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Angewandte Chemie International Edition, ISSN 1433-7851, 01/2017, Volume 56, Issue 1, pp. 46 - 48
Versatile C−H insertions: Novel protocols for metal‐carbene insertions using diazo compounds have been recently developed. Application of the respective... 
C−H functionalization | carbenes | palladium | diazo compounds | rhodium | ALPHA-DIAZOCARBONYL COMPOUNDS | ORGANIC-SYNTHESIS | CATALYZED REACTIONS | CYCLOPROPANATION | DIAZO-COMPOUNDS | C-H functionalization | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | MIGRATORY INSERTION | Diazo compounds | Chemical bonds | Palladium | Catalysis | Rhodium | Metals
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 50, pp. 16013 - 16017
A rhodium(II)‐ or copper(I)‐catalyzed formal intramolecular carbene insertion into vinylic C(sp2)−H bonds is reported herein. This method provides... 
metal carbenes | indenes | insertion | diazo compounds | N-tosylhydrazones | REAGENTS | METAL-CARBENE | EFFICIENT SYNTHESIS | DIAZO-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | FUNCTIONALIZATION | HYDROGEN | CROSS-COUPLING REACTIONS | CONSTRUCTION | Rhodium | Insertion | Copper
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2016, Volume 55, Issue 22, pp. 6530 - 6534
The first examples of the direct functionalization of non‐activated aryl sp2 C−H bonds with ethyl diazoacetate (N2CHCO2Et) catalyzed by Mn‐ or Fe‐based... 
iron | C−H activation | arenes | carbene | manganese | C-H activation | OXIDATION | ALPHA-DIAZOCARBONYL COMPOUNDS | ORGANIC-SYNTHESIS | BUCHNER REACTION | ACTIVATION | GOLD CATALYSIS | COMPLEXES | DIAZO-COMPOUNDS | C-H FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | ETHYL DIAZOACETATE | Catalysts | Dimethyl | Aromatic compounds | Iron | Bonding | Manganese | Alkylbenzenes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2017, Volume 56, Issue 41, pp. 12557 - 12560
The imidazolium chloride [C3H3N(C3H6NMe2)N{C(Me)(=NDipp)}]Cl (1; Dipp=2,6‐diisopropyl phenyl), a potential precursor to a tritopic NimineCNHCNamine pincer‐type... 
nickel | alkylation | pincer ligands | oxidative addition | N-heterocyclic carbenes | COORDINATION CHEMISTRY | ACTIVATION | TRANSITION-METAL-COMPLEXES | OLEFIN POLYMERIZATION | DINUCLEAR | IRON | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | HETEROCYCLIC CARBENE COMPLEXES | CATALYSTS | Nickel | Ethylene | Chloride | Hydrogen bonds | Precursors | Chemical bonds | Ligands | Alkylation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2012, Volume 51, Issue 42, pp. 10633 - 10637
Highly reactive gold vinylidene species are used for intermolecular C(sp3)H insertions into unactivated alkanes (see scheme). In addition, they can be... 
dual activation | gold | CH activation | benzocyclobutenes | vinylidenes | C-H activation | CATALYZED SYNTHESIS | METHYLENECYCLOPROPANES | C?H activation | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | REARRANGEMENT | DUAL-ACTIVATION | CARBENES | CYCLOISOMERIZATION | 2+2 CYCLOADDITION | GENERATION | DIYNES | Vinylidene | Gold | Cascades | Alkylidene | Insertion | Alkanes | Derivatives | Carbenes
Journal Article
Organic Letters, ISSN 1523-7060, 09/2017, Volume 19, Issue 17, pp. 4472 - 4475
N-Radical initiated aminosulfonylation of unactivated C­(sp3)–H bond through insertion of sulfur dioxide in the presence of visible light is reported. O-Aryl... 
BORONIC ACIDS | NITROGEN-CENTERED RADICALS | POTASSIUM METABISULFITE | COUPLED ELECTRON-TRANSFER | ONE-POT | 3-COMPONENT REACTION | SULFONE SYNTHESIS | CHEMISTRY, ORGANIC | PALLADIUM-CATALYZED AMINOSULFONYLATION | SURROGATE DABSO | C-H BONDS
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 07/2012, Volume 354, Issue 10, pp. 1902 - 1908
An efficient method for the synthesis of nitrogen heterocycles containing a cyclic amidine moiety has been developed. The process involves palladium‐catalyzed... 
CH activation | palladium | isocyanides | heteroaromatic compounds | cycloamidination | C-H activation | AMIDINES | ANNULATION | CHEMISTRY, ORGANIC | C?H activation | CYTOTOXIC ACTIVITY | CARBONYLATION | PALLADIUM-CATALYZED SYNTHESIS | CARBON-MONOXIDE | ARYL HALIDES | ANTIMALARIAL ACTIVITY | INHIBITORS | CHEMISTRY, APPLIED | DERIVATIVES | Synthesis | Accessibility | Aniline | Insertion | Activation | Derivatives | Catalysis
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2018, Volume 24, Issue 10, pp. 2360 - 2364
A general efficient and site‐selective cobalt‐catalyzed insertion of isonitrile into C−H and N−H bonds of arylamides through C−H bond activation and alcohol... 
amides | cobalt | C−H bond activation | heterocycles | isonitrile | Amides | Cobalt | Bonds | Hydrogen bonds | Migration | Insertion | Chelation | Reaction mechanisms | Alcohols
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 5/2013, Volume 42, Issue 12, pp. 5257 - 5269
As valuable C1 building blocks, isocyanides represent an important class of reactive species and synthons. During the past decades, exhaustive efforts have... 
RADICAL ANNULATIONS | CASCADE REACTIONS | PALLADIUM-CATALYZED SYNTHESIS | CARBON-MONOXIDE | 3-COMPONENT REACTION | SYNTHETIC REACTIONS | ARYL HALIDES | TERMINAL ALKYNES | C-H ACTIVATION | CONCISE SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | Insertion | Oxidation | Catalysis | Catalysts | Carbenes
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2019, Volume 25, Issue 40, pp. 9485 - 9490
A novel synthesis of indanes and dihydronaphtalenes based on the intramolecular insertion into C(sp3)−H bonds of gold(I) carbenes generated by retro‐Buchner... 
carbenes | indanes | decarbenation | gold catalysis | C−H insertion | ACTIVATION | NATURAL-PRODUCTS | COMPLEXES | BOND FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | GOLD(I) CARBENES | C-H insertion | RETRO-BUCHNER REACTION | GENERATION | ACCESS | ALKANES | Deuterium | Insertion | Gold | Isotope effect | Carbenes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2019, Volume 58, Issue 30, pp. 10110 - 10113
Journal Article