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catalysis (91) 91
science & technology (82) 82
chemistry (80) 80
physical sciences (80) 80
c-h activation (76) 76
silylation (54) 54
palladium (51) 51
c−h activation (50) 50
chemistry, multidisciplinary (42) 42
activation (38) 38
aromatic compounds (38) 38
ch activation (37) 37
functionalisation (31) 31
funktionalisierung (31) 31
catalysts (30) 30
synthesis (30) 30
hydrogen bonds (28) 28
iridium (26) 26
silylierung (26) 26
c‐h‐aktivierung (25) 25
c–h activation (24) 24
organic chemistry (24) 24
regioselectivity (24) 24
rhodium (24) 24
katalyse (22) 22
ruthenium (22) 22
substrates (22) 22
chemistry, organic (21) 21
ligands (21) 21
derivatives (20) 20
selectivity (20) 20
silicon (20) 20
bonding (19) 19
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oxidation (18) 18
chemical synthesis (17) 17
dehydrogenation (17) 17
homogeneous catalysis (16) 16
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chemistry, physical (15) 15
enantiomers (15) 15
natural products (15) 15
alkynes (14) 14
c-h-aktivierung (14) 14
hydrogen (14) 14
nitrogen (14) 14
functional groups (13) 13
ligand (13) 13
reagents (13) 13
strategy (13) 13
heterocycles (12) 12
silane (12) 12
stereoisomerism (12) 12
transition metals (12) 12
borylation (11) 11
coupling (11) 11
organic compounds (11) 11
silanes (11) 11
asymmetric catalysis (10) 10
c-h functionalization (10) 10
catalytic c-h activation (10) 10
electrons (10) 10
nickel (10) 10
alkylation (9) 9
arylierung (9) 9
asymmetrische katalyse (9) 9
c-h bond activation (9) 9
carbon dioxide (9) 9
chemical sciences (9) 9
c−h functionalization (9) 9
functional-group (9) 9
funktionelle gruppe (9) 9
hydrosilylation (9) 9
nachwachsender rohstoff (9) 9
natural-products (9) 9
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synthetic methods (9) 9
aldehydes (8) 8
amides (8) 8
arenes (8) 8
carbon - chemistry (8) 8
c–h functionalization (8) 8
elektron (8) 8
enantioselektivität (8) 8
hydrogen - chemistry (8) 8
hydrogen bonding (8) 8
molecular structure (8) 8
oxidation-reaction (8) 8
silicium (8) 8
totalsynthese (8) 8
wasserstoff (8) 8
alkenes (7) 7
chelation (7) 7
chemical tests and reagents (7) 7
enantio-selectivity (7) 7
heterocyclen (7) 7
homogene katalyse (7) 7
hydrocarbons (7) 7
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1. Full Text Rhodium‐Catalyzed Enantioselective Silylation of Cyclopropyl C−H Bonds
by Lee, Taegyo and Hartwig, John F
Angewandte Chemie (International ed.), ISSN 1433-7851, 07/2016, Volume 55, Issue 30, pp. 8723 - 8727
cyclopropanes | asymmetric catalysis | C−H activation | silylation | rhodium | Cyclopropanes - chemistry | Silanes - chemistry | Stereoisomerism | Catalysis | Hydrogen - chemistry | Carbon - chemistry | Rhodium - chemistry | Rhodium | Enantiomers | Index Medicus | C-H activation | cyclopropane
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2. Full Text Electrophilic Aromatic Substitution with Silicon Electrophiles: Catalytic Friedel–Crafts C−H Silylation
by Bähr, Susanne and Oestreich, Martin
Angewandte Chemie (International ed.), ISSN 1433-7851, 01/2017, Volume 56, Issue 1, pp. 52 - 59
C−H functionalization | cations | homogeneous catalysis | electrophilic aromatic substitution | Si−H activation | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | Substitution reactions | Silicon | Catalysis | Protons | Aromatic compounds | Chemical bonds | Protonation | Intermediates
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3. Full Text Anchoring of Silyl Donors on a N‐Heterocyclic Carbene through the Cobalt‐Mediated Silylation of Benzylic CH Bonds
by Mo, Zhenbo and Liu, Yang and Deng, Liang
Angewandte Chemie (International ed.), ISSN 1433-7851, 10/2013, Volume 52, Issue 41, pp. 10845 - 10849
hydrosilylation | CH activation | cobalt | silylation | carbene complexes | C-H activation | Catalysts | Olefins | Activation | Hydrosilylation | Selectivity | Carbenes | Cobalt | Anchoring
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4. Full Text Experimental and Computational Studies on Remote γ‑C(sp3)–H Silylation and Germanylation of Aliphatic Carboxamides
by Deb, Arghya and Singh, Sukriti and Seth, Kapileswar and Pimparkar, Sandeep and Bhaskararao, Bangaru and Guin, Srimanta and Sunoj, Raghavan B and Maiti, Debabrata
ACS catalysis, ISSN 2155-5435, 12/2017, Volume 7, Issue 12, pp. 8171 - 8175
germanylation | organopalladium crystal | mechanistic studies | DFT | silylation | γ-C-H activation | Physical Sciences | Chemistry | Chemistry, Physical | Science & Technology
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5. Full Text Iridium‐Catalyzed Regioselective Silylation of Aromatic and Benzylic CH Bonds Directed by a Secondary Amine
by Li, Qian and Driess, Matthias and Hartwig, John F
Angewandte Chemie (International ed.), ISSN 1433-7851, 08/2014, Volume 53, Issue 32, pp. 8471 - 8474
iridium | oxidation | CH activation | arenes | silane | C-H activation | Amines | Aniline | Dehydrogenation | Halogenation | Joining | Oxidation | Derivatives | Organic compounds
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6. Full Text Experimental and Computational Exploration of para‐Selective Silylation with a Hydrogen‐Bonded Template
by Maji, Arun and Guin, Srimanta and Feng, Sheng and Dahiya, Amit and Singh, Vikas Kumar and Liu, Peng and Maiti, Debabrata
Angewandte Chemie (International ed.), ISSN 1433-7851, 11/2017, Volume 56, Issue 47, pp. 14903 - 14907
regioselectivity | reaction mechanisms | hydrogen bonding | C−H activation | silylation | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology | GABA | Enzymes | Hydrogen | Hydrogen bonding | Analysis | Toluene | Regioselectivity | Toxicity | Selectivity | Mimicry | Lipophilic | γ-Aminobutyric acid | Computation | Computer applications | Biocompatibility | Silicon | Reaction mechanisms | Functional groups
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7. Full Text Scandium‐Catalyzed Silylation of Aromatic CH Bonds
by Oyamada, Juzo and Nishiura, Masayoshi and Hou, Zhaomin
Angewandte Chemie (International ed.), ISSN 1433-7851, 11/2011, Volume 50, Issue 45, pp. 10720 - 10723
CH activation | hydrosilanes | scandium | silylation | anisoles | C-H activation | Physical Sciences | Chemistry | Chemistry, Multidisciplinary | Science & Technology
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8. Full Text Rhodium‐Catalyzed Intramolecular C−H Silylation by Silacyclobutanes
by Zhang, Qing‐Wei and An, Kun and Liu, Li‐Chuan and Guo, Shuangxi and Jiang, Chenran and Guo, Huifang and He, Wei
Angewandte Chemie (International ed.), ISSN 1433-7851, 05/2016, Volume 55, Issue 21, pp. 6319 - 6323
β-hydrogen elimination | C−H activation | metallocycle | silylation | silole | C-H activation | Chemical tests and reagents | Hydrogen | Catalysis | Chemical bonds | Rhodium | Hydrogen bonds | Reagents | Organometallic compounds
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9. Full Text Revealing Silylation of C(sp2)/C(sp3)–H Bonds in Arylphosphines by Ruthenium Catalysis
by Wen, Jian and Dong, Ben and Zhu, Jinjun and Zhao, Yue and Shi, Zhuangzhi
Angewandte Chemie (International ed.), ISSN 1433-7851, 06/2020, Volume 59, Issue 27, pp. 10909 - 10912
C−H activation | silylation | site selectivity | coordination | phosphorus | Ruthenium | Chelation | Phosphorus | Selectivity | Catalysis | Functional groups | Ruthenium compounds | Index Medicus
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10. Full Text Divergent Synthesis of Silicon-Containing Peptides via Pd-Catalyzed Post-Assembly γ‑C(sp3)–H Silylation
by Zhan, Bei-Bei and Fan, Jun and Jin, Liang and Shi, Bing-Feng
ACS catalysis, ISSN 2155-5435, 04/2019, Volume 9, Issue 4, pp. 3298 - 3303
palladium | peptides | C-H activation | silylation | amino acids | Physical Sciences | Chemistry | Chemistry, Physical | Science & Technology
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