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DALTON TRANSACTIONS, ISSN 1477-9226, 2010, Volume 39, Issue 4, pp. 1046 - 1054
TheAZn(2)Sb(2)(P (3) over bar m1, A = Ca, Sr, Eu, Yb) class of Zintl compounds has shown high thermoelectric efficiency (zT similar to 1) and is an appealing... 
CAAL2SI2 | EFFICIENCY | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
JOURNAL OF APPLIED PHYSICS, ISSN 0021-8979, 02/2012, Volume 111, Issue 3
Single crystals of CaZn2Sb2, EuZn2Sb2, and YbZn2Sb2 were grown from melts of nominal composition AZn(5)Sb(5) (A =Ca,Eu,Yb) with the excess melt being removed... 
PHYSICS, APPLIED | THERMOELECTRIC-MATERIALS | CAAL2SI2 | CACD2SB2
Journal Article
Chemistry of Materials, ISSN 0897-4756, 10/2014, Volume 26, Issue 19, pp. 5710 - 5717
Classically, Zintl phases are defined as valence-precise line compounds and are thus expected to exhibit intrinsic semiconducting behavior. Contradicting this... 
TRANSITION | CAAL2SI2 | MATERIALS SCIENCE, MULTIDISCIPLINARY | SOLID-SOLUTIONS | CHEMISTRY | CHEMISTRY, PHYSICAL | CRYSTAL | METAL | CHAINS | THERMAL-CONDUCTIVITY | EFFICIENCY | CACD2SB2
Journal Article
Journal of Alloys and Compounds, ISSN 0925-8388, 05/2017, Volume 703, pp. 73 - 79
Zn Sb ( : Ca, Sr, Eu, Yb) Zintl compounds have shown excellent thermoelectric performance peaking around 700 K. Among these materials, EuZn Sb and YbZn Sb... 
CHEMISTRY, PHYSICAL | CA1-XEUXZN2SB2 | PERFORMANCE | CAAL2SI2 | MATERIALS SCIENCE, MULTIDISCIPLINARY | METALLURGY & METALLURGICAL ENGINEERING
Journal Article
Scientific Reports, ISSN 2045-2322, 12/2018, Volume 8, Issue 1, pp. 1 - 10
According to an earlier Abrikosov model, a positive, nonsaturating, linear magnetoresistivity (LMR) is expected in clean, low-carrier-density metals when... 
MULTIDISCIPLINARY SCIENCES | Magnetic fields | Metals | Low temperature
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 13, pp. 3422 - 3426
Experimentally, AZn2Sb2 samples (A=Ca, Sr, Eu, Yb) are found to have large charge carrier concentrations that increase with increasing electronegativity of A.... 
defect formation | electronic transport | phase stability | Zintl phases | THERMOELECTRIC-MATERIALS | CAAL2SI2 | ELECTRONEGATIVITY | COMPOUND | CHEMISTRY | EFFICIENCY | CHEMISTRY, MULTIDISCIPLINARY | Specific gravity
Journal Article
Nature Communications, ISSN 2041-1723, 12/2018, Volume 9, Issue 1, pp. 1 - 10
The Mg3Sb2 structure is currently being intensely scrutinized due to its outstanding thermoelectric properties. Usually, it is described as a layered Zintl... 
ZINTL PHASES | PERFORMANCE | CAAL2SI2 | MULTIDISCIPLINARY SCIENCES | PROGRAM | EXPANSION | Thermal properties | Organic chemistry | Interlayers | Thermoelectric materials | Anisotropy | Chemical bonds | Thermal conductivity | Magnesium | Electron density | Thermodynamic properties | Physical properties | Bonding
Journal Article
Journal of Solid State Chemistry, ISSN 0022-4596, 02/2019, Volume 270, pp. 346 - 359
Chemical combinations of metals with group 15 elements result in compounds demonstrating a plethora of crystal structures. Many such compounds, referred to as... 
Pnictides | Transition metal | Zintl phases | Crystal structure | PHYSICAL-PROPERTIES | 5TH MAIN-GROUP | CRYSTAL-STRUCTURE | CHEMISTRY, PHYSICAL | TEMPERATURE THERMOELECTRIC PROPERTIES | CHEMISTRY, INORGANIC & NUCLEAR | RARE-EARTH | CAAL2SI2 STRUCTURE | EARTH TITANIUM ANTIMONIDES | MAGNETIC-PROPERTIES | AB2X2 COMPOUNDS | TERNARY INTERMETALLIC PHASES
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 2010, Volume 39, Issue 4, pp. 1063 - 1070
Two new Zintl compounds Ba2Cd2As3 and Ba2Cd2Sb3 have been synthesized and structurally characterized. They crystallize in a novel monoclinic structure type... 
TRANSITION | CHALCOGENIDES | THERMOELECTRIC-MATERIALS | CRYSTAL-STRUCTURE | CAAL2SI2 STRUCTURE | YB14MN1-XALXSB11 | AB2X2 COMPOUNDS | COLORING PROBLEM | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 2015, Volume 44, Issue 46, pp. 20254 - 20264
A homologous series of ternary rare-earth zinc arsenides, prepared by reactions of the elements at 750 degrees C, has been identified with the formula... 
DESIGN | MEMBERS | CHEMISTRY | CAAL2SI2 STRUCTURE | AB2X2 COMPOUNDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry of Materials, ISSN 0897-4756, 02/2017, Volume 29, Issue 3, pp. 1236 - 1244
We explored the role of valence electron concentration in bond formation and superconductivity of mixed silicon–aluminum networks by using high-pressure... 
TRANSITION | CAAL2SI2 TYPE-STRUCTURE | ARSENIDES | CRYSTAL-STRUCTURE | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY | CHEMISTRY, PHYSICAL | BAAL4 | SILICIDES | STABILITY RANGE | MODEL | SOLID-STATE
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 02/2012, Volume 51, Issue 4, pp. 2621 - 2628
The ternary arsenides A(2)Zn(2)As(3) and the quaternary derivatives A(2)Ag(2)ZnAs(3) (A = Sr, Eu) have been prepared by stoichiometric reaction of the elements... 
A-EU | CRYSTAL-STRUCTURE | ZINTL PHASES | CAAL2SI2 STRUCTURE | MAGNETIC-PROPERTIES | AB2X2 COMPOUNDS | COLOSSAL MAGNETORESISTANCE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 11/2011, Volume 50, Issue 21, pp. 11152 - 11161
Ternary rare-earth zinc arsenides REZn3As3 (RE = La–Nd, Sm) with polymorphic modifications different from the previously known defect CaAl2Si2-type forms, and... 
REFINEMENT | PHYSICAL-PROPERTIES | COVELLITE | CAFE4AS3 | CADMIUM | CRYSTAL-STRUCTURE | COMPLEXES | CAAL2SI2 STRUCTURE | AB2X2 COMPOUNDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
INORGANIC CHEMISTRY FRONTIERS, ISSN 2052-1553, 08/2018, Volume 5, Issue 8, pp. 1744 - 1759
Compounds that crystallize in the layered CaAl2Si2 structural pattern have rapidly emerged as an exciting class of thermoelectric materials with attractive n-... 
ELECTRONIC-PROPERTIES | CAAL2SI2 TYPE-STRUCTURE | PERFORMANCE | MAIN-GROUP | ZINTL PHASE-COMPOUNDS | DEFECT CHEMISTRY | BREAKING BONDS | STABILITY RANGE | AB2X2 COMPOUNDS | THERMAL-CONDUCTIVITY | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 09/2011, Volume 50, Issue 17, pp. 8375 - 8383
Reported are two new series of Zintl phases, ACd4 Pn 3 and AZn4 Pn 3 (A = Na, K, Rb, Cs; Pn = As, P), whose structures feature complex atomic arrangements... 
SUPERCONDUCTIVITY | THERMOELECTRIC-MATERIALS | CRYSTAL-STRUCTURE | RARE-EARTH | CAAL2SI2 STRUCTURE | DENSITY-FUNCTIONAL THEORY | AB2X2 COMPOUNDS | PHOSPHIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
by Lin, XS and Mar, A
INORGANIC CHEMISTRY, ISSN 0020-1669, 06/2013, Volume 52, Issue 12, pp. 7261 - 7270
Four series of ternary rare-earth zinc arsenides have been prepared by reaction of the elements at 750 C: RE4Zn2-xAs5 forming for RE = La-Nd, Sm; and... 
TRANSITION | EU | STACKING VARIANTS | CAAL2SI2 | STABILITY | CRYSTAL | MODEL | AB2X2 COMPOUNDS | PHOSPHIDES | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Materials Science and Engineering A, ISSN 0921-5093, 01/2007, Volume 444, Issue 1-2, pp. 157 - 169
Journal Article
MONATSHEFTE FUR CHEMIE, ISSN 0026-9247, 09/2014, Volume 145, Issue 9, pp. 1381 - 1387
The ternary pnictides Li3LaX (2) (X = P, As, Sb, Bi) were synthesized by the reaction of the elements in sealed niobium ampoules in a resistance furnace. The... 
Pnictides | Solid-state NMR | LI-7 | LI12SI7 | Crystal chemistry | Lithium | CAAL2SI2 STRUCTURE | DIFFRACTION | RAY | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 08/2014, Volume 53, Issue 16, pp. 8431 - 8441
Two series of Mn-substituted rare-earth zinc arsenides RE1-yMnxZn2-xAs2 (RE = Eu-Lu) and RE2-yMnxZn4-xAs4 (RE = La-Nd, Sm, Gd) were prepared by reaction of the... 
SUPERCONDUCTIVITY | CAAL2SI2 TYPE-STRUCTURE | CRYSTAL-STRUCTURE | TRANSITION-METAL | THERMOELECTRIC PROPERTIES | RAY PHOTOELECTRON-SPECTRA | CHEMISTRY | STABILITY RANGE | AB2X2 COMPOUNDS | PNICTIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, ISSN 0932-0784, 04/2018, Volume 73, Issue 4, pp. 285 - 293
Pnictogen-based Zintl compounds have fascinating properties. Nowadays these compounds have gained exceptional interest in thermoelectric and opto-electronic... 
Band Structure | PHYSICS, MULTIDISCIPLINARY | THERMOELECTRIC-MATERIALS | CRYSTAL-STRUCTURE | ZINTL PHASES | CHEMISTRY, PHYSICAL | CAAL2SI2 STRUCTURE | Reflection | Zintl Compounds | AB2X2 COMPOUNDS
Journal Article
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