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Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 19, pp. 5263 - 5266
Both aryl components of diaryliodonium salts can be used in a domino one‐pot reaction via in situ generation of a directing group. A number of heterocycles... 
C–H activation | iodonium compounds | N-heterocycles | arylation | IODONIUM SALTS | ONE-POT SYNTHESIS | COMPLEXES | CARBAZOLES | H BOND FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | TOSYLATES | C-H activation | CONSTRUCTION | IODINE REAGENTS | ARYL CHLORIDES | C-H
Journal Article
Science, ISSN 0036-8075, 02/2017, Volume 355, Issue 6324, pp. 499 - 503
The enzymatic beta-C-H hydroxylation of the feedstock chemical isobutyric acid has enabled the asymmetric synthesis of a wide variety of polyketides. The... 
FUNCTIONALIZATION | C(SP)-H BONDS | MILD CONDITIONS | C-H ARYLATION | BETA-HYDROXYISOBUTYRIC ACID | MULTIDISCIPLINARY SCIENCES | INDOLINES | BOND ACTIVATION | ISOBUTYRIC ACID | LIGAND | AUXILIARY | Isobutyric acid | Enzymes | Synthesis (chemistry) | Asymmetry | Catalysts | Chemical bonds | Ligands | Palladium
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2014, Volume 53, Issue 15, pp. 3868 - 3871
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2016, Volume 55, Issue 31, pp. 9084 - 9087
Herein, we report the palladium‐catalyzed direct arylation of unactivated aliphatic C−H bonds in free primary amines. This method takes advantage of an... 
palladium catalysis | C−H activation | directing groups | primary amines | arylation | ROOM-TEMPERATURE | C(SP)-H BONDS | PALLADIUM | NITROGEN-HETEROCYCLES | UNACTIVATED C(SP)-H | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | FUNCTIONALIZED MOLECULES | C-H activation | ALIPHATIC-AMINES | ETHER SYNTHESIS | Aniline | Palladium | Catalysis
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2012, Volume 18, Issue 15, pp. 4480 - 4484
All CH bonds are not equal: The intramolecular arylation of unactivated C(sp3)H bonds in the presence of a chiral Pd/binepine catalyst allows the synthesis... 
CH activation | palladium | asymmetric catalysis | CC coupling | C-C coupling | C-H activation | ORGANIC-SYNTHESIS | C(SP)-H BONDS | CHIRAL LIGANDS | QUATERNARY STEREOCENTERS | BOND FUNCTIONALIZATION | INDOLINES | C?H activation | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | C?C coupling | DISCOVERY | ALKANE ARYLATION | Catalysts | Palladium | Synthesis | Organic chemistry | Chemical Sciences
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2018, Volume 57, Issue 40, pp. 13288 - 13292
Reported herein is an unprecedented copper‐catalyzed arylation of remote C(sp3)−H bonds. Stirring a trifluorotoluene solution of either N‐fluorocarboxamides or... 
C−H functionalization | cross-coupling | copper | homogeneous catalyst | radicals | ACID DERIVATIVES | ROOM-TEMPERATURE | ALKYLATION | INTRAMOLECULAR FUNCTIONALIZATION | C-H functionalization | INTERMOLECULAR TRIFLUOROMETHYLARYLATION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | UNACTIVATED ALKENES | 1,4-EPIMINE COMPOUNDS | AMINATION | Copper compounds | Copper | Sulfonamides | Hydrogen | Catalysis | Sodium | Acids
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2016, Volume 138, Issue 44, pp. 14554 - 14557
Pd­(II)-catalyzed γ-C­(sp3)–H arylation of primary amines is realized by using 2-hydroxy­nicotinaldehyde as a catalytic transient directing group. Importantly,... 
FUNCTIONALIZATION | UNACTIVATED C(SP)-H BONDS | C(SP)-H BONDS | PALLADIUM | ACTIVATION | AMINATION | NITROGEN-HETEROCYCLES | ALIPHATIC-AMINES | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | Amines - chemistry | Molecular Structure | Catalysis | Palladium - chemistry | Alkylation | Chemical reactions | Usage | Palladium | Amines | Chemical properties
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2017, Volume 23, Issue 58, pp. 14450 - 14453
Herein we describe the auxiliary‐directed arylation of unactivated C(sp3)−H bonds with aryldiazonium salts, which proceeds under synergistic photoredox and... 
palladium | C−H activation | photoredox | metallaphotoredox | arylation | AMIDATION | CARBON-HYDROGEN BONDS | SINGLE-ELECTRON TRANSMETALATION | CHEMISTRY, MULTIDISCIPLINARY | ALIPHATIC AMIDES | C-H activation | C-H ARYLATION | NICKEL | ARYL HALIDES | OXIDATIVE CYCLIZATION | C(SP)-H | DUAL CATALYSIS | Amides | Palladium | Catalysis | Salts | Quaternary | Selectivity | Aliphatic compounds
Journal Article