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1. Full Text Blocky poly(ɛ‐caprolactone‐co‐butylene 2,5‐furandicarboxylate) copolyesters via enzymatic ring opening polymerization
by Morales‐Huerta, Juan Carlos and Martínez de Ilarduya, Antxon and Muñoz‐Guerra, Sebastián
Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 02/2018, Volume 56, Issue 3, pp. 290 - 299
ABSTRACT Cyclic oligo(butylene 2,5‐furandicarboxylate) and ɛ‐caprolactone were copolymerized in bulk at 130–150 °C by enzymatic ring opening polymerization... 
caprolactone copolyesters | furanic copolyesters | furan‐based polyesters | ring‐opening polymerization | aliphatic‐aromatic copolyesters | enzymatic polymerization | ɛ‐caprolactone | 2,5‐furandicarboxylic acid | poly(butylene furanoate) copolyesters | FDCA | furan-based polyesters | 2,5-furandicarboxylic acid | ɛ-caprolactone | aliphatic-aromatic copolyesters | ring-opening polymerization | AROMATIC COPOLYESTERS | POLYESTERS | POLYMER SCIENCE | CATALYZED SYNTHESIS | CRYSTAL-STRUCTURE | 5-furandicarboxylic acid | TEMPERATURES | caprolactone | POLYAMIDES | Ring opening polymerization | Heat treatment | Bulk polymerization | Crystallization | Polymerization | Copolymerization | Chemical synthesis | Ring opening | Thermal stability | Enginyeria química | Copolímers | Furan-based polyesters | Poliester | Polimerització | Polyesters | Àrees temàtiques de la UPC
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2. Full Text ε-Caprolactone: Activated monomer polymerization; controversy over the mechanism of polymerization catalyzed by phosphorus acids (diarylhydrogen phosphates). Do acids also act as initiators?
by Lewinski, Piotr and Pretula, Julia and Kaluzynski, Krzysztof and Kaźmierski, Sławomir and Penczek, Stanislaw
Journal of Catalysis, ISSN 0021-9517, 03/2019, Volume 371, pp. 305 - 312
Whenever Activated Monomer Mechanism (AMM) is involved in cationic ring-opening polymerization of cyclic esters, giving biodegradable polymers, catalysts and... 
Ring opening polymerization | DOSY | Diphenyl phosphate | Activated monomer polymerization | Poly(ε-caprolactone) | Cationic polymerization | Organocatalysis | Poly(epsilon-caprolactone) | CYCLIC ESTERS | L,L-LACTIDE | STANNOUS OCTOATE | CHEMISTRY, PHYSICAL | CATIONIC-POLYMERIZATION | ENGINEERING, CHEMICAL | ORGANOCATALYSTS | KINETICS | RING-OPENING POLYMERIZATION | BONE | L-LACTIDE POLYMERIZATION | PROPAGATION
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3. Full Text Synthesis of new molecularly imprinted polymer via reversible addition fragmentation transfer polymerization as a drug delivery system
by Abdollahi, Elaheh and Khalafi-Nezhad, Ali and Mohammadi, Ali and Abdouss, Majid and Salami-Kalajahi, Mehdi
Polymer, ISSN 0032-3861, 05/2018, Volume 143, pp. 245 - 257
Living free-radical polymerization via reversible addition fragmentation chain transfer (RAFT) polymerization in presence of a chain transfer agent (CTA) was... 
Drug delivery system | Molecularly imprinted polymer | Reversible addition fragmentation transfer polymerization | POLYMER SCIENCE | BULK-POLYMERIZATION | MICROSPHERES | RELEASE | METHACRYLATE | TRANSFER RADICAL POLYMERIZATION | NANOPARTICLES | CHAIN TRANSFER POLYMERIZATION | PRECIPITATION POLYMERIZATION | ACID)-GRAFTED GRAPHENE OXIDE | SOLID-PHASE EXTRACTION
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4. Full Text Reversible addition‐fragmentation chain transfer polymerization of diisopropyl fumarate using various dithiobenzoates as chain transfer agents
by Takada, Kohei and Matsumoto, Akikazu
Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 10/2017, Volume 55, Issue 19, pp. 3266 - 3275
ABSTRACT Dialkyl fumarates as 1,2‐disubstituted ethylenes exhibit unique features of radical polymerization kinetics due to their significant steric hindrance... 
controlled polymerization | living polymerization | molecular weight distribution | chain transfer | dithioester | stiffness | dialkyl fumarate | radical polymerization | reversible addition‐fragmentation chain transfer (RAFT) | reversible addition-fragmentation chain transfer (RAFT) | NITROXIDE TRAPPING TECHNIQUE | TERT-BUTYL FUMARATE | POLYMER SCIENCE | TRANSFER RAFT POLYMERIZATION | BLOCK-COPOLYMERS | METHYL-METHACRYLATE | EVALUATED RATE COEFFICIENTS | FREE-RADICAL POLYMERIZATION | ABSOLUTE RATE CONSTANTS | MEAN-SQUARE RADIUS | POLY(DIISOPROPYL FUMARATE) | Polymerization | Usage | Vinyl polymers | Benzoates | Addition polymerization | Bulk polymerization | Molecular weight distribution | Fragments | Steric hindrance | Chains (polymeric) | Molecular weight | Fragmentation | Termination (polymerization) | Molecular conformation | Chain transfer | Propagation (polymerization) | Polymers
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5. Full Text Synthesis of polyolefin‐block‐polystyrene through sequential coordination and anionic polymerizations
by Jeon, Jong Yeob and Park, Su Hyun and Kim, Dong Hyun and Park, Seung Soo and Park, Geun Ho and Lee, Bun Yeoul
Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 10/2016, Volume 54, Issue 19, pp. 3110 - 3118
ABSTRACT Two representative bulk polymers, polyolefin (PO) and polystyrene (PS), were molecularly connected to form PO‐block‐PS by sequentially performing... 
block copolymers | polymerization | coordinative chain transfer polymerization | polyolefin | polystyrene | POLYMER SCIENCE | MOLECULAR-WEIGHT | TRIBLOCK COPOLYMERS | OLEFIN POLYMERIZATION | STYRENE | P-METHYLSTYRENE | CHAIN-TRANSFER POLYMERIZATION | SHUTTLING POLYMERIZATION | ZIRCONOCENE CATALYSTS | RADICAL POLYMERIZATION | THERMOPLASTIC ELASTOMERS | Polymerization | Cytokinins | Surface active agents | Polystyrene | Block copolymers | Polystyrene resins | Bulk polymerization | Catalysts | Styrenes | Initiators | Anionic polymerization | Polyolefins
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6. Microwave-assisted free radical polymerizations
by Fang, Liangjing and Han, Guang and Zhang, Huiqi
Advances in Polymer Science, ISSN 0065-3195, 2016, Volume 274, pp. 87 - 130
Microwave irradiation has drawn rapidly increasing interest in the field of polymer science as an alternative heating method for polymer syntheses and... 
Heterogeneous polymerization | Microwave irradiation | Homogeneous polymerization | Free radical polymerizations | Conventional heating | ORGANIC-SYNTHESIS | POLYMER SCIENCE | METHYL-METHACRYLATE | MINIEMULSION POLYMERIZATION | DISPERSION POLYMERIZATION | SINGLE-STEP SYNTHESIS | SOLID-STATE | ACCELERATED SYNTHESIS | FREE EMULSION POLYMERIZATION | RING-OPENING POLYMERIZATION | RAPID SYNTHESIS
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7. Full Text How chain length dependencies interfere with the bulk RAFT polymerization rate and microstructural control
by De Rybel, Nils and Van Steenberge, Paul H.M and Reyniers, Marie-Françoise and D'hooge, Dagmar R and Marin, Guy B
Chemical Engineering Science, ISSN 0009-2509, 02/2018, Volume 177, pp. 163 - 179
A pseudo-steady state based (PSSA) deterministic solution strategy is presented to calculate the concentrations of single and multi-arm macrospecies types in... 
Diffusional limitations | Polymerization kinetics | Controlled radical polymerization | Chain length distribution | Pseudo steady-state approximation | ADDITION-FRAGMENTATION CHAIN | METHYL-METHACRYLATE | RATE RETARDATION | THERMAL POLYMERIZATION | ENGINEERING, CHEMICAL | FREE-RADICAL POLYMERIZATIONS | TERMINATION RATE COEFFICIENTS | MOLECULAR-WEIGHT DISTRIBUTION | KINETIC-ANALYSIS | POPULATION BALANCE-EQUATIONS | GRADIENT COPOLYMERS | Polymerization | Nitriles | Methyl methacrylate | Analysis
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8. Full Text Nitroxide mediated suspension polymerization of methacrylic monomers
by Ballard, Nicholas and Aguirre, Miren and Simula, Alexandre and Leiza, Jose R and van Es, Steven and Asua, José M
Chemical Engineering Journal, ISSN 1385-8947, 05/2017, Volume 316, pp. 655 - 662
Suspension polymerization offers a scalable route to the synthesis of poly(methacrylic) resins with controlled molecular weight and complex macromolecular... 
Methacrylates | Controlled radical polymerization | Suspension polymerization | Block copolymer | Nitroxide mediated polymerization | ACID-CATALYZED DISPROPORTIONATION | DISPERSED SYSTEMS | METHYL-METHACRYLATE | MINIEMULSION POLYMERIZATION | PULSED-LASER | STYRENE | CHAIN TRANSFER | ENGINEERING, CHEMICAL | LIVING RADICAL POLYMERIZATION | ENGINEERING, ENVIRONMENTAL | KINETICS | WATER | Polymerization | Methyl methacrylate | Block copolymers
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9. Full Text Kinetics and Mechanism of Cyclic Esters Polymerization Initiated with Tin(II) Octoate. 3. † Polymerization of l,l-Dilactide
by Kowalski, Adam and Duda, Andrzej and Penczek, Stanislaw
Macromolecules, ISSN 0024-9297, 10/2000, Volume 33, Issue 20, pp. 7359 - 7370
Following our previous papers on the mechanism of cyclic esters polymerization induced by tin(II) octoate (Sn(Oct)2) and particularly papers on ε-caprolactone... 
L-LACTIDE | BIODEGRADABLE POLYMERS | POLYMER SCIENCE | ACID | THERMODYNAMICS | EPSILON-CAPROLACTONE | BULK-POLYMERIZATION | ANIONIC-POLYMERIZATION | STANNOUS OCTOATE | POLYLACTONES | RING-OPENING POLYMERIZATION
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10. RAFT alcoholic dispersion polymerization with polymerization-induced self-assembly
by Andrew B Lowe
ISSN 0032-3861, 12/2016, Volume 106, p. 161
This article reviews the current state of the art with respect to RAE!' alcoholic dispersion polymerization processes that proceed with polymerization-induced... 
Studies | Nanoparticles | Self assembly | Self-assembly | Bulk polymerization | Polymerization | Copolymerization | Dispersion
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11. Full Text Mechanically Initiated Bulk‐Scale Free‐Radical Polymerization
by Wang, Zhao and Ayarza, Jorge and Esser‐Kahn, Aaron P
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2019, Volume 58, Issue 35, pp. 12023 - 12026
Mechanical initiation of polymerization offers the chance to generate polymers in new environments using an energy source with unique capabilities. Recently, a... 
mechanochemistry | nanoparticles | polymers | radicals | ultrasound | CHEMISTRY, MULTIDISCIPLINARY | RAFT POLYMERIZATION | Polymers | Crosslinked polymers | Ultrasonic waves | Nanoparticles | Organic chemistry | Ultrasonic imaging | Bulk polymerization | Piezoelectricity | Polymerization | Zinc oxide | Crosslinking | Ultrasound
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12. Full Text Organic‐acid mediated bulk polymerization of ε‐caprolactam and its copolymerization with ε‐caprolactone
by Sanchez‐Sanchez, Ana and Basterretxea, Andere and Mantione, Daniele and Etxeberria, Agustin and Elizetxea, Cristina and de la Calle, Amaia and García‐Arrieta, Sonia and Sardon, Haritz and Mecerreyes, David
Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 08/2016, Volume 54, Issue 15, pp. 2394 - 2402
ABSTRACT Polyamides (PA) constitute one of the most important classes of polymeric materials and have gained strong position in different areas, such as... 
organocatalysis | copolymerization | ring‐opening polymerization | sulfonic acids | poly(ester amide)s | polyamides | biodegradable polymers | polyesters | ring-opening polymerization | POLYMER SCIENCE | ORGANOCATALYSIS | organo catalysis | Hydrogen | Polymerization | Ionic liquids | Copolymerization | Sulfates | Melting points | Organic acids | Sulfonic acid
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13. Full Text Single site catalysts for stereoselective ring-opening polymerization of lactides
by Dijkstra, Pieter Jelle and Du, Hongzhi and Feijen, Jan
Polymer Chemistry, ISSN 1759-9954, 2/2011, Volume 2, Issue 3, pp. 52 - 527
Poly(lactide) (PLA) is the most well known biodegradable and biocompatible material among the aliphatic polyesters nowadays explored for biomedical,... 
RACEMIC LACTIDE | SALEN-ALUMINUM | POLYMER SCIENCE | ALUMINUM COMPLEXES | EPSILON-CAPROLACTONE | BULK-POLYMERIZATION | POLY(LACTIC ACID) | RAC-LACTIDE | CHAIN-END CONTROL | GROUP-3 METAL-COMPLEXES | CATIONIC-POLYMERIZATION
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14. Full Text Single site catalysts for stereoselective ring-opening polymerization of lactides
by Dijkstra, Pieter J and Du, H and Feijen, Jan
Polymer chemistry, ISSN 1759-9954, 2011, Volume 2, Issue 3, pp. 520 - 527
Poly(lactide) (PLA) is the most well known biodegradable and biocompatible material among the aliphatic polyesters nowadays explored for biomedical,... 
Syndiotacticity | Architecture | Catalysts | Polymerization | Catalysis | Polylactides | Stereochemistry | Aliphatic compounds
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15. Full Text In situ monitoring of styrene polymerization using Raman spectroscopy. Multi‐scale approach of homogeneous and heterogeneous polymerization processes
by Brun, Nadège and Youssef, Itab and Chevrel, Marie‐Claire and Chapron, David and Schrauwen, Cornélius and Hoppe, Sandrine and Bourson, Patrice and Durand, Alain
Journal of Raman Spectroscopy, ISSN 0377-0486, 06/2013, Volume 44, Issue 6, pp. 909 - 915
Free radical polymerization of styrene was monitored in situ by combining Raman spectroscopy to other experimental techniques (gravimetry and rheology). Three... 
polymerization | rheokinetics | in situ monitoring | styrene | BULK-POLYMERIZATION | METHYL-METHACRYLATE | EMULSION POLYMERIZATION | MODEL | THERMAL POLYMERIZATION | POLYETHYLENE | RHEO-RAMAN | POLYSTYRENE | SPECTROSCOPY | MINIEMULSION | SCATTERING | Polymerization | Chemical properties | Raman spectroscopy | Analysis | Bulk polymerization | Emulsion polymerization | Styrenes | Molecular dynamics | Monitors | Rheometers | Physics
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