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carbene-phosphinidene (10) 10
transition-metal-complexes (9) 9
chemistry, inorganic & nuclear (8) 8
chemistry, multidisciplinary (6) 6
coordination chemistry (5) 5
ligands (5) 5
phosphorus (5) 5
heterocyclic carbene-phosphinidene (4) 4
adducts (3) 3
arsenic-bridged complexes (3) 3
carbenes (3) 3
carbonyls (3) 3
gaussian-basis sets (3) 3
infrared spectroscopy (3) 3
infrared-spectra (3) 3
ligand (3) 3
phosphanylidene-phosphorane (3) 3
tin (3) 3
analysis (2) 2
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carben (2) 2
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chemistry (2) 2
chemistry, organic (2) 2
chromium (2) 2
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covalent radii (2) 2
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density-functional calculations (2) 2
generalized gradient approximation (2) 2
infrared-spectrometry (2) 2
ir-spektroskopie (2) 2
main-group compounds (2) 2
nuclear magnetic resonance spectroscopy (2) 2
nuclear magnetic resonance--nmr (2) 2
phosphaalkenes (2) 2
phosphinidenides (2) 2
phosphor (2) 2
phosphorus analogs (2) 2
ray crystal-structure (2) 2
ray crystal-structures (2) 2
reactivity (2) 2
reagent (2) 2
temperature (2) 2
terminal-phosphinidene complexes (2) 2
tungsten complexes (2) 2
1st isolated examples (1) 1
ab-initio (1) 1
adduct (1) 1
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Journal of the American Chemical Society, ISSN 0002-7863, 08/2018, Volume 140, Issue 30, pp. 9409 - 9412
The cyclic alkyl­(amino) carbene (cAAC) anchored silylene with two phosphinidenes was isolated as (cAAC)­Si­{P­(cAAC)}2 (3) at room temperature, which was... 
TRANSITION-METAL-COMPLEXES | ANALOG | TEMPERATURE | DIMER | COMPOUND | BOND FORMATION | ATOMS | CARBENE-PHOSPHINIDENE | ADDUCT | CATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 01/2020, Volume 26, Issue 1, pp. 192 - 197
Herein, the synthesis of new low-valent Group 14 phosphinidenide complexes [({SIDipp}P)(2)M] exhibiting P-M p pi-p pi interactions... 
phosphinidenides | REAGENT | phosphinidenes | PHOSPHORUS | CAGE COMPOUNDS | DENSITY-FUNCTIONAL CALCULATIONS | tetrylenes | TIN | CARBENE-PHOSPHINIDENE | CHEMISTRY, MULTIDISCIPLINARY | N-heterocyclic carbenes
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2018, Volume 140, Issue 1, pp. 151 - 154
The cyclic alkyl­(amino) carbene (cAAC) stabilized monoanionic phosphorus atom in the form of lithium phosphinidene [cAACPLi­(THF)2]2 (1) has been isolated as... 
DONATION | TRANSITION-METAL-COMPLEXES | TEMPERATURE | REACTIVITY | SODIUM PHOSPHAETHYNOLATE | ADDUCTS | CARBENE-PHOSPHINIDENE | NA(OCP) | LIGAND | BOND | CHEMISTRY, MULTIDISCIPLINARY | Phosphorus compounds | Chemical properties | Structure | Carbenes | Lithium compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2018, Volume 140, Issue 24, pp. 7466 - 7470
A room-temperature-stable crystalline phosphanorcaradiene 2 has been synthesized via a C–C bond forming strategy induced by the demetalation of a... 
1ST ISOLATED EXAMPLES | REARRANGEMENT | NORCARADIENE | PHOSPHORUS ANALOGS | AB-INITIO | CHEMISTRY | CARBENE-PHOSPHINIDENE | BENZENE OXIDE | TAUTOMERISM | CHEMISTRY, MULTIDISCIPLINARY | TERMINAL-PHOSPHINIDENE COMPLEXES
Journal Article
Dalton Transactions, ISSN 1477-9226, 2017, Volume 46, Issue 11, pp. 3556 - 3568
N, C, N-Chelated pnictinidenes ArE [where E = As (1), Sb (2) or Bi (3); Ar = C6H3-2,6-(CHvNt-Bu)(2)] were used as ligands for the coordination of transition... 
COORDINATION CHEMISTRY | CARBONYL-COMPLEXES | INFRARED-SPECTRA | DATIVE BONDS | TRANSITION-METAL-COMPLEXES | COVALENT RADII | RAY CRYSTAL-STRUCTURES | CARBENE-PHOSPHINIDENE | PHOSPHANYLIDENE-PHOSPHORANE | MAIN-GROUP COMPOUNDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 11/2017, Volume 46, Issue 48, pp. 17080 - 17092
We present the synthesis of a zwitterionic triphosphenium molecule, Bu(C H )(PPh ) P (L), which can act as a single- or multidentate ligand with group 6, 7, 8... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 2017, Volume 46, Issue 48, pp. 17080 - 17092
We present the synthesis of a zwitterionic triphosphenium molecule, tBu(C5H2)(PPh2)(2)P-I (L), which can act as a single-or multidentate ligand with group 6,... 
COORDINATION CHEMISTRY | CARBONYLS | CATALYSIS | HETEROCYCLIC CARBENE-PHOSPHINIDENE | ATOMS LI | TRANSITION-METAL-COMPLEXES | LIGANDS | TUNGSTEN COMPLEXES | GAUSSIAN-BASIS SETS | ARSENIC-BRIDGED COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | Bimetals | Nuclear magnetic resonance--NMR | Chemical bonds | Phosphorus | Dimers | Coordination compounds | Chemical synthesis | Carbonyls
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2019, Volume 25, Issue 19, pp. 4914 - 4919
Journal Article
Dalton Transactions, ISSN 1477-9226, 03/2017, Volume 46, Issue 11, pp. 3556 - 3568
N,C,N-Chelated pnictinidenes ArE [where E = As (1), Sb (2) or Bi (3); Ar = C6H3-2,6-(CH&z.dbd; Nt-Bu)2] were used as ligands for the coordination of transition... 
Infrared spectroscopy | Transition metals | Molecular structure | Chromium | Antimony | Ligands | NMR spectroscopy | Bonding
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 10/2013, Volume 52, Issue 19, pp. 11438 - 11449
Journal Article
Zeitschrift für anorganische und allgemeine Chemie, ISSN 0044-2313, 10/2018, Volume 644, Issue 19, pp. 1143 - 1148
A new way is presented to prepare group 14 compounds substituted with a terminal NHC stabilized phosphenidenyl substituent. On this occasion, it is shown that... 
Tin | N‐heterocyclic carbene | Phosphorus | Phosphaalkenes | Silicon | N-heterocyclic carbene | HETEROCYCLIC CARBENE-PHOSPHINIDENE | ENERGY | TRANSITION-METAL-COMPLEXES | APPROXIMATION | CRYSTAL | ADDUCTS | CHEMISTRY, INORGANIC & NUCLEAR | CROWN-ETHER | BASIS-SETS
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 09/2017, Volume 845, pp. 49 - 54
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 11/2013, Volume 32, Issue 21, pp. 6178 - 6181
A novel dimerization of maleic anhydride involving olefinic to carbonyl C-C coupling and an [1,7]-H shift is promoted by a strongly nucleophilic pyramidal... 
MULTICOMPONENT REACTIONS | DIMOLYBDENUM COMPLEX | CRYSTAL-STRUCTURE | BEHAVIOR | REACTIVITY | CHEMISTRY, ORGANIC | P-H | POLYMERIZATION | CARBENE-PHOSPHINIDENE | TRIPHENYLPHOSPHINE | C-H BONDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
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