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c-sp3-h bonds (32) 32
chemistry, organic (30) 30
chemistry, multidisciplinary (29) 29
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ketones (7) 7
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Angewandte Chemie International Edition, ISSN 1433-7851, 10/2015, Volume 54, Issue 44, pp. 13049 - 13052
Journal Article
Organic Letters, ISSN 1523-7060, 06/2017, Volume 19, Issue 11, pp. 2793 - 2796
The Iodine-mediated oxidative intramolecular amination of anilines via cleavage of unactivated (sp 3)­C–H and N–H bonds for the production of indolines is... 
C-SP3-H BONDS | C(SP)-H BONDS | VISIBLE-LIGHT | COUPLING REACTIONS | CATALYZED C(SP)-H | MECHANISTIC INSIGHTS | CHEMISTRY, ORGANIC | FORMING REACTIONS | C-H AMINATION | METHYL KETONES | PD(II)-CATALYZED AMINATION
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 07/2016, Volume 358, Issue 15, pp. 2422 - 2426
Journal Article
by Xiao, XS and Hou, C and Zhang, ZH and Ke, ZF and Lan, JY and Jiang, HF and Zeng, W
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 09/2016, Volume 55, Issue 39, pp. 11897 - 11901
For the first time, a highly regioselective intermolecular sulfonylamidation unactivated secondary Csp(3)-H bond has been achieved using IrIII catalysts. The... 
C-SP3-H BONDS | C(SP)-H BONDS | ACTIVATION | tosyl azides | COMPLEXES | iridium catalysis | COPPER | CHEMISTRY, MULTIDISCIPLINARY | sulfonylamidation | nitrene insertion | C(sp)-H activation | NITROGEN-SOURCE | C-H AMINATION | CATALYZED INTRAMOLECULAR AMINATION | INSIGHTS
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2018, Volume 16, Issue 36, pp. 6655 - 6658
An efficient Cu-catalyzed method for direct C-N bond formation on the C-3 position of imidazo[1,2-a]pyridines is reported. The robust copper catalyst tolerated... 
Journal Article
by Qiu, GYS and Wu, J
ORGANIC CHEMISTRY FRONTIERS, ISSN 2052-4129, 2015, Volume 2, Issue 2, pp. 169 - 178
This review is focused on the recent advances in the transition metal-catalyzed direct remote C-H-functionalization of alkyl groups via C(sp(3))-H bond... 
C-SP3-H BONDS | ACID DERIVATIVES | PALLADIUM | DIRECT ARYLATION | CHEMISTRY, ORGANIC | ELECTRON-DEFICIENT ARENES | BETA-KETO-ESTERS | CARBON-HYDROGEN BONDS | LIGAND | INTERMOLECULAR ARYLATION
Journal Article
RSC ADVANCES, ISSN 2046-2069, 12/2019, Volume 9, Issue 71, pp. 41684 - 4172
Cross-dehydrogenative coupling reactions between two unmodified C-H bonds are one of the most attractive and fundamental strategies for the construction of C-C... 
EFFICIENT HETEROGENEOUS CATALYST | GOLD NANOPARTICLES | C-SP3-H BONDS | COPPER NANOPARTICLES | TERTIARY-AMINES | NANO-CATALYSTS | TERMINAL ALKYNES | RECYCLABLE CATALYST | CHEMISTRY, MULTIDISCIPLINARY | HIGHLY EFFICIENT | CARBOXYLIC-ACIDS | Chemical reactions | Cross coupling | Dehydrogenation | Bonding | Substrates | Covalent bonds
Journal Article
Chemical Communications, ISSN 1359-7345, 03/2016, Volume 52, Issue 19, pp. 3758 - 3761
A practical approach to radical C-H bond functionalization by the photolysis of a hypervalent iodine(III) reagent is presented. The photolysis of... 
UNACTIVATED C-SP3-H BONDS | CENTERED RADICALS | ALCOHOLS | FREE OXIDATIVE ESTERIFICATION | CHEMISTRY | BENZYLIC-ACETOXYLATION | ARYL | REDUCTIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | HETEROAROMATIC BASES | CARBOXYLIC-ACIDS | Benzene - chemistry | Iodine - chemistry | Photolysis | Indicators and Reagents - chemistry
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2017, Volume 82, Issue 24, pp. 13542 - 13549
A kinetic study on the hydrogen atom transfer (HAT) reactions from the aliphatic C–H bonds of a series of 1-Z-pentyl, 1-Z-propyl, and Z-cyclohexyl derivatives... 
UNACTIVATED C-SP3-H BONDS | SELECTIVE OXIDATION | COMPLEX | CONTAINING MOLECULES | ABSTRACTION REACTIONS | METHYLENIC SITES | CHEMISTRY, ORGANIC | IRON CATALYST | ALKOXYL RADICALS | ABSOLUTE RATE CONSTANTS | LATE-STAGE FUNCTIONALIZATION
Journal Article
by Sun, K and Mu, SQ and Liu, ZH and Feng, RR and Li, YL and Pang, K and Zhang, B
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 09/2018, Volume 16, Issue 36, pp. 6655 - 6658
An efficient Cu-catalyzed method for direct C-N bond formation on the C-3 position of imidazo[1,2-a]pyridines is reported. The robust copper catalyst tolerated... 
C-SP3-H BONDS | AMINO KETONES | METAL-FREE CONDITIONS | STRATEGY | CHEMISTRY, ORGANIC | H AMINATION | REGIOSELECTIVE SULFENYLATION | IMIDAZOPYRIDINES | DEHYDROGENATIVE COUPLING REACTION | IMIDAZOHETEROCYCLES | IMIDATION
Journal Article
Organic Letters, ISSN 1523-7060, 05/2018, Volume 20, Issue 9, pp. 2720 - 2723
Substituted N-cyclohexyl amides undergo aliphatic C–H bond oxidation with H2O2 catalyzed by manganese complexes. The reactions are directed by torsional... 
UNACTIVATED C-SP3-H BONDS | STRAIN RELEASE | FUNCTIONALIZATION | NONHEME IRON | ACTIVATION | HYDROXYLATION | CHEMISTRY, ORGANIC | ENHANCED REACTIVITY | RADICALS | EFFICIENT | ATOM TRANSFER
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 02/2016, Volume 52, Issue 19, pp. 3758 - 3761
A practical approach to radical C-H bond functionalization by the photolysis of a hypervalent iodine(iii) reagent is presented. The photolysis of... 
Photolysis | Reagents | Alkylbenzene | Esters | Transformations | Bonding | Radicals | Alkylbenzenes
Journal Article
Acta Chimica Sinica, ISSN 0567-7351, 01/2017, Volume 75, Issue 1, pp. 15 - 21
In recent years, visible-light-promoted photoredox catalytic activation of organic molecules has been flourishing vigorously. This kind of methodology usually... 
Green chemistry | Toluene derivatives | Visible light photoredox | H bond activation | OXIDATION | HYDROGEN EVOLUTION REACTION | DEHYDROGENATIVE-COUPLING REACTION | STRATEGY | ARYLATION | green chemistry | AROMATIZATION | CHEMISTRY, MULTIDISCIPLINARY | C-sp3-H bond activation | C-H BONDS | toluene derivatives | PHOTOREDOX CATALYSIS | visible light photoredox | EFFICIENT
Journal Article
Nature Communications, ISSN 2041-1723, 09/2015, Volume 6, Issue 1, p. 8404
The past decade has witnessed significant advances in C-H bond functionalizations with the discovery of new mechanisms. Non-precious transition-metal-catalysed... 
C-SP3-H BONDS | FUNCTIONALIZATION | C(SP)-H BONDS | ROUTE | ELECTRON | C-H BOND | TOLUENE DERIVATIVES | MULTIDISCIPLINARY SCIENCES | OXIDATIVE ACTIVATION | ARYLATION | Nickel - chemistry | Amino Acids, Aromatic - chemistry | Chemistry Techniques, Synthetic
Journal Article
RSC Advances, ISSN 2046-2069, 07/2015, Volume 5, Issue 85, pp. 69119 - 69123
An efficient di-tert-butyl peroxide (DTBP) promoted synthesis of oxindole has been developed. This methodology involves C(sp(3))-H and C(sp(2))-H bond... 
C-SP3-H CENTERS | 3,3-DISUBSTITUTED OXINDOLES | ENANTIOSELECTIVE SYNTHESIS | CARBENE LIGANDS | ALPHA-ARYLATION | NATURAL-PRODUCTS | N-ARYLACRYLAMIDES | SULFONATED OXINDOLES | C-H ACTIVATION | CATALYTIC ASYMMETRIC-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic & Biomolecular Chemistry, ISSN 1477-0520, 2015, Volume 13, Issue 2, pp. 447 - 451
A highly efficient catalytic asymmetric alkynylation of prochiral CH2 groups in tetrahydroisoquinoline was developed using copper catalyzed... 
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 01/2015, Volume 13, Issue 2, pp. 447 - 451
A highly efficient catalytic asymmetric alkynylation of prochiral CH2 groups in tetrahydroisoquinoline was developed using copper catalyzed... 
C-SP3-H BONDS | SP C-H | ELECTRON-TRANSFER | VISIBLE-LIGHT PHOTOCATALYSIS | ENANTIOSELECTIVE SYNTHESIS | TERTIARY-AMINES | OXIDATIVE ACTIVATION | CHEMISTRY, ORGANIC | BONDS ADJACENT | DUAL-CATALYSIS | HIGHLY EFFICIENT
Journal Article
Chemical Science, ISSN 2041-6520, 01/2018, Volume 9, Issue 11, pp. 2873 - 2878
Transition metal-free intramolecular hydride transfer onto arynes is reported for the first time. This unique transformation is utilized in redox-neutral... 
Deuterium | Chemical reactions | Hydrides | Amines | Hydrogen bonds | Dehydrogenation
Journal Article
Chemical science, ISSN 2041-6520, 10/2017, Volume 8, Issue 10, pp. 7180 - 7185
We report a unified photoredox-catalysis strategy for both hydroxylation and amidation of tertiary and benzylic C-H bonds. Use of hydroxyl... 
Journal Article