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Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 44, pp. 13872 - 13875
A practical method is presented for ring opening various indoles and benzofurans with concomitant stereoselective silylation using readily generated (diphenyl‐tert‐butylsilyl... 
indoles | transition-metal-free reactions | benzofuran | silylation | dearomatization | ACTIVATION | REAGENTS | STEREOSPECIFIC SYNTHESIS | TRIMETHYLSILICONIDE ANIONS | ALLYLSILANES | C-H SILYLATION | CHEMISTRY, MULTIDISCIPLINARY | CYCLIC ENOL ETHERS | AROMATIC HETEROCYCLES | STEREOSELECTIVE-SYNTHESIS | BOND SILYLATION | Metal catalysts | Fracture mechanics | Catalysts | Metals | Phenols | Lithium | Ductile-brittle transition | Indoles | Catalysis | Ring opening
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 30, pp. 8723 - 8727
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2014, Volume 53, Issue 32, pp. 8471 - 8474
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2016, Volume 55, Issue 21, pp. 6319 - 6323
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2018, Volume 140, Issue 4, pp. 1502 - 1507
We report the silylation of primary C–H bonds located β to secondary and tertiary alcohols by exploiting perfluorinated esters as traceless directing groups... 
DIRECTING GROUPS | FUNCTIONALIZATION | OXIDATION | ACTIVATION | CATALYZED ENANTIOSELECTIVE SILYLATION | NATURAL-PRODUCTS | SYNTHETIC APPLICATIONS | C(SP)-H | AMINE DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 12, pp. 3233 - 3237
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2016, Volume 55, Issue 1, pp. 236 - 239
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2018, Volume 140, Issue 51, pp. 18032 - 18038
The functionalization of unactivated C­(sp3)–H bonds of aliphatic amines catalyzed by transition-metal complexes is important because amine-based functionality... 
FUNCTIONALIZATION | ACTIVATION | ENANTIOSELECTIVE SILYLATION | DEHYDROGENATIVE SILYLATION | ARYLATION | NITROGEN | UNACTIVATED C(SP)-H | REGIOSELECTIVE SILYLATION | DIRECTING-GROUP | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 9, pp. 3204 - 3207
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 44, pp. 13859 - 13862
Journal Article
Tetrahedron, ISSN 0040-4020, 08/2019, Volume 75, Issue 31, pp. 4059 - 4070
.... Our group has developed a series of silylations of primary C–H bonds that occur with site selectivity and diastereoselectivity resulting from an approach to run the reactions as intramolecular processes... 
Natural product | Oxidation | Iridium | Silylation | C–H bond functionalization | ACTIVATION | DIRECTED HYDROXYLATION | HYDROSILANES | CHEMISTRY, ORGANIC | REGIOSELECTIVE SILYLATION | C-H bond functionalization | FUNCTIONALIZATION | INTERMOLECULAR SILYLATION | DIVERGENT | GERMANYLATION | BORYLATION | Bonds | Catalysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2008, Volume 47, Issue 39, pp. 7508 - 7510
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2018, Volume 57, Issue 17, pp. 4769 - 4773
Journal Article