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Angewandte Chemie International Edition, ISSN 1433-7851, 06/2015, Volume 54, Issue 27, pp. 7891 - 7894
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2017, Volume 56, Issue 1, pp. 46 - 48
Versatile C−H insertions : Novel protocols for metal‐carbene insertions using diazo compounds have been recently developed. Application of the respective... 
C−H functionalization | carbenes | palladium | diazo compounds | rhodium | ALPHA-DIAZOCARBONYL COMPOUNDS | ORGANIC-SYNTHESIS | CATALYZED REACTIONS | CYCLOPROPANATION | DIAZO-COMPOUNDS | C-H functionalization | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | MIGRATORY INSERTION | Diazo compounds | Chemical bonds | Palladium | Catalysis | Rhodium | Metals
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 50, pp. 16013 - 16017
A rhodium(II)‐ or copper(I)‐catalyzed formal intramolecular carbene insertion into vinylic C(sp 2 )−H bonds is reported herein. This method provides... 
metal carbenes | tosylhydrazones | indenes | insertion | diazo compounds | N-tosylhydrazones | REAGENTS | METAL-CARBENE | EFFICIENT SYNTHESIS | DIAZO-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | FUNCTIONALIZATION | HYDROGEN | CROSS-COUPLING REACTIONS | CONSTRUCTION | Rhodium | Insertion | Copper
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2016, Volume 55, Issue 22, pp. 6530 - 6534
The first examples of the direct functionalization of non‐activated aryl sp 2 C−H bonds with ethyl diazoacetate (N 2 CHCO 2 Et) catalyzed by Mn‐ or Fe‐based... 
iron | C−H activation | arenes | carbene | manganese | C-H activation | OXIDATION | ALPHA-DIAZOCARBONYL COMPOUNDS | ORGANIC-SYNTHESIS | BUCHNER REACTION | ACTIVATION | GOLD CATALYSIS | COMPLEXES | DIAZO-COMPOUNDS | C-H FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | ETHYL DIAZOACETATE | Catalysts | Dimethyl | Aromatic compounds | Iron | Bonding | Manganese | Alkylbenzenes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2017, Volume 56, Issue 41, pp. 12557 - 12560
The imidazolium chloride [C 3 H 3 N(C 3 H 6 NMe 2 )N{C(Me)(=NDipp)}]Cl ( 1 ; Dipp=2,6‐diisopropyl phenyl), a potential precursor to a tritopic N imine C NHC N... 
nickel | alkylation | pincer ligands | oxidative addition | N-heterocyclic carbenes | COORDINATION CHEMISTRY | ACTIVATION | TRANSITION-METAL-COMPLEXES | OLEFIN POLYMERIZATION | DINUCLEAR | IRON | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | HETEROCYCLIC CARBENE COMPLEXES | CATALYSTS | Nickel | Ethylene | Chloride | Hydrogen bonds | Precursors | Chemical bonds | Ligands | Alkylation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2012, Volume 51, Issue 42, pp. 10633 - 10637
Highly reactive gold vinylidene species are used for intermolecular C(sp 3 )H insertions into unactivated alkanes (see scheme). In addition, they can be... 
dual activation | gold | CH activation | benzocyclobutenes | vinylidenes | C-H activation | CATALYZED SYNTHESIS | METHYLENECYCLOPROPANES | C?H activation | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | REARRANGEMENT | DUAL-ACTIVATION | CARBENES | CYCLOISOMERIZATION | 2+2 CYCLOADDITION | GENERATION | DIYNES | Vinylidene | Gold | Cascades | Alkylidene | Insertion | Alkanes | Derivatives | Carbenes
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 11/2016, Volume 22, Issue 45, pp. 16062 - 16065
A novel and highly efficient diazo‐OH insertion/Conia‐ene cascade reaction of readily available homopropargylic acids and alcohols with diazo carbonyl... 
cascade reactions | conia-ene | synergistic catalysis | diazo compounds | O−H insertion | GOLD | ONE-POT SYNTHESIS | O-H insertion | REACTIVITY | CARBENE/ALKYNE METATHESIS | ENANTIOSELECTIVE ADDITION | RHODIUM/COPPER CATALYSIS | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | CYCLIZATION | Stereoselectivity | Gold | Silver | Catalysts | Cascades | Tetrahydrofuran | Insertion | Alcohols
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2019, Volume 25, Issue 40, pp. 9485 - 9490
A novel synthesis of indanes and dihydronaphtalenes based on the intramolecular insertion into C(sp 3 )−H bonds of gold(I) carbenes generated by retro‐Buchner... 
carbenes | indanes | decarbenation | gold catalysis | C−H insertion | ACTIVATION | NATURAL-PRODUCTS | COMPLEXES | BOND FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | GOLD(I) CARBENES | C-H insertion | RETRO-BUCHNER REACTION | GENERATION | ACCESS | ALKANES | Deuterium | Insertion | Gold | Isotope effect | Carbenes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2014, Volume 53, Issue 11, pp. 2978 - 2981
A palladium‐catalyzed asymmetric OH insertion reaction was developed. Palladium complexes with chiral spiro bisoxazoline ligands promoted the insertion of... 
carbenes | palladium | asymmetric catalysis | bisoxazoline ligands | α‐aryl‐α‐aryloxyacetates | α-aryl-α-aryloxyacetates | CYCLOPROPANATION | alpha-aryl-alpha-aryloxyacetates | AGONISTS | CHEMISTRY, MULTIDISCIPLINARY | DIAZOCARBONYL COMPOUNDS | N-TOSYLHYDRAZONES | POTENT | HALO CARBOXYLIC-ACIDS | ESTERS | STEREOSELECTIVE-SYNTHESIS | INHIBITORS | DERIVATIVES
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 08/2012, Volume 45, Issue 8, pp. 1365 - 1377
Journal Article
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