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Angewandte Chemie International Edition, ISSN 1433-7851, 05/2010, Volume 49, Issue 22, pp. 3791 - 3794
New direction: Changes in the ligand structure divert the reactivity of vanadium(V) oxo complexes from alcohol oxidation to a novel non‐oxidative CO bond... 
CO cleavage | vanadium | lignin | aryl enones | non‐oxidative cleavage | COMPLEXES | non-oxidative cleavage | FRAGMENTATION | CHEMISTRY, MULTIDISCIPLINARY | C-O cleavage | ALCOHOLS | OXYGEN | PEROXIDASE | CHEMICALS | BIOMASS | AEROBIC OXIDATION | KETYL RADICALS | FUELS | Models, Chemical | Oxidation-Reduction | Oxygen - chemistry | Lignin - chemistry | Vanadium - chemistry | Catalysis | Carbon - chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2013, Volume 52, Issue 48, pp. 12674 - 12678
Breaking point: An effective reductive cleavage of inert aryl CO bonds with an inexpensive iron catalyst has been developed. During this process, the... 
CO cleavage | iron | lignin | arenes | heterogeneous catalysis | C-O cleavage | HYDROGENOLYSIS | HYDROGENATION | CONVERSION | GUAIACOL | CO cleavage | CHEMISTRY, MULTIDISCIPLINARY | CROSS-COUPLING REACTIONS | NICKEL-CATALYSTS | ETHERS | HYDRODEOXYGENATION | Linkages | Iron and steel industry | Catalysts | Aromatic compounds | Cleavage | Inert | Iron | Catalysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2010, Volume 132, Issue 36, pp. 12554 - 12555
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 12, pp. 3187 - 3190
A Ni‐catalyzed stannylation of aryl esters with air‐ and moisture‐insensitive silylstannyl reagents via Csp2 −O cleavage is described. This protocol is... 
cross-coupling | nickel | aryl esters | C−O cleavage | ACTIVATION | REAGENTS | CHEMISTRY, MULTIDISCIPLINARY | C-O cleavage | PHENOL DERIVATIVES | BORONIC ACIDS | OME CLEAVAGE | CROSS-COUPLING REACTIONS | ETHERS | STILLE REACTION | CYCLIZATION | Esters
Journal Article
Journal of Catalysis, ISSN 0021-9517, 01/2019, Volume 369, pp. 283 - 295
Tungsten carbides exhibit excellent performance in many heterogeneous processes because of their distinctive catalytic properties. Preparation of tungsten... 
C–O bond cleavage | Tungsten carbide | Guaiacol | Phenol | Regioselectivity | Hydrogenolysis | METAL CARBIDES | HYDROGENATION | C-O bond cleavage | HIGH-TEMPERATURE | CHEMISTRY, PHYSICAL | ADSORPTION | ULTRASMALL | ENGINEERING, CHEMICAL | NANOPARTICLES | HYDRODEOXYGENATION | CHEMICAL-PROPERTIES | SURFACE-CHEMISTRY | Lignin | Hydrogen | Specific gravity | Analysis | Tungsten | Bonds | Density functionals | Catalysis
Journal Article
Green Chemistry, ISSN 1463-9262, 2016, Volume 18, Issue 24, pp. 6545 - 6555
The efficient cleavage of lignin beta-O-4 ether bonds to produce aromatics is a challenging and attractive topic. Recently a growing number of studies have... 
GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | SELECTIVE OXIDATION | ORGANOSOLV LIGNIN | KRAFT LIGNIN | VALUABLE CHEMICALS | C-O BONDS | ARYL ETHERS | MODEL COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | HETEROGENEOUS NICKEL-CATALYSTS | MOLYBDENUM CARBIDE CATALYST | PHENOLIC MONOMERS | Sulfides | Catalysts | Chemical bonds | Phenols | Cleavage | Ethers | Bonding | Radicals
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 22, pp. 6339 - 6342
The decarboxylative C−H/C−O functionalization was accomplished by air‐ and water‐tolerant manganese(I) catalysis. The versatile C−H allylation occurred by... 
imines | C−H activation | C−O cleavage | heterocycles | manganese | amino acids | CATALYSIS | ALLYLATION | ARENES | CARBON-HYDROGEN BONDS | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | C-O cleavage | FUNCTIONALIZATION | CARBOXYLATE ASSISTANCE | C-H activation | PEPTIDES | AMINO-ACIDS | Schiff bases | Amino acids | Chemotherapy | Catalysis | Cancer | Selectivity | Indoles | Manganese
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2014, Volume 53, Issue 38, pp. 10160 - 10163
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2015, Volume 54, Issue 13, pp. 4075 - 4078
We report the first enantioselective CC bond formation through CO bond cleavage using aryl ester counterparts. This method is characterized by its wide... 
C‐O cleavage | aryl esters | C‐O electrophiles | nickel catalysis | C-O electrophiles | C-O cleavage
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2014, Volume 136, Issue 15, pp. 5587 - 5590
The nickel-catalyzed reaction of N-aryl amides with hydroborane or diboron reagents resulted in the formation of the corresponding reduction or borylation... 
ETHERS | ANILINE DERIVATIVES | CROSS-COUPLINGS | HYDROGENOLYSIS | DIAZONIUM SALTS | C-O BONDS | ARYLTRIMETHYLAMMONIUM IODIDES | AMMONIUM-SALTS | CHEMISTRY, MULTIDISCIPLINARY | TRANSFORMATIONS | Analysis | Carbamates | Amides | Oxidation-reduction reaction | Influence | Nickel | Research
Journal Article
Green Chemistry, ISSN 1463-9262, 05/2015, Volume 17, Issue 11, pp. 4908 - 4912
A base-catalysed transformation and cleavage of lignin beta-O-4 model compounds in dimethyl carbonate is reported. The reaction system consists of readily... 
GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | HYDROGENOLYSIS | CHEMICALS | CONVERSION | WOOD | KRAFT LIGNIN | DEPOLYMERIZATION | CHEMISTRY | C-O BONDS | DEGRADATION | CHEMISTRY, MULTIDISCIPLINARY | RANEY-NICKEL | Dimethyl | Benzene | Reagents | Cleavage | Transformations | Derivatives | Carbonates | Bonding
Journal Article
Green Chemistry, ISSN 1463-9262, 2016, Volume 18, Issue 24, pp. 6545 - 6555
The efficient cleavage of lignin β-O-4 ether bonds to produce aromatics is a challenging and attractive topic. Recently a growing number of studies have... 
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2017, Volume 23, Issue 55, pp. 13628 - 13632
Tertiary silane 1H, 2‐[(diphenylsilyl)methyl]‐6‐methylpyridine, reacts with tris(pentafluorophenyl)borane (BCF) to form the intramolecular pyridine‐stabilized... 
C−C bond formation | silicon | small molecule activation | boron | INSERTION | SMALL MOLECULES | FRUSTRATED LEWIS-PAIR | COMPLEXES | COORDINATION | CO | BORANE | CHEMISTRY, MULTIDISCIPLINARY | H BOND ACTIVATION | C-C bond formation | REDUCTION | CARBON-MONOXIDE | SI-H | Pyridines | Fracture mechanics | Aromatic compounds | Metals | Deoxygenation | Chemical bonds | Cleavage | Ductile-brittle transition | Carbon monoxide | Communications | Communication
Journal Article
Green Chemistry, ISSN 1463-9262, 11/2015, Volume 17, Issue 11, pp. 5001 - 5008
Simple FeCl sub(3)-derived iron catalysts are used for the cleavage of beta -O-4 linkages in lignin and lignin model compounds. The degradation of the beta... 
Degradation | Linkages | Methyl radicals | Catalysts | Cleavage | Peroxides | Iron | Catalysis
Journal Article