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Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 9086 - 9139
Catalytic C–H bond activation, which was an elusive subject of chemical research until the 1990s, has now become a standard synthetic method for the formation... 
ARYL GRIGNARD-REAGENTS | ORGANIC-SYNTHESIS | CROSS-COUPLING REACTIONS | N-HETEROCYCLIC CARBENE | DIRECT ARYLATION | SCHIFF-BASES | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | METAL-METAL COOPERATIVITY | HYDRIDE COMPLEXES | ALKYL-HALIDES
Journal Article
Organic Letters, ISSN 1523-7060, 06/2011, Volume 13, Issue 12, pp. 3232 - 3234
Aromatic carboxamides and 2-phenylpyridine derivatives can be ortho-alkylated with Grignard reagents in the presence of a cobalt catalyst and DMPU as a ligand.... 
CHEMISTRY, ORGANIC | METHYLATION | DIRECT ARYLATION | IMINES | CARBON-HYDROGEN
Journal Article
Organic Letters, ISSN 1523-7060, 02/2012, Volume 14, Issue 3, pp. 728 - 731
A cationic ruthenium(II) complex enabled efficient oxidative alkenylations of anilides in water as a green solvent and proved applicable to double C–H bond... 
FUNCTIONALIZATION | ALKENES | PALLADIUM | ACTIVATION | ETHYLENE | ALKYLATION | ARENES | CHEMISTRY, ORGANIC | CARBON-HYDROGEN BONDS | DIRECT ARYLATIONS | CLEAVAGE
Journal Article
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 9247 - 9301
Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient synthetic approach to construct N-functionalized molecules. Over... 
INTRAMOLECULAR C(SP)-H AMINATION | NITROGEN-CONTAINING HETEROCYCLES | UNACTIVATED C(SP)-H BONDS | AEROBIC OXIDATIVE AMINATION | VISIBLE-LIGHT PHOTOREDOX | O-BENZOYL-HYDROXYLAMINES | NITRENE TRANSFER-REACTIONS | BENZYLIC METHYLENE GROUPS | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | N BOND-FORMATION
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 05/2016, Volume 45, Issue 10, pp. 2900 - 2936
Organic reactions that involve the direct functionalization of non-activated C-H bonds represent an attractive class of transformations which maximize atom-and... 
C(SP)-H BOND ACTIVATION | ROOM-TEMPERATURE | OXIDIZING DIRECTING GROUP | VISIBLE-LIGHT PHOTOCATALYSIS | N-TYPE REACTIONS | (ELECTRON-DEFICIENT ETA-CYCLOPENTADIENYL)RHODIUM(III) CATALYST | CARBON-HYDROGEN BONDS | ORTHO-ARYLATION | SECONDARY ALKYL-HALIDES | CHEMISTRY, MULTIDISCIPLINARY | LATE-STAGE FUNCTIONALIZATION
Journal Article
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 8787 - 8863
Transition metal-mediated C–H bond activation and functionalization represent one of the most straightforward and powerful tools in modern organic synthetic... 
TRACELESS DIRECTING GROUPS | HEXA-PERI-HEXABENZOCORONENES | AZINE N-OXIDES | 1ST TOTAL-SYNTHESIS | METALATION-DEPROTONATION MECHANISM | CARBON-HYDROGEN BONDS | ASYMMETRIC TOTAL-SYNTHESIS | SINGLE-ELECTRON TRANSFER | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE ARENES | CATALYZED DIRECT ARYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 12/2010, Volume 12, Issue 24, pp. 5688 - 5691
A synthetic method of isoquinolines from aryl ketone O-acyloxime derivatives and internal alkynes has been developed using [Cp*RhCl2]2−NaOAc as the potential... 
ACTIVATION | C-H BOND | BENZAMIDES | ANNULATION | ARYLATION | AROMATIC IMINES | CHEMISTRY, ORGANIC | CATALYZED OXIDATIVE COUPLING/CYCLIZATION | CARBON-HYDROGEN | HYDROARYLATION
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 11/2012, Volume 41, Issue 22, pp. 7572 - 7589
In the last five years and currently, research on solar fuels has been intense and no sub-area in this field has been more active than the development of water... 
VISIBLE-LIGHT | IN-VITRO | EXCITED-STATE | COUPLED ELECTRON-TRANSFER | BUILDING-BLOCKS | ARTIFICIAL PHOTOSYNTHESIS | CARBON-HYDROGEN BONDS | CHARGE-TRANSFER | OXYGEN-EVOLVING CATALYST | CHEMISTRY, MULTIDISCIPLINARY | RUTHENIUM COMPLEX
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 05/2011, Volume 133, Issue 17, pp. 6541 - 6544
This communication describes a new method for the Pd/polrxometalate-catalyzed aerobic olefination of unactivated sp(3)C H bonds. Nitrogen heterocycles serve as... 
OXIDATIVE FUNCTIONALIZATION | COUPLING REACTION | ARYLATION | CARBON-HYDROGEN BONDS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION
Journal Article
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 9333 - 9403
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 11/2013, Volume 5, Issue 1, pp. 29 - 39
Remarkable recent progress has been accomplished in direct C-H functionalizations for the formation of C-N and C-O bonds through the use of readily accessible... 
Accessibility
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2014, Volume 136, Issue 9, pp. 3354 - 3357
A Cu(OAc)2-mediated C–H amidation and amination of arenes and heteroarenes has been developed using a readily removable directing group. A wide range of... 
CUPRIC ACETATE | PALLADIUM | CROSS-COUPLING REACTIONS | ACTIVATION | AROMATIC CARBOXAMIDES | ARYL | CARBON-HYDROGEN BONDS | INHIBITORS | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | CATALYZED ARYLATION | Copper | Influence
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2010, Volume 132, Issue 2, pp. 460 - 461
Pd(II)-catalyzed enantioselective C−H olefination of diphenylacetic acid substrates has been achieved through the use of monoprotected chiral amino acid... 
FUNCTIONALIZATION | ALCOHOLS | ACTIVATION | AMINATION | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | HYDROACYLATION | CATALYSTS | CYCLIZATION | MOLECULAR-OXYGEN
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2013, Volume 135, Issue 6, pp. 2124 - 2127
We report an efficient method for the alkylation of γ-C(sp3)–H bonds of picolinamide-protected aliphatic amine substrates with primary alkyl iodides via... 
HALIDES | FUNCTIONALIZATION | C(SP)-H BONDS | CROSS-COUPLING REACTIONS | AMINATION | ARYLATION | ORTHO-C(SP)-H BONDS | CARBON-HYDROGEN BONDS | OXIDATIVE ADDITION | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 08/2017, Volume 19, Issue 16, pp. 4279 - 4282
A cobalt­(II)-catalyzed regioselective aryl C–H bond oxygenation between arenes and aryl or aliphatic carboxylic acids under bidendate-chelation assistance is... 
FUNCTIONALIZATION | OXIDATION | SUBSTITUTION | AMINATION | PHOSPHORAMIDATE PROTIDES | ARYLATION | CHEMISTRY, ORGANIC | ALKYLAMINES | CARBON-HYDROGEN BONDS | ANHYDRIDES | CLEAVAGE
Journal Article