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chemistry, multidisciplinary (226) 226
carbenes (197) 197
chemistry, organic (189) 189
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palladium (129) 129
migratory insertion (123) 123
diazo-compounds (112) 112
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activation (64) 64
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Angewandte Chemie International Edition, ISSN 1433-7851, 06/2015, Volume 54, Issue 27, pp. 7891 - 7894
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 42, pp. 13140 - 13144
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 04/2015, Volume 51, Issue 38, pp. 7986 - 7995
Cross-coupling reactions involving metal carbene migratory insertion have been established as a new type of coupling reaction with diazo compounds as the reaction partners... 
Insertion | Activation | Joining | Carbenes | Bonding
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2018, Volume 140, Issue 1, pp. 466 - 474
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2010, Volume 49, Issue 6, pp. 1139 - 1142
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 10, pp. 2716 - 2720
.... Migratory insertion of α‐oxo palladium carbene species, generated by intermolecular oxidation, is proposed as the key step in this reaction... 
carbenes | cross-coupling | oxidation | palladium | ynamides | TERMINAL ALKYNES | DIAZO-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | N-TOSYLHYDRAZONES | INTERMOLECULAR OXIDATION | CONJUGATED ENYNONES | METAL CARBENE | ENE-YNE-KETONES | OXO GOLD CARBENES | BOND | ACCESS | Hydrogenation | Palladium | Bromides | Insertion | Chemical reactions | Oxidation | Coupling
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2010, Volume 49, Issue 48, pp. 9182 - 9186
Making head or tail of it: The first single‐operation, highly selective intermolecular tail‐to‐tail hetero‐hydroalkenylation from two readily available... 
nickel | insertion | homogeneous catalysis | N‐heterocyclic carbenes | olefination | N-heterocyclic carbenes | 1,3-DIENES | SELECTIVE DIMERIZATION | INTERNAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | ETHYLENE | EFFICIENT | SIMPLE ALKENES | RUTHENIUM COMPLEX | CYCLIZATION | ASYMMETRIC HYDROVINYLATION | CONJUGATE ADDITION
Journal Article
ACS Catalysis, ISSN 2155-5435, 11/2013, Volume 3, Issue 11, pp. 2586 - 2598
Transition-metal-catalyzed cross-coupling reactions involving a carbene migratory insertion process have been developed rapidly during the past ten years... 
coupling reaction | catalysis | migratory insertion | cascade reaction | carbene | ALPHA-DIAZOCARBONYL COMPOUNDS | ORGANIC-SYNTHESIS | TANDEM CATALYSIS | CROSS-COUPLING REACTION | CHEMISTRY, PHYSICAL | TERMINAL ALKYNES | CARBONYL-COMPOUNDS | DIAZO-COMPOUNDS | N-TOSYLHYDRAZONES | ALLYL HALIDES | VINYL HALIDES
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2015, Volume 21, Issue 8, pp. 3215 - 3218
.... Herein, we report that metal coordinated DACs also exhibit electrophilic reactivity, undergoing attack by Zn and Cd dialkyl precursors to afford the migratory insertion products [(6‐MesDAC‐R)MR] (M=Zn, Cd; R=Et, Me; Mes=mesityl... 
carbenes | cadmium | migratory insertion | zinc | alkyl ligands | Cadmium | Carbenes | Alkyl ligands | Zinc | Migratory insertion | Ligands
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2013, Volume 135, Issue 36, pp. 13502 - 13511
Journal Article
ACS Catalysis, ISSN 2155-5435, 03/2017, Volume 7, Issue 3, pp. 1993 - 1997
.... Metal carbene migratory insertion and C­(sp2)–H bond activation are proposed as the key steps in this transformation... 
metal carbene | annulation | C-H activation | polycyclic aromatic hydrocarbons | Pd catalysis | ACTIVATION | REAGENTS | ALKYLATION | CHEMISTRY, PHYSICAL | DIAZO-COMPOUNDS | INDOLES | N-TOSYLHYDRAZONES | RH(III)-CATALYZED SYNTHESIS | ARYL | CYCLIZATION | ACCESS
Journal Article