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Green Chemistry, ISSN 1463-9262, 2016, Volume 18, Issue 24, pp. 6545 - 6555
...=O can decrease the beta-O-4 bond dissociation energy (BDE) from 274.0 kJ mol(-1) to 227.8 kJ mol(-1), and thus the beta-O-4 bond is more readily cleaved in the subsequent transfer hydrogenation, or acidolysis... 
GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | SELECTIVE OXIDATION | ORGANOSOLV LIGNIN | KRAFT LIGNIN | VALUABLE CHEMICALS | C-O BONDS | ARYL ETHERS | MODEL COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | HETEROGENEOUS NICKEL-CATALYSTS | MOLYBDENUM CARBIDE CATALYST | PHENOLIC MONOMERS | Sulfides | Catalysts | Chemical bonds | Phenols | Cleavage | Ethers | Bonding | Radicals
Journal Article
Green chemistry : an international journal and green chemistry resource : GC, ISSN 1463-9262, 2016, Volume 18, Issue 24, pp. 6545 - 6555
... (BDE) from 274.0 kJ mol−1 to 227.8 kJ mol−1, and thus the β-O-4 bond is more readily cleaved in the subsequent transfer hydrogenation, or acidolysis... 
Journal Article
Science (American Association for the Advancement of Science), ISSN 0036-8075, 11/2013, Volume 342, Issue 6162, pp. 1076 - 1080
Asymmetric hydrogenation of alkenes is one of the most widely used methods for the preparation of single enantiomer compounds, especially in the pharmaceutical and agrochemical industries... 
Base metals | Pyridines | Alkenes | Catalysts | REPORTS | Ligands | Alkanes | Iridium | Enantiomers | Cobalt | Phosphines | REDUCTION | LIGANDS | MECHANISM | C=O | MULTIDISCIPLINARY SCIENCES | AMINO-ACID DERIVATIVES | COMPLEXES | Alkenes - chemistry | Small Molecule Libraries - analysis | Small Molecule Libraries - chemistry | High-Throughput Screening Assays | Phosphines - chemistry | Stereoisomerism | Hydrogenation | Cobalt - chemistry | Usage | Olefins | Properties | Methods | Studies | Catalysis | Metallurgy | Asymmetry | Precursors | Iron
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2013, Volume 52, Issue 8, pp. 2231 - 2234
Journal Article
Green Chemistry, ISSN 1463-9262, 07/2017, Volume 19, Issue 13, pp. 2876 - 2924
.... The modified catalysts have been also applied to the selective hydrogenation of carbonyl and carboxyl groups, which are also common functional groups in biomass-derived building blocks. This review deals with the performance, the structure of the active sites, and the reaction mechanism over the catalysts with direct bonds between noble metal particles and metal oxide species. 
Metal oxides | Catalysts | Hydrogenolysis | Noble metals | Catalysis | Oxygen content | Bonding | Hydrogenation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2019, Volume 58, Issue 4, pp. 1129 - 1133
Herein, we report on the use of the iron pincer complex Iron‐MACHO‐BH, in the base‐free transfer hydrogenation of esters with EtOH as a hydrogen source... 
iron | transfer hydrogenation | ester compounds | base-free | ethanol | ASYMMETRIC TRANSFER HYDROGENATION | DEPOLYMERIZATION | FUTURE | CHEMISTRY, MULTIDISCIPLINARY | KETONES | REDUCTION | LIGANDS | C=O | BONDS | RUTHENIUM COMPLEXES | Hydrogen storage | Ethanol | Esters | Iron | Polyester resins | Hydrogenation | Substrates | Aliphatic compounds | Alcohols | Lactones | Polyesters | Hydrogen ion concentration | Diols
Journal Article
Green Chemistry, ISSN 1463-9262, 7/2017, Volume 19, Issue 13, pp. 2876 - 2924
.... The modified catalysts have been also applied to the selective hydrogenation of carbonyl and carboxyl groups, which are also common functional groups in biomass... 
IR-RE CATALYSTS | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | PTMO BIMETALLIC CATALYSTS | AQUEOUS-PHASE HYDROGENATION | PROPYLENE-GLYCOL | GLYCEROL HYDROGENOLYSIS | C-O BOND | ION-EXCHANGE-RESIN | SUCCINIC ACID | CHEMOSELECTIVE HYDROGENOLYSIS | CHEMISTRY, MULTIDISCIPLINARY | TETRAHYDROFURFURYL ALCOHOL
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2016, Volume 55, Issue 48, pp. 15175 - 15179
The use of abundantly available transition metals in reactions that have been preferentially mediated by rare noble metals, for example, hydrogenations, is a desirable aim in catalysis... 
imines | nitroarenes | benzimidazoles | cobalt catalysis | hydrogenation | CARBON | ALKYLATION | DEHYDROGENATIVE CONDENSATION | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | NITRO-COMPOUNDS | AMINES | CHEMOSELECTIVE HYDROGENATION | COBALT CATALYST | C=O BONDS | GOLD CATALYSTS | Schiff bases | Catalysis | Aldehydes | Metal catalysts | Cobalt | Hydrogenation | Chemical industry
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 2010, Volume 254, Issue 5, pp. 729 - 752
Journal Article
Journal of Catalysis, ISSN 0021-9517, 02/2019, Volume 370, pp. 107 - 117
...), with impregnation method (IM) as contrast, to study the difference in the interfacial structure induced by the preparation methods and the catalytic behavior for selective hydrogenation of 2-ethylanthraquinone... 
Selective hydrogenation of C[dbnd]O Bonds | Layered double hydroxide | Metal-hydroxide interface | Sandwich structure | Oxygen vacancy | ACETYLENE | PERFORMANCE | DISPERSION | CHEMISTRY, PHYSICAL | MIXED-OXIDE | HYDROTALCITE | ENGINEERING, CHEMICAL | NANOPARTICLES | CATALYTIC-OXIDATION | Selective hydrogenation of C=O Bonds | ATOMIC LAYER DEPOSITION | Palladium catalysts | Hydroxides | Adsorption | Hydrogen | Hydrogenation
Journal Article