Labels | Conversion | Tracers
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10. Full Text Application of Fundamental Organometallic Chemistry to the Development of a Gold‐Catalyzed Synthesis of Sulfinate Derivatives
by Johnson, Miles W and Bagley, Scott W and Mankad, Neal P and Bergman, Robert G and Mascitti, Vincent and Toste, F. Dean
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2014, Volume 53, Issue 17, pp. 4404 - 4407
The development of a gold(I)‐catalyzed sulfination of aryl boronic acids is described. This transformation proceeds through an unprecedented mechanism which... 
gold | sulfonamides | structure elucidation | heterocycles | synthetic methods | SULFUR-DIOXIDE | COMPLEXES | REACTIVITY | SULFONES | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | AMINOSULFONYLATION | BORONIC ACIDS | ARYL | INHIBITORS | Gold - chemistry | Sulfonamides - chemical synthesis | X-Ray Diffraction | Organometallic Compounds - chemistry | Boronic Acids - chemistry | Molecular Structure | Catalysis | Sulfones - chemical synthesis | Sulfonamides | Pharmaceutical industry | Drugs | Anions | Synthesis | Aromatic compounds | Metalorganic compounds | X-rays | Transformations | Derivatives | Sulfones
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11. Full Text Nickel‐Catalyzed Monofluoromethylation of Aryl Boronic Acids
by Su, Yi‐Ming and Feng, Guang‐Shou and Wang, Zhen‐Yu and Lan, Quan and Wang, Xi‐Sheng
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2015, Volume 54, Issue 20, pp. 6003 - 6007
Aryl boronic acids can be monofluoromethylated under nickel catalysis. The utility of this method is demonstrated by the monofluoromethylation of a borylated... 
monofluoromethylation | nickel | catalysis | radicals | aryl boronic acid | HALIDES | ALPHA-ARYLATION | COPPER-MEDIATED DIFLUOROMETHYLATION | FLUORINATION | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | IODIDES | CROSS-COUPLING REACTIONS | (2-PYRIDYL)SULFONYL GROUP | SUZUKI REACTIONS | SECONDARY ALKYL CHLORIDES | Hydrocarbons, Fluorinated - chemical synthesis | Nickel - chemistry | Hydrocarbons, Fluorinated - chemistry | Organometallic Compounds - chemistry | Boronic Acids - chemistry | Molecular Structure | Catalysis | Nickel | Drugs | Utilities | Catalysts | Aromatic compounds | Derivatives | Fluorometers | Radicals
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12. Full Text Boric Acid: A Highly Efficient Catalyst for Transamidation of Carboxamides with Amines
by Nguyen, Thanh Binh and Sorres, Jonathan and Tran, Minh Quan and Ermolenko, Ludmila and Al-Mourabit, Ali
Organic Letters, ISSN 1523-7060, 06/2012, Volume 14, Issue 12, pp. 3202 - 3205
A novel method of transamidation of carboxamides with amines using catalytic amounts of readily available boric acid under solvent-free conditions has been... 
AMIDATIONS | FORMYLATION | SECONDARY CARBOXAMIDES | ACTIVATION | CHEMISTRY, ORGANIC | CONDENSATION | ALDEHYDES | AMIDE BOND FORMATION | AMINOLYSIS | CARBOXYLIC-ACIDS | HYDROCHLORIDE | Amines - chemistry | Amides - chemistry | Molecular Structure | Boric Acids - chemistry | Catalysis | Amination | Organic chemistry | Chemical Sciences
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13. Full Text Chan–Lam-Type S-Arylation of Thiols with Boronic Acids at Room Temperature
by Xu, Hua-Jian and Zhao, Yong-Qiang and Feng, Teng and Feng, Yi-Si
The Journal of Organic Chemistry, ISSN 0022-3263, 03/2012, Volume 77, Issue 6, pp. 2878 - 2884
In this work, an efficient CuSO4-catalyzed S-arylation of thiols with aryl and heteroaryl boronic acids at room temperature is established. This catalytic... 
CROSS-COUPLING REACTIONS | ORGANOBORONIC ACIDS | LIGAND-FREE | PHENYLBORONIC ACIDS | CATALYZED C-S | N-CYCLOPROPYLATION | ARYL HALIDES | CHEMISTRY, ORGANIC | SULFUR BOND FORMATION | ARYLBORONIC ACIDS | COPPER CATALYST | Temperature | Oxidants - chemistry | Stereoisomerism | Ligands | Sulfhydryl Compounds - chemistry | Boronic Acids - chemistry | Molecular Structure | Catalysis | Thermal properties | Arylation | Boric acid | Chemical properties | Analysis
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14. Full Text Boronic Acid‐Based Carbohydrate Sensing
by Zhai, Wenlei and Sun, Xiaolong and James, Tony D and Fossey, John S
Chemistry – An Asian Journal, ISSN 1861-4728, 09/2015, Volume 10, Issue 9, pp. 1836 - 1848
The covalent boron–diol interaction enables elaborate design of boronic acid‐based saccharide sensors. Over the last decade, this research topic has been well... 
molecular sensors | functionalized polymers | sensors | boronic acid | saccaride sensing | AFFINITY SEPARATION | SACCHARIDES | RECOGNITION | FERROCENE | SILICA PARTICLES | GLYCOPROTEINS | CHEMISTRY, MULTIDISCIPLINARY | ELECTROPHORESIS | GLUCOSE | DERIVATIVES | FLUORESCENCE SENSOR | Animals | Peptides - chemistry | Humans | Models, Molecular | Biosensing Techniques - methods | Electrochemical Techniques - methods | Polymers - chemistry | Boronic Acids - chemistry | Carbohydrates - analysis | Hydrogels - chemistry | Molecular Imprinting - methods
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15. Full Text Base-free nickel-catalysed decarbonylative Suzuki–Miyaura coupling of acid fluorides
by