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carbanions (18) 18
chemistry (13) 13
chemistry, multidisciplinary (10) 10
chemistry, organic (10) 10
derivatives (8) 8
polymer science (8) 8
spectroscopy (8) 8
carbanion pump (7) 7
catalysis (7) 7
chemistry, analytical (7) 7
anionic polymerization (5) 5
organic chemistry (5) 5
analytical chemistry (4) 4
biochemical research methods (4) 4
kinetics (4) 4
polymers (4) 4
polystyrene (4) 4
acid (3) 3
acidities (3) 3
acids (3) 3
aldehydes (3) 3
alkyl carbanions (3) 3
alkylation (3) 3
anionic-polymerization (3) 3
anions (3) 3
bioinformatics (3) 3
biotechnology (3) 3
carbanion (3) 3
chemistry, physical (3) 3
cyclization (3) 3
design (3) 3
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generation (3) 3
heterocycles (3) 3
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ketones (3) 3
mass-spectrometry (3) 3
polymerization (3) 3
proteomics (3) 3
silacyclobutane (3) 3
addition polymerization (2) 2
alkaloids (2) 2
analysis (2) 2
anions - chemistry (2) 2
asymmetric catalysis (2) 2
asymmetric-synthesis (2) 2
block copolymers (2) 2
carbonyl-compounds (2) 2
catalysts (2) 2
collision-induced dissociation (2) 2
cyclisation (2) 2
decarboxylation (2) 2
diblock copolymers (2) 2
diphenylethylene (2) 2
heterocyclic-compounds (2) 2
inorganic chemistry (2) 2
ions (2) 2
ketoprofen (2) 2
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lithium-salts (2) 2
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photochemistry (2) 2
physical chemistry (2) 2
polymer sciences (2) 2
reaction mechanisms (2) 2
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reagents (2) 2
ring-opening polymerization (2) 2
singlet (2) 2
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stereoisomerism (2) 2
styrene (2) 2
sulfamerazine - chemistry (2) 2
sulfur (2) 2
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water - chemistry (2) 2
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1,1-bisalkadienes (1) 1
1,1‐bisalkadienes (1) 1
1-bisalkadienes (1) 1
2-his-1-carboxylate facial triad (1) 1
2-vinyloxyethylisothiocyanate (1) 1
4h-chromene (1) 1
9,10-bisanthracene (1) 1
9,10‐bisanthracene (1) 1
[m – 2h + na] – ions (1) 1
[m-2h+na] ions (1) 1
abschrecken (1) 1
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Polymer journal, ISSN 0032-3896, 2004, Volume 36, Issue 10, pp. 856 - 865
... (carbanion pump efficiency) was studied in the presence of diphenylethylene. Combination of a silacyclobutane with potassium counter ion was the most effective among the silacycles studied (1:1 molar ratio... 
Alkaline Metal Alkoxide | Silacycle | Diphenylethylene | Silacyclobutane | Carbanion Pump | Block Copolymer | Anionic Polymerization | silacycle | diphenylethylene | block copolymer | carbanion pump | POLYMER SCIENCE | alkaline metal alkoxide | silacyclobutane | anionic polymerization
Journal Article
Macromolecules, ISSN 0024-9297, 05/2007, Volume 40, Issue 10, pp. 3784 - 3789
A new class of metal-containing diblock copolymers, PFS-b-P2VP (PFS = poly(ferrocenyldimethylsilane), P2VP = poly(2-vinylpyridine)), with a hydrophobic... 
CRYSTALLIZATION | POLYMERS | POLYMER SCIENCE | PHASE-BEHAVIOR | ANIONIC-POLYMERIZATION | CARBANION PUMP | DIPHENYLETHYLENE | WALLED CARBON NANOTUBES | ORGANOMETALLIC BLOCK-COPOLYMERS | MICELLAR MORPHOLOGIES | POLYFERROCENE BLOCK
Journal Article
Macromolecules, ISSN 0024-9297, 03/2004, Volume 37, Issue 5, pp. 1720 - 1727
An efficient synthesis is described of diblock copolymers from [1]dimethylsilaferrocenophane (FS) and methyl methacrylate (MMA). First, living anionic... 
THIN-FILMS | DIBLOCK COPOLYMERS | POLYMER SCIENCE | HOMOPOLYMER BLENDS | SILICON-BRIDGED FERROCENOPHANES | RING-OPENING POLYMERIZATION | CARBANION PUMP | THERMOPLASTIC ELASTOMERS | MOLECULAR-WEIGHT POLY(METALLOCENES) | STRAINED METALLOCENOPHANES | TEMPLATES
Journal Article
Tetrahedron, ISSN 0040-4020, 01/2010, Volume 66, Issue 3, pp. 698 - 708
The addition of mono- and dianions of ethyl N-pivaloyl-3-aminocrotonate to substituted nitroarenes, followed by action of silylating or acylating agent, leads... 
Nitroso group | Heterocycles | Carbanions | Cyclisation | Nitroarenes | CORE | POTENTIATE | EFFLUX PUMP INHIBITORS | ALKYLATION | QUINOLINES | CHEMISTRY, ORGANIC | LEVOFLOXACIN | MEDIATED DIRECT CONDENSATION | FRIEDLANDER SYNTHESIS | DERIVATIVES | CYCLIZATION | Acylation
Journal Article
Journal of polymer science. Part A, Polymer chemistry, ISSN 0887-624X, 03/2011, Volume 49, Issue 6, pp. 1376 - 1386
Journal Article
2011, Advances in Polymer Science, ISBN 9783642160479, Volume 235, 49
Book Chapter
2015, 1st ed. 2015, ISBN 4431541853, 1075
This book examines a wide range of topics on anionic polymerization, from basic principles to experimental techniques important for practice. Coverage includes... 
Chemistry, Physical organic | Polymer Sciences | Chemistry | Physical Chemistry | Nanotechnology | Addition polymerization
eBook
Macromolecular Chemistry and Physics, ISSN 1022-1352, 06/2008, Volume 209, Issue 11, pp. 1106 - 1114
The paper describes the living anionic polymerization of styrenes to homo‐ and diblock copolymers in continuous flow, using a microstructured mixing set‐up... 
block copolymers | continuous flow | microreactor | polystyrene | anionic polymerization | Anionic polymerization | Microreactor | Polystyrene | Block copolymers | Continuous flow | POLYMERS | POLYMER SCIENCE | METHYL-METHACRYLATE | STYRENE | MICROMIXERS | MICROREACTORS | KINETICS | MOLECULAR-WEIGHT DISTRIBUTION | RADICAL POLYMERIZATION
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2013, Volume 355, Issue 16, pp. 3244 - 3252
The hitherto unreported ability of the methylsulfinyl carbanion (dimsyl anion) to generate acyl anion equivalents is described. The dimsyl anion, in fact,... 
mass spectrometry | carbanions | synthetic methods | CC coupling | C-C coupling | ASYMMETRIC-SYNTHESIS | CYANIDE ION | CHEMISTRY, ORGANIC | N-HETEROCYCLIC CARBENES | GAMMA-BUTYROLACTONES | CC coupling | KETONES | NUCLEOPHILIC ACYLATION | CONJUGATE UMPOLUNG | SELECTIVE SYNTHESIS | DIMETHYL-SULFOXIDE | CHEMISTRY, APPLIED | CARBON BOND FORMATIONS
Journal Article
European journal of organic chemistry, ISSN 1434-193X, 2010, Volume 2010, Issue 25, pp. 4893 - 4901
In the present study the abilities of catalysts modified by formamidine ligands have been examined in the zinc‐catalyzed hydrosilylation of ketones and the... 
Amidine ligands | Epoxidation | Iron | Hydrosilylation | Homogeneous catalysis | Zinc | ASYMMETRIC HYDROSILYLATION | ENANTIOSELECTIVE HYDROSILYLATION | CHIRAL LIGANDS | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | SAUREAMID-REAKTIONEN | KETONES | DIMOLYBDENUM COMPLEXES | REDUCTION | 2-HIS-1-CARBOXYLATE FACIAL TRIAD | ALPHA-AMINO CARBANIONS
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2011, Volume 17, Issue 13, pp. 3679 - 3692
The first catalytic asymmetric synthesis of β‐sultones is reported. This development has enabled a rapid access to a number of highly enantioenriched...