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1. Full Text Complementary Strategies for Directed C(sp3)−H Functionalization: A Comparison of Transition‐Metal‐Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer
by Chu, John C. K and Rovis, Tomislav
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2018, Volume 57, Issue 1, pp. 62 - 101
The functionalization of C(sp3)−H bonds streamlines chemical synthesis by allowing the use of simple molecules and providing novel synthetic disconnections.... 
C−H functionalization | carbenes | hydrogen atom transfer | nitrenes | transition metals | RADICAL TRANSLOCATION REACTIONS | INTERMOLECULAR AMINATION | ENANTIOSELECTIVE SYNTHESIS | ALPHA-AMINO-ACIDS | UNACTIVATED C(SP)-H | INTRAMOLECULAR FUNCTIONALIZATION | C-H functionalization | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | INSERTION REACTIONS | ALIPHATIC-AMINES | LATE-STAGE FUNCTIONALIZATION | Comparative analysis | Hydrogen | Chemical bonds | Activation | Chemical synthesis | Metals | Hydrogen ion concentration
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2. Full Text Asymmetric Synthesis of Spiropyrazolones by Rhodium‐Catalyzed C(sp2)−H Functionalization/Annulation Reactions
by Zheng, Jun and Wang, Shao‐Bo and Zheng, Chao and You, Shu‐Li
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2017, Volume 56, Issue 16, pp. 4540 - 4544
Rhodium‐catalyzed C(sp2)−H functionalization reactions of 4‐aryl‐5‐pyrazolones followed by [3+2] annulation reactions with alkynes provide rapid access to... 
asymmetric catalysis | pyrazolones | C-H functionalization | alkynes | rhodium | ACTIVATION | HYDROGENATION | BIARYL COMPOUNDS | OXIDATIVE ANNULATION | INTERNAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | CHIRAL CYCLOPENTADIENYL LIGANDS | PHOSPHORUS LIGANDS | ALKENES | Synthesis | Catalysis | Rhodium | Enantiomers | Organic compounds | Organic chemistry | Asymmetric synthesis | Catalysts | Aromatic compounds | Quaternary | Chemical reactions | Chemical synthesis | Pyrazolones | Substrates | Alkynes
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3. Full Text Tertiary‐Alcohol‐Directed Functionalization of Remote C(sp3)−H Bonds by Sequential Hydrogen Atom and Heteroaryl Migrations
by Wu, Xinxin and Wang, Mingyang and Huan, Leitao and Wang, Dongping and Wang, Jinwei and Zhu, Chen
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2018, Volume 57, Issue 6, pp. 1640 - 1644
Reported for the first time is a tertiary‐alcohol‐guided heteroarylation of remote C(sp3)−H bonds. The mild and direct generation of alkoxyl radicals from... 
C−H activation | electron transfer | radicals | heteroaryls | photocatalysis | VISIBLE-LIGHT PHOTOCATALYSIS | PHOTOCHEMICAL-REACTION | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS | ALKOXY RADICALS | C-H activation | TETRAHYDROFURANS | COUPLED ELECTRON-TRANSFER | HYPOCHLORITES | H BONDS | GENERATION | Hydrogen | Catalysis | Alcohols | Alcohol | Ketones | Migration | Hydrogen ion concentration
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4. Full Text Transition‐Metal‐Catalyzed Selective Functionalization of C(sp3)−H Bonds in Natural Products
by Karimov, Rashad R and Hartwig, John F
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2018, Volume 57, Issue 16, pp. 4234 - 4241
Direct functionalization of natural products is important for studying the structure–activity and structure–property relationships of these molecules. Recent... 
regioselectivity | oxidation | catalysis | amination | C−H bond functionalization | COMPLEX | CARBON | DRUG DISCOVERY | HYDROXYLATIONS | METHYL-GROUPS | CYCLOPALLADATION | FLUORINATION | C-H bond functionalization | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | CHALLENGES | AZIDATION | Chemical bonds | Transformation | Molecular structure | Natural products | Metals
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5. Full Text Functionalization of Organic Molecules by Transition‐Metal‐Catalyzed C(sp3)H Activation
by Jazzar, Rodolphe and Hitce, Julien and Renaudat, Alice and Sofack‐Kreutzer, Julien and Baudoin, Olivier
Chemistry – A European Journal, ISSN 0947-6539, 03/2010, Volume 16, Issue 9, pp. 2654 - 2672
Transition‐metal‐catalyzed CH activation has recently emerged as a powerful tool for the functionalization of organic molecules. While many efforts have... 
CH functionalization | CH activation | alkanes | C-H functionalization | Alkanes | C-H activation | IRIDIUM POLYHYDRIDE SYSTEM | AEROBIC OXIDATIVE AMINATION | THERMOCHEMICAL ALKANE DEHYDROGENATION | PD(OAC)-CATALYZED DOMINO REACTIONS | CARBON-HYDROGEN BONDS | FORMING REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | CROSS-COUPLING REACTIONS | HINDERED GRIGNARD-REAGENTS | PROTON-ABSTRACTION MECHANISM | Organic chemistry | Synthesis (chemistry) | Aromatic compounds | Breaking | Strategy | Activation | Functional groups | Chemical Sciences
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6. Full Text Radical Enantioselective C(sp3)−H Functionalization
by Lu, Qingquan and Glorius, Frank
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2017, Volume 56, Issue 1, pp. 49 - 51
Radical style: Several breakthroughs have recently been achieved in enantioselective C(sp3)−H functionalization through radical activation. These new... 
C−H functionalization | copper catalysis | photoredox catalysis | asymmetric synthesis | radical activation | VISIBLE-LIGHT | CATALYSIS | ALKENES | CROSS-COUPLINGS | PHOTOREDOX | ARYLATION | C-H functionalization | CHEMISTRY, MULTIDISCIPLINARY | Synthesis | Catalysis | Enantiomers | Organic compounds | Alkanes
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7. Full Text Dual C(sp3)−H Bond Functionalization of N‐Heterocycles through Sequential Visible‐Light Photocatalyzed Dehydrogenation/[2+2] Cycloaddition Reactions
by Xu, Guo‐Qiang and Xu, Ji‐Tao and Feng, Zhi‐Tao and Liang, Hui and Wang, Zhu‐Yin and Qin, Yong and Xu, Peng‐Fei
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2018, Volume 57, Issue 18, pp. 5110 - 5114
Herein we describe a mild method for the dual C(sp3)−H bond functionalization of saturated nitrogen‐containing heterocycles through a sequential visible‐light... 
C−H functionalization | [2+2] cycloaddition | dehydrogenation | visible-light photocatalysis | synthetic methods | ORGANIC-CHEMISTRY | ACTIVATION | NITROGEN-HETEROCYCLES | PHARMACEUTICALS | C-H functionalization | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | PHOTOREDOX CATALYSIS | METHODOLOGY | AMINES | DIELS-ALDER REACTION | Amino acids | Catalysis | Dehydrogenation | Acetylene | Cycloaddition | Hydrogen bonds | Esters | Nitrogen | Amino radical | Intermediates
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8. Full Text Palladium‐Catalyzed Cross‐Dehydrogenative Functionalization of C(sp2)H Bonds
by Wu, Yinuo and Wang, Jun and Mao, Fei and Kwong, Fuk Yee
Chemistry – An Asian Journal, ISSN 1861-4728, 01/2014, Volume 9, Issue 1, pp. 26 - 47
The catalytic cross‐dehydrogenative coupling (CDC) reaction has received intense attention in recent years. The attractive feature of this coupling process is... 
CH activation | palladium | dehydrogenation | homogeneous catalysis | cross‐coupling | cross-coupling | C-H activation | DIRECTING GROUP | C-H BOND | HYDROGEN SUBSTITUTION-REACTIONS | BETA-KETO-ESTERS | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE ARENES | TOLUENE DERIVATIVES | COUPLING REACTIONS | AROMATIC SUBSTITUTION | HECK REACTION | ORTHO-ACYLATION | Oxidation-Reduction | Molecular Structure | Catalysis | Hydrogen - chemistry | Hydrogenation | Palladium - chemistry | Carbon - chemistry
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