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Angewandte Chemie International Edition, ISSN 1433-7851, 02/2014, Volume 53, Issue 9, pp. 2477 - 2480
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2014, Volume 53, Issue 41, pp. 11065 - 11069
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2017, Volume 56, Issue 40, pp. 12288 - 12291
Utilizing halogens as traceless directing goups represents an attractive strategy for C−H functionalization. A two C−H alkylation system, initiated by the... 
alkylation | palladium | C−H activation | arenes | cyclization | DOMINO REACTION | INTRAMOLECULAR ARYLATION | BIS-ANNELATED BENZENES | BOND FORMATION | N BOND | CHEMISTRY, MULTIDISCIPLINARY | DIRECTING GROUPS | FUNCTIONALIZATION | C-H activation | ARYL CHLORIDES | PROTON-ABSTRACTION MECHANISM | Palladium | Carbon-carbon composites | Halides | Halogens | Chemical bonds | Biocompatibility | Activation | Alkylation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2018, Volume 57, Issue 15, pp. 4058 - 4062
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2014, Volume 136, Issue 5, pp. 1789 - 1792
The direct alkylation of unactivated sp3 C–H bonds of aliphatic amides was achieved via nickel catalysis with the assist of a bidentate directing group. The... 
PALLADIUM | CROSS-COUPLING REACTIONS | STEREOSPECIFIC FORMATION | SN BONDS | ACTIVATION | C-H BOND | O BOND | NEUTRAL ENDOPEPTIDASE | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS | Chemical bonds | Nickel | Research | Analysis | Alkylation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2014, Volume 53, Issue 44, pp. 11950 - 11954
The alkylation of unactivated β‐methylene C(sp3)H bonds of α‐amino acid substrates with a broad range of alkyl iodides using Pd(OAc)2 as the catalyst is... 
alkylation | CH activation | palladium | synthetic methods | amino acids | DIRECTING GROUP | HALIDES | ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | PALLADIUM-CATALYZED ALKYLATION | FUNCTIONALIZATION | CROSS-COUPLING REACTIONS | C-H activation | AMINO-ACIDS | STEREOSELECTIVE-SYNTHESIS | Amino acids | Synthesis | Iodides | Strategy | Transformations | Compatibility | Arrays | Bonding | Alkylation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2019, Volume 58, Issue 6, pp. 1823 - 1827
Herein we report a highly selective photoredox C(sp3)−H alkylation/arylation of ethers through the combination of a photo‐organocatalyst (benzaldehyde) and a... 
alkylation | benzaldehyde | photoredox reaction | arylation | nickel catalysis | CARBON | LIGHT | PHOTOCHEMISTRY | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | Aldehydes | Nickel | Catalysis | Ethers | Alkylation | Benzaldehyde
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2018, Volume 57, Issue 20, pp. 5858 - 5862
The site‐selective functionalization of unactivated C(sp3)−H bonds remains one of the greatest challenges in organic synthesis. Herein, we report on the... 
alkylation | palladium | peptides | palladacycles | site selectivity | C(SP)-H BONDS | ACTIVATION | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | CATALYZED ARYLATION | DIRECTING GROUPS | FUNCTIONALIZATION | UNACTIVATED C(SP)-H BONDS | STEREOSELECTIVE-SYNTHESIS | Hydrogen bonds | Oligopeptides | Peptides | Amino acids | Activation | Palladium | Bonding | Alkylation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2014, Volume 53, Issue 21, pp. 5410 - 5413
The first catalytic and enantioselective CH alkylation of ferrocene derivatives with various alkenes was achieved. A cationic iridium complex, having a chiral... 
enantioselectivity | iridium | alkylation | CH activation | synthetic methods | C-H activation | PALLADIUM | ACTIVATION | COMPLEX | ASYMMETRIC-SYNTHESIS | ACIDS | BOND FORMATION | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | CH activation | KINETIC RESOLUTION | REDOX | 1,4-ADDITION | Alkenes | Cationic | Ferrocenes | Ligands | Activation | Derivatives | Dienes | Bonding | Alkylation
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2017, Volume 23, Issue 37, pp. 8814 - 8817
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2019, Volume 58, Issue 12, pp. 4002 - 4006
The synthetic utility of tertiary amines to oxidatively generate α‐amino radicals is well established, however, primary amines remain challenging because of... 
amines | reaction mechanisms | radicals | photochemistry | synthetic methods | ACIDS | ALPHA-AMINOALKYL RADICALS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | ATOM | FUNCTIONALIZATION | ABSTRACTION | ADDITION-REACTIONS | ARENECARBONITRILES | ALIPHATIC-AMINES | PHOTOCHEMICAL-REACTIONS | Side reactions | Divergence | Amines | Alkenes | Sulfonamides | Selectivity | Catalysis | Derivatives |