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CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 11/2016, Volume 22, Issue 47, pp. 16733 - 16748
In recent years, much interest has been paid to difluoromethylthiolated molecules as the "SCF2" moiety is a key motif in drug and agrochemical research.... 
REAGENT | difluoromethylthiolation | S-DIFLUOROMETHYLATION | C-NUCLEOPHILES | DIFLUOROCARBENE PRECURSOR | CHEMISTRY, MULTIDISCIPLINARY | MEDICINAL CHEMISTRY | DIFLUOROMETHYL ETHERS | TRIFLUOROMETHYLTHIOLATION | sulfur | ALPHA-FLUORINATED ETHERS | difluoromethylation | ARYL | THIOETHERS | synthetic methods | fluorine
Journal Article
Chemical Science, ISSN 2041-6520, 2018, Volume 9, Issue 26, pp. 5781 - 5786
Direct introduction of a difluoromethylthio group (-SCF2H) to arenes represents an efficient route to access a valuable catalogue of organofluorines; however,... 
REAGENT | DIFLUOROMETHYLATION | DIFLUOROCARBENE | AMINES | CATALYST-FREE | ALPHA-FLUORINATED ETHERS | C-NUCLEOPHILES | ARYL IODIDES | THIOETHERS | CHEMISTRY, MULTIDISCIPLINARY | DISULFIDES
Journal Article
Organic Letters, ISSN 1523-7060, 05/2017, Volume 19, Issue 10, pp. 2758 - 2761
A simple and efficient visible-light photoredox one-pot method for difluoromethylation of phenols and thiophenols has been developed. The protocol uses... 
MEDICINAL CHEMISTRY | CATALYSIS | DECARBOXYLATIVE COUPLINGS | ETHERS | DIAZONIUM SALTS | DIFLUOROCARBENE | AMINO-ACIDS | SYNTHETIC APPLICATIONS | CHEMISTRY, ORGANIC | C-NUCLEOPHILES | ARYL
Journal Article
by Yan, Q and Jiang, LQ and Yi, WB and Liu, QR and Zhang, W
ADVANCED SYNTHESIS & CATALYSIS, ISSN 1615-4150, 07/2017, Volume 359, Issue 14, pp. 2471 - 2480
Journal Article
Chemical science, ISSN 2041-6520, 06/2016, Volume 7, Issue 6, pp. 3757 - 3762
A palladium-catalyzed difluoromethylthiolation of heteroaryl halides and triflates under mild conditions was described. A vast range of heteroaryl halides such... 
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 01/2015, Volume 56, Issue 2, pp. 283 - 295
The copper-catalyzed propargylic substitution reaction has become a powerful synthetic method to prepare the compounds containing the propargylic subunit.... 
N-Nucleophiles | Copper | Asymmetric catalysis | Propargylic substitution | C-Nucleophiles | ALKYLATION | CHEMISTRY, ORGANIC | ALCOHOLS | AMINATION | BETA-KETOESTERS | COUPLING REACTIONS | AMINES | ESTERS | ACETATES | SYSTEMS | METAL | Cycloaddition | Tetrahedrons | Handles | Selectivity | Sulfur | Nucleophiles | Carbon
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2013, Volume 52, Issue 47, pp. 12390 - 12394
Two‐in‐one: Me3SiCF2Br is an efficient difluorocarbene source and is compatible with both neutral and aqueous basic conditions. Bromide‐ion‐initiated [2+1]... 
carbenes | cycloaddition | heterocycles | synthetic methods | fluorine | REAGENT | ACID | TFDA | C-NUCLEOPHILES | DIFLUOROCARBENE PRECURSOR | CYCLOPROPENES | CHEMISTRY, MULTIDISCIPLINARY | ALPHA-FLUORINATED ETHERS | GEM-DIFLUOROCYCLOPROPANES | GENERATION | DERIVATIVES
Journal Article
Organic Letters, ISSN 1523-7060, 08/2015, Volume 17, Issue 15, pp. 3802 - 3805
The difluoromethylation of terminal alkynes through the use of fluoroform as a source of difluorocabene is described. The choice of solvents and bases was... 
NUCLEOPHILIC TRIFLUOROMETHYLATION | EFFICIENT PRECURSOR | DIRECT CUPRATION | ENANTIOSELECTIVE FLUORINATION | BOND-FORMING REACTIONS | ELECTROGENERATED BASE | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | CUCF3 | C-NUCLEOPHILES | ALDEHYDES
Journal Article
Chemical Science, ISSN 2041-6520, 01/2018, Volume 9, Issue 26, pp. 5781 - 5786
Direct introduction of a difluoromethylthio group (–SCF2H) to arenes represents an efficient route to access a valuable catalogue of organofluorines; however,... 
Additives | Light irradiation | Noble metals | Access routes | Aromatic compounds | Reagents
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 33, pp. 10547 - 10553
Journal Article
Organic Letters, ISSN 1523-7060, 07/2016, Volume 18, Issue 14, pp. 3354 - 3357
Siladifluoromethylations and difluoromethylations on sp3, sp2, and sp carbons of lithiated carbamates, arenes, and terminal alkynes, respectively, have been... 
NUCLEOPHILIC TRIFLUOROMETHYLATION | ORGANOZINC REAGENTS | SP CARBON | DIFLUOROPROPARGYL BROMIDES | BUILDING-BLOCKS | COPPER-MEDIATED DIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | FUNCTIONAL-GROUPS | BOND ACTIVATION | C-NUCLEOPHILES
Journal Article
Chemical Science, ISSN 2041-6520, 2016, Volume 7, Issue 6, pp. 3757 - 3762
A palladium-catalyzed difluoromethylthiolation of heteroaryl halides and triflates under mild conditions was described. A vast range of heteroaryl halides such... 
MEDICINAL CHEMISTRY | REAGENT | HALIDES | DIRECT DIFLUOROMETHYLATION | HETEROCYCLES | ARYLATION | COMPLEXES | ALPHA-FLUORINATED ETHERS | C-NUCLEOPHILES | THIOETHERS | CHEMISTRY, MULTIDISCIPLINARY | Iodides | Aromatic compounds | Searching | Halides | Chemists | Bromides | Palladium | Lead compounds
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2016, Volume 55, Issue 51, pp. 15807 - 15811
A new shelf‐stable and easily scalable difluoromethylthiolating reagent S‐(difluoromethyl) benzenesulfonothioate (PhSO2SCF2H) was developed. PhSO2SCF2H is a... 
reaction mechanisms | decarboxylation | radicals | synthetic methods | fluorine | DIFLUOROCARBENE | C-NUCLEOPHILES | CHEMISTRY, MULTIDISCIPLINARY | MEDICINAL CHEMISTRY | DIFLUOROMETHYLATION | ETHERS | TRIFLUOROMETHYLTHIOLATION | HETEROCYCLES | ARYL | ALIPHATIC CARBOXYLIC-ACIDS | THIOETHERS | Chemical tests and reagents | Fluorides
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2015, Volume 54, Issue 26, pp. 7648 - 7652
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 04/2018, Volume 59, Issue 14, pp. 1301 - 1308
In the past few years, organic chemists have made significant contributions to the development of difluoromethylation and difluoromethylenation of carbon... 
CF2 carbene | Difluoromethylation | Difluoroolefination | Fluoroalkylation | carbene | DIFLUOROMETHYLATED ARENES | ACIDS | COMPLEXES | CHEMISTRY, ORGANIC | DIFLUORINATED PHOSPHONIUM SALTS | DIAZO-COMPOUNDS | C-NUCLEOPHILES | ORGANOZINC REAGENTS | ACYL CHLORIDES | BROMODIFLUOROACETATE | TRIFLUOROMETHYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 02/2013, Volume 15, Issue 4, pp. 917 - 919
Journal Article
Beilstein Journal of Organic Chemistry, ISSN 1860-5397, 02/2014, Volume 10, Issue 1, pp. 344 - 351
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 03/2014, Volume 55, Issue 11, pp. 1913 - 1915
In the course of our syntheses of functionalised pyridine and quinoline derivatives, we examined the reactivities of pyridine and quinoline -oxides towards the... 
Quinoline | Pyridine | N-Oxide | Coupling agents | C-nucleophiles | CONVERSION | CHEMISTRY, ORGANIC | AMIDES | Oxides | Anhydrides | Pyridines | Tetrahedrons | Activation | Derivatives | Nucleophiles | Carbon | Organic chemistry | Chemical Sciences
Journal Article
Synthetic Communications, ISSN 0039-7911, 09/2016, Volume 46, Issue 17, pp. 1397 - 1416
Ring-opening reactions of oxetanes yield important functionalized products depending upon the nature of nucleophiles as well as substitution pattern on the... 
oxetanes | ring-opening reactions | C-nucleophiles | heterocycles | nucleophiles | ANIONIC-POLYMERIZATION | CHEMISTRY, ORGANIC | POLYADDITION | 3-ETHYL-3-(HYDROXYMETHYL)OXETANE | EPOXIDES | CHLOROMETHYL GROUPS | QUATERNARY ONIUM SALTS | PENDANT HYDROXYL-GROUPS | POLYETHER | STEREOSELECTIVE-SYNTHESIS | BIS(OXETANE)S
Journal Article
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