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Science (American Association for the Advancement of Science), ISSN 1095-9203, 2016, Volume 352, Issue 6291, pp. 1304 - 1308
The use of sp(3) C-H bonds--which are ubiquitous in organic molecules--as latent nucleophile equivalents for transition metal-catalyzed cross-coupling reactions has the potential to substantially streamline synthetic... 
Organic chemistry | Nickel | Catalysts | Carbon | Carbon-carbon composites | Cross coupling | Hydrogen atoms | Catalysis | Nucleophiles | Arrays
Journal Article
SCIENCE, ISSN 0036-8075, 10/2016, Volume 354, Issue 6310, pp. aah5133 - aah5133
.... Here, we review catalytic intermolecular reductive couplings of unactivated and activated olefin-derived nucleophiles with carbonyl partners... 
ALPHA-OLEFINS | KETONES | C-C COUPLINGS | ALDOL REACTION | HYDROHYDROXYALKYLATION | MULTIDISCIPLINARY SCIENCES | HYDROXY ESTERS | H BONDS | TITANIUM CATALYST | FORMING TRANSFER HYDROGENATION | OXIDATION LEVEL | Organic chemistry | Chemical reactions | Catalysts | Metals | Carbon-carbon composites | Olefins | Reagents | Coupling | Catalysis | Nucleophiles | Carbonyls
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2014, Volume 136, Issue 15, pp. 5750 - 5754
A general method for intermolecular allylic C–H alkylation of terminal olefins with tertiary nucleophiles has been accomplished employing palladium­(II)/bis­(sulfoxide) catalysis. Allylic C... 
HIMBACINE | OXIDATION | ACTIVATION | SERIAL LIGAND CATALYSIS | NATURAL-PRODUCTS | BOND FUNCTIONALIZATION | OLEFINS | RECEPTORS | SELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED DIRECT ARYLATION | Hydrocarbons - chemistry | Proton Magnetic Resonance Spectroscopy | Hydrogen - chemistry | Alkylation | Carbon - chemistry | Palladium | Research | Nucleophiles | Hydrogen bonding | Analysis | Stereoselectivity | Olefins | Cascades | Esters | Dienes | Aliphatic compounds
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2016, Volume 55, Issue 5, pp. 1894 - 1898
.... Under mild reaction conditions (RT to 40 °C), Cu(OTf)2 mediates the selective coupling of functionalized aryl boron species with a variety of stabilized sp3‐nucleophiles... 
oxidation | copper | arenes | boron | synthetic methods | Arenes | Boron | Oxidation | Synthetic methods | Copper | Cross coupling | Transformation | Iodides | Aromatic compounds | Quaternary | Reagents | Bromides | Esters | Nucleophiles | Substrates | Methylene
Journal Article
Science, ISSN 0036-8075, 07/2016, Volume 353, Issue 6295, pp. 144 - 150
Enantioenriched alcohols found in an array of bioactive natural products and pharmaceutical agents are often synthesized by asymmetric nucleophilic addition to... 
ALCOHOLS | HYDROGENATION | REAGENTS | PROPARGYLATION | AMINES | C BOND FORMATION | MULTIDISCIPLINARY SCIENCES | CARBONYL | 1,3-ENYNES | ALDEHYDES | HYDROAMINATION | Stoichiometry | Chemical properties | Ketones | Nucleophiles | Olefins | Analysis | Ligands | Catalysts | Copper | Carbon | Asymmetry | Metalorganic compounds | Reagents | Biocompatibility | Alcohols
Journal Article