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Journal Article
Chemical Reviews, ISSN 0009-2665, 06/2016, Volume 116, Issue 12, pp. 7330 - 7396
This Review summarizes the advances in the construction of all-carbon quaternary stereocenters via catalytic enantioselective desymmetrization of prochiral and... 
TRICYCLIC BETA-LACTONES | POLYCYCLIC DERIVATIVES | STEREOGENIC CENTER | AMINO-ACID | INTERMOLECULAR DESYMMETRIZATION | C-C BOND | EFFICIENT CONSTRUCTION | ASYMMETRIC TOTAL-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | H ARYLATION | WIELAND-MIESCHER | Catalysis | Cyclization | Stereoisomerism | Carbon - chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2001, Volume 40, Issue 24, pp. 4591 - 4597
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2010, Volume 46, Issue 39, pp. 7295 - 736
All-carbon quaternary stereocenters are ubiquitous motifs in biological products and pharmaceutical agents. However, due to sterical reasons, these centers are... 
ALKENYLBORONIC ACIDS | N-HETEROCYCLIC CARBENE | ENANTIOSELECTIVE SYNTHESIS | CARBON STEREOCENTERS | SUBSTITUTED CYCLIC ENONES | DIALKYLZINC REAGENTS | STEREOGENIC CENTERS | TRISUBSTITUTED ENONES | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS | ARYL ALUMINUM REAGENTS | Indicators and Reagents | Catalysis | Metals - chemistry | Stereoisomerism
Journal Article
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 4/2004, Volume 101, Issue 15, pp. 5363 - 5367
Only a few catalytic asymmetric C-C bond-forming reactions have been shown to be useful for constructing all-carbon quaternary stereocenters. This Perspective... 
Alkenes | Catalysts | Ketones | Diels Alder reactions | Ligands | Overman | Perspectives | Catalysis | Nucleophiles | Dienes | Carbon | ACTIVATION | DIELS-ALDER REACTIONS | ALPHA-ARYLATION | MULTIDISCIPLINARY SCIENCES | CONSTRUCTION | PHASE-TRANSFER CATALYSIS | NUCLEOPHILE | ENANTIOSELECTIVE MICHAEL ADDITIONS | ENE-TYPE CYCLIZATION | HECK REACTION | ALLYLIC ALKYLATIONS | Research
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2015, Volume 137, Issue 50, pp. 15668 - 15671
An enantioselective, intermolecular dehydrogenative Heck arylation of trisubstituted alkenes to construct remote quaternary stereocenters has been developed.... 
DENSITY FUNCTIONALS | ALCOHOLS | OLEFINATION | ARYL | HYDROHETEROARYLATION | DERIVATIVES | SELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | CARBON STEREOGENIC CENTERS | HYDROARYLATION | CYCLIZATION | Alkenes - chemistry | Molecular Structure | Stereoisomerism | Hydrogen - chemistry | Indoles - chemistry | Arylation | Olefins | Analysis | Ligands | Chemical properties | Research | Stereochemistry
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 05/2013, Volume 2013, Issue 14, pp. 2745 - 2759
All‐carbon quaternary stereocenters have posed significant challenges in the synthesis of complex natural products. These important structural motifs have... 
All‐carbon quaternary stereocenters | Palladium | Natural products | Asymmetric cataly­sis | Total synthesis | Allylation | Asymmetric catalysis | All-carbon quaternary stereocenters | CHEMISTRY, ORGANIC | FORMAL TOTAL-SYNTHESIS | ALPHA | ALDEHYDES | KETONES | LIGANDS | SILYL ENOL ETHERS | ESTERS | ENANTIOSELECTIVE TOTAL-SYNTHESIS | CONCISE SYNTHESIS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2003, Volume 42, Issue 15, pp. 1688 - 1690
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2014, Volume 136, Issue 42, pp. 14642 - 14645
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2014, Volume 53, Issue 24, pp. 6180 - 6183
Journal Article
Organic Letters, ISSN 1523-7060, 10/2012, Volume 14, Issue 19, pp. 4990 - 4993
The first enantioselective copper-catalyzed cyclopropanation of N-acyl indoles is described. Using carbohydrate-based bis(oxazoline) ligands (glucoBox), the... 
ORGANIC-SYNTHESIS | COMPLEX | BIS(OXAZOLINE) LIGANDS | CHEMISTRY, ORGANIC | FORMAL TOTAL-SYNTHESIS | STEREOSELECTIVE-SYNTHESIS | RING-SYSTEM | PHYSOSTIGMINE | CENTERS | CATALYTIC ASYMMETRIC-SYNTHESIS | ALKALOIDS | Cyclopropanes - chemistry | Ligands | Molecular Structure | Stereoisomerism | Indoles - chemistry | Carbon - chemistry
Journal Article
Chemical Communications, ISSN 1359-7345, 02/2016, Volume 52, Issue 11, pp. 2257 - 2260
Herein, a novel and efficient gold-catalyzed intermolecular C(sp(2))-H functionalization (Friedel-Crafts alkylation) and aldol annulation strategy is... 
CYCLOADDITION | ACTIVATION | CARBON-CARBON BOND | STRATEGY | CARBENE INSERTION | CYCLOPROPANATION REACTIONS | VINYL DIAZO DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | ARYL-ALPHA-DIAZOACETATES | ETHYL DIAZOACETATE | DIAZOESTERS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2013, Volume 135, Issue 8, pp. 2983 - 2986
A highly enantioselective Friedel–Crafts alkylation reaction of indoles with β-CF3-β-disubstituted nitroalkenes was achieved using a Ni(ClO4)2–bisoxazoline... 
COMPLEX | ASYMMETRIC-SYNTHESIS | ACID | PYRROLES | 1,3-DIPOLAR CYCLOADDITION REACTIONS | STEREOGENIC CENTERS | FLUORINATION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | INDOLES | NITROALKENES | Catalysis | Nickel - chemistry | Stereoisomerism | Alkylation | Carbon - chemistry | Thermal properties | Analysis | Methyl groups | Nickel compounds | Ring formation (Chemistry) | Chemical properties
Journal Article