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1. Full Text Transition‐Metal‐Mediated and ‐Catalyzed C−F Bond Activation by Fluorine Elimination
by Fujita, Takeshi and Fuchibe, Kohei and Ichikawa, Junji
Angewandte Chemie (International ed.), ISSN 1433-7851, 01/2019, Volume 58, Issue 2, pp. 390 - 402
C−C bond formation | C−F bond activation | elimination | fluorine | metal catalyst | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Organic chemistry | Reviews | Fluorine | Metals | Chemical bonds | Activation | Carbon | Intermediates
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2. Full Text Friedel–Crafts Reaction of Benzyl Fluorides: Selective Activation of CF Bonds as Enabled by Hydrogen Bonding
by Champagne, Pier Alexandre and Benhassine, Yasmine and Desroches, Justine and Paquin, Jean‐François
Angewandte Chemie (International ed.), ISSN 1433-7851, 12/2014, Volume 53, Issue 50, pp. 13835 - 13839
Friedel–Crafts reaction | benzyl fluorides | arenes | CF activation | hydrogen bonds | Arenes | Hydrogen bonds | Benzyl fluorides | C-F activation | Friedel-Crafts reaction | Lewis acid | Transition metals | Aromatic compounds | Alkanes | Activation | Fluorides | Hydrogen bonding
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3. Full Text Lewis Acid Promoted Single C–F Bond Activation of the CF3 Group: SN1′‐Type 3,3‐Difluoroallylation of Arenes with 2‐Trifluoromethyl‐1‐alkenes
by Fuchibe, Kohei and Hatta, Hibiki and Oh, Ken and Oki, Rie and Ichikawa, Junji
Angewandte Chemie (International ed.), ISSN 1433-7851, 05/2017, Volume 56, Issue 21, pp. 5890 - 5893
Lewis acids | C−F bond activation | allylation | carbocations | fluorine | Olefins | Bonds | Fluorides | Lewis acid | Activation | Fluoride | Alkenes | Acids | Aromatic compounds
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4. Full Text Nickel-Catalyzed Allylic C(sp3)–F Bond Activation of Trifluoromethyl Groups via β‑Fluorine Elimination: Synthesis of Difluoro-1,4-dienes
by Ichitsuka, Tomohiro and Fujita, Takeshi and Ichikawa, Junji
ACS catalysis, ISSN 2155-5435, 10/2015, Volume 5, Issue 10, pp. 5947 - 5950
trifluoromethylalkenes | C-F bond activation | 1,4-dienes | β-fluorine elimination | alkynes | nickel catalysis | Physical Sciences | Chemistry | Chemistry, Physical | Science & Technology
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5. Full Text Palladium‐Catalyzed CF Bond Formation via Directed CH Activation
by Li, Yan and Wu, Yun and Li, Guang‐Shui and Wang, Xi‐Sheng
Advanced synthesis & catalysis, ISSN 1615-4150, 05/2014, Volume 356, Issue 7, pp. 1412 - 1418
fluorination | catalysis | CH activation | palladium | CF bond formation | C-H activation | C-F bond formation | Physical Sciences | Chemistry | Chemistry, Organic | Chemistry, Applied | Science & Technology | Organic chemistry | Hydrogen bonds | Fluorine | Palladium | Fluorides | Fluorination | Bonding | Synthesis | Strategy | Activation | Transformations
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6. Full Text Main-Group Lewis Acids for C–F Bond Activation
by Stahl, Timo and Klare, Hendrik F. T and Oestreich, Martin
ACS catalysis, ISSN 2155-5435, 07/2013, Volume 3, Issue 7, pp. 1578 - 1587
C-F bond functionalization | C-F bond activation | homogeneous catalysis | main-group Lewis acids | hydrodefluorination | fluorine | Physical Sciences | Chemistry | Chemistry, Physical | Science & Technology
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7. Full Text A Highly Reactive Rhodium(I)–Boryl Complex as a Useful Tool for CH Bond Activation and Catalytic CF Bond Borylation
by Teltewskoi, Michael and Panetier, Julien A and Macgregor, Stuart A and Braun, Thomas
Angewandte Chemie (International ed.), ISSN 1433-7851, 05/2010, Volume 49, Issue 23, pp. 3947 - 3951
CH activation | CF activation | boryl ligands | borylation | rhodium | Boryl ligands | C-H activation | Rhodium | C-F activation | Borylation | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology
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8. Full Text Umpolung of Fluoroform by CF Bond Activation: Direct Difluoromethylation of Lithium Enolates
by Iida, Toshiaki and Hashimoto, Ryota and Aikawa, Kohsuke and Ito, Shigekazu and Mikami, Koichi
Angewandte Chemie (International ed.), ISSN 1433-7851, 09/2012, Volume 51, Issue 38, pp. 9535 - 9538
lithium | CF bond activation | synthetic methods | umpolung | fluorine | C-F bond activation | Hydrocarbons, Fluorinated - chemical synthesis | Quantum Theory | Lithium - chemistry | Ketones - chemistry | Hydrocarbons, Fluorinated - chemistry | Organometallic Compounds - chemistry | Molecular Structure | Methylation | Index Medicus | Transition metals | Fluoroform | Equivalence | Lithium | Activation | Inert | Bonding
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9. Full Text C−F Bond Activation by a Saturated N‐Heterocyclic Carbene: Mesoionic Compound Formation and Adduct Formation with B(C6F5)3
by Pait, Moumita and Kundu, Gargi and Tothadi, Srinu and Karak, Suvendu and Jain, Shailja and Vanka, Kumar and Sen, Sakya S
Angewandte Chemie (International ed.), ISSN 1433-7851, 02/2019, Volume 58, Issue 9, pp. 2804 - 2808
ylides | structure elucidation | C−F activation | carbanions | N-heterocyclic carbenes | Lewis acid | Fluoride | Fluorides
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10. Full Text Carbon–fluorine bond activation for the synthesis of functionalized molecules
by Unzner, Teresa A and Magauer, Thomas
Tetrahedron letters, ISSN 0040-4039, 02/2015, Volume 56, Issue 7, pp. 877 - 883
C–F bond activation | Medicinal chemistry | Catalysis | Fluorine | C-F bond activation | Physical Sciences | Chemistry | Chemistry, Organic | Science & Technology | Fluorides | Quinones | Synthesis (chemistry) | Hydrogen bonds | Tetrahedrons | Bonding strength | Activation | Magnesium | Bonding
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