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c-h activation (215) 215
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olefins (29) 29
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rhodium (25) 25
acyloxylation (24) 24
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forming reductive elimination (24) 24
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amides (22) 22
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The Journal of Organic Chemistry, ISSN 0022-3263, 10/2017, Volume 82, Issue 19, pp. 10470 - 10478
The quinazolinone ring has been exploited as a directing group for C­(sp3)–H functionalization for the first time. The proximal C−γ­(sp3)–H bonds have been... 
FUNCTIONALIZATION | OXIDATION | ACTIVATION | ACETOXYLATION | OXYGENATION | ARYLATION | CHEMISTRY, ORGANIC | ACYLOXYLATION | C(SP)-H | C-H BONDS | Usage | Heterocyclic compounds | Chemical bonds | Palladium | Chemical properties | Research | Catalysis
Journal Article
Organic Letters, ISSN 1523-7060, 09/2014, Volume 16, Issue 18, pp. 4790 - 4793
A copper-mediated terminal position-selective C(sp3)–H acetoxylation using a bidentate directing group and AgOAc as an oxidant was achieved. This reaction has... 
OXIDATION | ACID-DERIVATIVES | AMINATION | ACTIVATION | OXYGENATION | AMIDATION | OXIDANT | CHEMISTRY, ORGANIC | C-H BONDS | CARBON-HYDROGEN | CATALYZED ARYLATION
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2016, Volume 22, Issue 40, pp. 14171 - 14174
Palladium‐catalyzed C−H acetoxylation has been proposed as a key transformation in the first chemical synthesis of steroids bearing a unique... 
oxidation | protecting groups | steroids | C−H activation | rearrangement | METABOLITES | ACTIVATION | METHYL-GROUPS | UNACTIVATED C(SP)-H | CHEMISTRY, MULTIDISCIPLINARY | C-H activation | BONDS | ALKOXYLATION | METANDIENONE | Synthesis (chemistry) | Metabolites | Inversions | Transformations | Palladium | Bearing | Steroids
Journal Article
Chemical Communications, ISSN 1359-7345, 02/2015, Volume 51, Issue 15, pp. 3219 - 3222
Journal Article
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 09/2019, Volume 21, Issue 17, pp. 7154 - 7157
The controlled construction of defined oxidation patterns is one of the key aspects in the synthesis of natural products and bioactive molecules. Towards this... 
OXIDATION | C-H ACETOXYLATION | AMINO-ACIDS | ALKYLATION | ARYLATION | BONDS | CHEMISTRY, ORGANIC | ACYLOXYLATION | C(SP)-H | SELECTIVE FUNCTIONALIZATION
Journal Article
Organic Letters, ISSN 1523-7060, 09/2014, Volume 16, Issue 18, pp. 4870 - 4873
A direct regioselective acetoxylation of enamides has been accomplished using a combination of Cu(OAc)2 and rhodium catalyst. Cu(OAc)2 is served as the oxidant... 
DIRECTING GROUPS | FUNCTIONALIZATION | ACTIVATION | SELECTIVE OLEFINATION | OXYGENATION | ARENES | ARYLATION | CHEMISTRY, ORGANIC | DERIVATIVES | C-H BONDS | ENAMIDES
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 05/2014, Volume 356, Issue 7, pp. 1544 - 1548
We report a new protocol for palladium‐catalyzed acetoxylation of the γ‐C(sp3)H bonds of N‐alkylpicolinamide substrates using PhI(OAc)2 oxidant. These... 
palladium | picolinamides | CH acetoxylation | C-H acetoxylation | C(SP)-H BONDS | ACID DERIVATIVES | ACTIVATION | NATURAL-PRODUCTS | CHEMISTRY, ORGANIC | ORTHO-C(SP)-H BONDS | CARBON-HYDROGEN BONDS | C-H BONDS | FUNCTIONALIZATION | COUPLING REACTIONS | CHEMISTRY, APPLIED
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 12/2018, Volume 2018, Issue 44, pp. 6088 - 6091
A palladium‐catalyzed γ‐C(sp3)–H acetoxylation of triflyl‐protected amines has been achieved. The use of pyridine or 2‐alkoxyquinoline‐type ligands is key to... 
Ligand design | C–H activation | Palladium | Amines | Acetoxylation | DIRECTING GROUP | C-H ACETOXYLATION | ACTIVATION | PD(II)-CATALYZED OLEFINATION | ACIDS | BOND FUNCTIONALIZATION | CHEMISTRY, ORGANIC | UNACTIVATED C(SP)-H | REDUCTIVE ELIMINATION | CATALYZED ARYLATION | C-H activation
Journal Article
Chemical Communications, ISSN 1359-7345, 2019, Volume 55, Issue 49, pp. 7049 - 7052
A palladium catalyzed selective C(sp(3))-H arylation and acetoxylation of alcohols using a practical bidentate auxiliary were developed. Masked alcohols were... 
DIRECTING GROUPS | FUNCTIONALIZATION | OXIDATION | KETONES | AMINES | STRATEGY | VERSATILITY | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 02/2018, Volume 83, Issue 4, pp. 2448 - 2454
Pd-catalyzed acetoxylation of gamma-C(sp(3))-H bonds directed by Bts-protected amines using inexpensive PhI(OAc)(2) as oxidant is reported. The Bts-protecting... 
FUNCTIONALIZATION | ACID-DERIVATIVES | EFFICIENT SYNTHESES | NATIVE CHEMICAL LIGATION | CHEMISTRY, ORGANIC | CARBON-HYDROGEN BONDS | C(SP)-H | INHIBITOR | C-H ACTIVATION | AUXILIARY
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 07/2017, Volume 359, Issue 13, pp. 2235 - 2240
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 04/2019, Volume 2019, Issue 15, pp. 2635 - 2638
First‐time use of a palladium(II)–thiadiazole catalyst in the allylic oxidation of terminal olefins to linear allylic acetates. Employing this strategy, a... 
Ligands | Palladium | Allylic oxidation | Alkenes | Regioselectivity | ALLYLIC ACETOXYLATION | OXIDATION | PD(II) | ALKYLATION | COMPLEXES | CHEMISTRY, ORGANIC | C-H AMINATION | ISOCHROMANS | Palladium catalysts | Usage | Olefins
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 09/2016, Volume 358, Issue 17, pp. 2739 - 2744
Journal Article