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carboboration (114) 114
chemistry, multidisciplinary (65) 65
alkynes (64) 64
chemistry, organic (53) 53
alkenes (48) 48
copper (47) 47
boron (43) 43
catalysis (39) 39
hydroboration (38) 38
stereoselective-synthesis (29) 29
palladium (25) 25
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esters (18) 18
halides (18) 18
3-component carboboration (17) 17
reactivity (17) 17
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copper-catalyzed reaction (15) 15
kupfer (15) 15
olefins (14) 14
1,1-organoboration (13) 13
chemistry, inorganic & nuclear (13) 13
complexes (13) 13
enantioselective arylboration (13) 13
organozirconium reagents (13) 13
regioselectivity (13) 13
chemistry, physical (12) 12
terminal alkynes (12) 12
1,1-carboboration (11) 11
aromatic compounds (11) 11
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aryl (10) 10
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molecular structure (10) 10
organoboron compounds (10) 10
arylboration (9) 9
boranes (9) 9
boronic esters (9) 9
chemical synthesis (9) 9
chemistry (9) 9
construction (9) 9
mathematical analysis (9) 9
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frustrated lewis pairs (8) 8
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allylic carbonates (7) 7
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kreuzkupplung (7) 7
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Organic Letters, ISSN 1523-7060, 11/2016, Volume 18, Issue 21, pp. 5460 - 5463
A palladium-catalyzed 1,2-arylboration of vinylarenes with aryldiazonium tetrafluoroborates and bis­(pinacolato)­diboron has been disclosed. It is reported for... 
CHEMISTRY, ORGANIC | ALKENES | ALKYNES | CARBOBORATION | COMPLEXES
Journal Article
ACS Catalysis, ISSN 2155-5435, 10/2016, Volume 6, Issue 10, pp. 6417 - 6421
A ligand-controlled regiodivergent and stereospecific copper-catalyzed alkylboration of unactivated terminal alkynes has been developed. Anti-Markovnikov... 
carboboration | copper | regiodivergent | vinylboronic esters | alkynes | ORGANOBORON COMPOUNDS | HALIDES | CHEMISTRY, PHYSICAL | COPPER(I)-CATALYZED REACTION | ALKENES | CROSS-COUPLING REACTIONS | SYNERGISTIC CATALYSIS | STEREOSELECTIVE-SYNTHESIS | CARBON-DIOXIDE | 3-COMPONENT CARBOBORATION | GRIGNARD-REAGENTS
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2015, Volume 21, Issue 11, pp. 4257 - 4261
An iron‐catalyzed diboration reaction of alkynes with bis(pinacolato)diboron (B2pin2) and external borating agents (MeOB(OR)2) affords diverse symmetrical or... 
carboboration | iron | diboration | alkyl halides | alkynes | Iron | Diboration | Alkyl halides | Carboboration | Alkynes | HALIDES | ALKENES | HYDROBORATION | ACTIVATION | FORMAL CARBOBORATION | REGIO | CHEMISTRY, MULTIDISCIPLINARY | Alkynes - chemistry | Molecular Structure | Catalysis | Stereoisomerism | Iron - chemistry | Halides | Chemical properties | Borates | Trapping | Mathematical analysis | Borating | Bonding agents | Radicals
Journal Article
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 06/2019, Volume 17, Issue 24, pp. 5913 - 5915
A method for (hetero)arylboration of alkynes is presented. The reaction allows for the synthesis of densely functionalized tetrasubstituted alkenes with... 
CHEMISTRY, ORGANIC | CATALYSIS | ENANTIOSELECTIVE ARYLBORATION | ALKYLBORATION | CARBOBORATION
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 06/2019, Volume 2019, Issue 24, pp. 2912 - 2917
The reactions of dimesityl(propynyl)phosphane (9) with either of the halogeno‐B(C6F5)2 reagents 10a,b (hal: Cl, Br) proceeds through addition and rearrangement... 
Halogenoboranes | Synthesis design | Phospholes | Structure elucidation | Carboboration | Reagents | Derivatives
Journal Article
Organic Letters, ISSN 1523-7060, 03/2018, Volume 20, Issue 5, pp. 1346 - 1349
An enantioselective Cu-catalyzed borylative cross-coupling reaction of alkenes, bis­(pinacolato)­diboron (B2(pin)2), and methyl iodide is reported. Alkenes... 
IMINES | CARBOBORATION | CHEMISTRY, ORGANIC | STEREOSELECTIVE-SYNTHESIS | LIGAND | ARYLBORATION | ALKYNES | COPPER(I)-CATALYZED REACTION | EFFICIENT | ALKYLBORATION | CYCLIZATION
Journal Article
Organic Letters, ISSN 1523-7060, 08/2016, Volume 18, Issue 16, pp. 3956 - 3959
A method for the arylboration of 1-arylalkenes with bis­(pinacolato)­diboron and aryl chlorides or tosylates by cooperative Ni/Cu catalysis has been developed,... 
ALKENES | ENANTIOSELECTIVE SYNTHESIS | SYNERGISTIC CATALYSIS | ARYL HALIDES | CHEMISTRY, ORGANIC | BORONIC ESTERS | CO-CATALYSIS | STEREOSELECTIVE-SYNTHESIS | ALKYNES | CARBON-DIOXIDE | 3-COMPONENT CARBOBORATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2015, Volume 137, Issue 46, pp. 14578 - 14581
A method for the catalytic enantioselective diarylation of alkenes is presented. The method allowed for the synthesis of highly enantioenriched... 
ETHYLENE | SYNERGISTIC CATALYSIS | STEREOCENTERS | CARBOBORATION | CASCADE | OLEFINS | INTRAMOLECULAR ARYLCYANATION | LIGAND | ALLENES | CARBOAMINATION | CHEMISTRY, MULTIDISCIPLINARY | Arylation | Research | Chemical properties | Catalysis | Olefins
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2011, Volume 696, Issue 6, pp. 1184 - 1188
Treatment of R Si(C C-SiMe ) [ (Me), (Ph)] with HB(C F ) at low temperature (253 K ( ), 273 K ( )) gives the –B(C F ) substituted silacyclobutene products ( ,... 
Boron | Silicon | Hydroboration | Photolysis | Carboboration
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2016, Volume 138, Issue 9, pp. 2897 - 2900
The aryl to vinyl palladium 1,4-migration was realized for the first time. The generated alkenyl palladium species was trapped by diboron reagents under... 
IRIDIUM-CATALYZED BORYLATION | ACTIVATION | DIRECT ARYLATION | FORMAL CARBOBORATION | RHODIUM | MECHANISM | 1,4-PALLADIUM MIGRATION | COUPLING REACTION | EFFICIENT SYNTHESIS | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2016, Volume 138, Issue 24, pp. 7528 - 7531
We report the first copper-catalyzed regio- and stereoselective borylalkylation of dialkylsubstituted internal alkynes with bis­(pinacolato)­diboron and alkyl... 
CHLOROBORANE | N-HETEROCYCLIC CARBENE | HYDROGENATION | REDUCTIVE COUPLINGS | CARBOBORATION | ALLYLATION | HYDROAMINATION | REGIOSELECTIVITY | ALLENES | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | Chemical synthesis | Catalysis | Research
Journal Article
Organic Letters, ISSN 1523-7060, 02/2015, Volume 17, Issue 3, pp. 620 - 623
Stereoselective silicon-tethered alkylboration of alkynes in the presence of a copper(I) catalyst and a diboron reagent provided the corresponding cyclic... 
CHLOROBORANE | PALLADIUM | HYDROBORATION | SILABORATION | CARBOBORATION | CHEMISTRY, ORGANIC | SELECTIVE SYNTHESIS | CATALYZED BORYLATION | EFFICIENT | DIBORATION | CYCLIZATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2019, Volume 58, Issue 47, pp. 17068 - 17073
We report the development of palladium(0)‐catalyzed syn‐selective 1,2‐carboboration and ‐silylation reactions of alkenes containing cleavable directing groups.... 
carboboration | palladium | directing group | alkene | borylation | Silanes | Alkenes | Aromatic compounds | Chemical reactions | Palladium | Nucleophiles | Viability
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2014, Volume 20, Issue 40, pp. 12874 - 12880
Journal Article
by Park, Y and Yun, J
ORGANIC LETTERS, ISSN 1523-7060, 11/2019, Volume 21, Issue 21, pp. 8779 - 8782
A highly enantioselective copper-catalyzed reduction of beta, beta-disubstituted alkenylboron compounds was developed using hydrosilane. The copper hydride... 
ALKENES | HYDROBORATION | LIGANDS | SCOPE | ENANTIOSELECTIVE HYDROGENATION | CARBOBORATION | SECONDARY | CHEMISTRY, ORGANIC | TRANSFORMATIONS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2017, Volume 139, Issue 29, pp. 9823 - 9826
A method for the regiodivergent arylboration of dienes is presented. These reactions allow for the formation of a diverse range of synthetically versatile... 
PALLADIUM | ALKENES | ISOPRENE | COOPERATIVE CATALYSIS | 1,3-DIENES | SYNERGISTIC CATALYSIS | ALKYLATION | CONJUGATED DIENES | CARBOBORATION | ALLENES | CHEMISTRY, MULTIDISCIPLINARY | Chemical reactions | Chemical properties | Research | Catalysts | Halides | Alkadienes
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 12/2019, Volume 10, Issue 47, pp. 10944 - 10947
Nickel-catalyzed 1,2-carboboration of alkenes is emerging as a useful method for chemical synthesis. Prior studies have been limited to only the incorporation... 
DIFUNCTIONALIZATION | CROSS-COUPLINGS | SECONDARY ALKYL-HALIDES | CHEMISTRY, MULTIDISCIPLINARY | 3-COMPONENT CARBOBORATION
Journal Article
Chemical Communications, ISSN 1359-7345, 2010, Volume 46, Issue 20, pp. 3580 - 3582
The frustrated Lewis pair P(o-tolyl)(3)/B(C6F5)(3) reacts with 1,7-octadiyne by acetylene C-C coupling to yield the zwitterionic product 2a. In contrast, the... 
CHLOROBORANE | HYDROGEN | ACTIVATION | 1,6-ENYNES | CARBOBORATION | 1,1-ORGANOBORATION | CHIRALITY | REDUCTIVE CYCLIZATION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 02/2019, Volume 58, Issue 6, pp. 1719 - 1723
Two methods are reported for the 1,2- and 1,1-arylboration of -methyl vinyl arenes. In the case of 1,2-arylboration, the formation of a quaternary center... 
REAGENTS | REGIOSELECTIVE ARYLBORATION | 1,1-DIARYLATION | COMPLEXES | SECONDARY | carboboration | TERTIARY | CHEMISTRY, MULTIDISCIPLINARY | ARYL BROMIDES | CROSS-COUPLING REACTIONS | homogeneous catalysis | cross-coupling | copper | palladium | ENANTIOSELECTIVE ARYLBORATION | Enantiomers | Copper | Catalysis
Journal Article
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