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Angewandte Chemie (International ed.), ISSN 1433-7851, 08/2017, Volume 56, Issue 35, pp. 10539 - 10544
...‐phosphonates, followed by a chemo‐ and regioselective C(sp3)−C(CO) bond‐cleavage step, provided heavily functionalized β‐ketophosphonates... 
cross-coupling | silver | C(sp3)−P bond formation | 1,3-dicarbonyl compounds | C−C bond cleavage | P bond formation | C(sp | Chemotherapy | Phosphonates | Cancer | Carbon-carbon composites | Coupling (molecular) | Silver | Cross coupling | Cleavage | Selectivity
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 02/2014, Volume 53, Issue 7, pp. 1891 - 1895
...Catalytic carboncarbon bond (CC) activation/functionalization provides a unique platform to develop novel transformations that are challenging using... 
decarbonylation | CC activation | homogeneous catalysis | spirocycles | rhodium | C=C activation | Polycyclic Compounds - chemistry | Cyclization | Stereoisomerism | Spiro Compounds - chemical synthesis | Molecular Structure | Catalysis | Rhodium - chemistry | Spiro Compounds - chemistry | Index Medicus | Pathways | Olefins | Cleavage | Activation | Joining | Formations | Transformations | Bonding
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 05/2015, Volume 54, Issue 20, pp. 5859 - 5863
...C bond cleavage of the β‐O‐4 lignin linkage of 1,3‐dilignol model compounds. A mechanistic pathway involving a dehydrogenation‐initiated retro... 
lignin | CC bond cleavage | homogeneous catalysis | cleavage reactions | ruthenium complexes | Lignin | Cleavage reactions | C-C bond cleavage | Ruthenium complexes | Homogeneous catalysis | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Linkages | Pathways | Dehydrogenation | Ligands | Cleavage | Mathematical models | Transformations | Catalytic activity | Bonding
Journal Article
Angewandte Chemie, ISSN 1521-3757, 07/2019, Volume 131, Issue 31, pp. 10803 - 10807
The selective cleavage of thermodynamically stable C(sp3)−C(sp3) single bonds is rare compared to their ubiquitous formation... 
Morpholine | Amine | Luft | C-C-Spaltung | Kupfer | Transformation | Amines | Catalysts | Natural products | Amides | Cleavage | Catalysis | Functional groups
Journal Article
FEBS letters, ISSN 0014-5793, 01/2019, Volume 593, Issue 1, pp. 67 - 79
...–C bond cleavage reaction of steroids. A major change in product distribution is observed with CYP154C8, when the reactions are supported by NADPH and spinach redox partners ferredoxin and ferredoxin reductase, compared with previously... 
redox partner | cytochrome P450 | lyase | steroid hydroxylase | C–C bond cleavage | Biochemistry & Molecular Biology | Biophysics | Life Sciences & Biomedicine | Science & Technology | Cell Biology | Index Medicus
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 10/2015, Volume 54, Issue 43, pp. 12692 - 12696
.... Preliminary mechanistic studies reveal that the reaction likely proceeds by a radical‐mediated CC bond cleavage/CN3 bond formation pathway... 
azidation | azides | cyclobutanols | CC cleavage | manganese | C-C cleavage | Cleavage | Synthesis | Pathways | Bonding | Radicals
Journal Article
Current Organic Chemistry, ISSN 1385-2728, 05/2012, Volume 16, Issue 10, pp. 1170 - 1214
The catalytic C-C bond activation by rhodium complexes has found a wide application in organic synthesis... 
C-C bond cleavage | Synthesis | Catalysis | Rhodium | Physical Sciences | Chemistry | Chemistry, Organic | Science & Technology
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 03/2012, Volume 51, Issue 10, pp. 2485 - 2488
... frameworks could arise if an unsaturated organic functionality is directly inserted into a carbon–carbon single bond. 3 Such an insertion reaction also dispenses... 
insertion reaction | nickel | asymmetric synthesis | homogeneous catalysis | CC cleavage | C-C cleavage | Carbon-carbon composites | Synthesis | Pathways | Asymmetry | Olefins | Insertion | Cleavage | Nickel | Bonding
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 01/2015, Volume 54, Issue 2, pp. 414 - 429
...–heteroatom bonds in a predictable and efficient manner. In this Review, we show an alternative approach where challenging molecular skeletons could be prepared through selective cleavage of carbon–carbon bonds... 
ring opening | strained molecules | CC activation | stereocenters | carbometalation | Carbometalation | Strained molecules | C-C activation | Ring opening | Stereocenters | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Synthesis | Organic compounds | Chemical bonds | Carbon | Carbon-carbon composites | Construction | Chemists | Strategy | Cleavage | Bonding | Life Sciences
Journal Article