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chemistry, organic (22) 22
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 01/2015, Volume 137, Issue 1, pp. 42 - 45
A zerovalent copper- and cobalt-catalyzed direct coupling of the sp(3) alpha-carbon of alcohols with alkenes and hydroperoxides was developed in which the... 
C(SP)-H BONDS | ALLYLIC ALCOHOLS | CARBONYLATION-PEROXIDATION | ASYMMETRIC ADDITION | BOND ACTIVATION | ENANTIOSELECTIVE ADDITION | AROMATIC-ALDEHYDES | C-H FUNCTIONALIZATION | NUCLEOPHILIC-ADDITION | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS
Journal Article
Chemical Communications, ISSN 1359-7345, 11/2014, Volume 50, Issue 85, pp. 12867 - 12869
A new oxidative coupling of unactivated terminal alkenes with amides using peroxides is described, in which mono- and difunctionalization of alkenes are... 
HYDROAMIDATION | FORMAMIDES | BONDS | CATALYZED CARBONYLATION-PEROXIDATION | ALDEHYDES | ARYL | HECK REACTION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 11/2014, Volume 50, Issue 85, pp. 12867 - 12869
A new oxidative coupling of unactivated terminal alkenes with amides using peroxides is described, in which mono- and difunctionalization of alkenes are... 
Journal Article
Organic Letters, ISSN 1523-7060, 05/2016, Volume 18, Issue 9, pp. 2264 - 2267
An iron-catalyzed radical [2 + 2 + 2] annulation of benzene-linked 1,7-enynes with aldehydes has been developed. With this method, a variety of fused [6.6.6]... 
ALKENES | CYCLOADDITION REACTIONS | CARBON | MECHANISTIC INSIGHTS | AZAPHILONES | CHEMISTRY, ORGANIC | CARBONYLATION-PEROXIDATION | CYCLOISOMERIZATION | 3,4-DIHYDROQUINOLIN-2(1H)-ONES | CYCLIZATION | 1,N-ENYNES
Journal Article
Organic Letters, ISSN 1523-7060, 09/2015, Volume 17, Issue 17, pp. 4324 - 4327
A novel convergent radical cyclization of an aldehyde with two alkenes has been developed. With this method, polyfunctionalized 3,4-dihydropyrans are built in... 
FUNCTIONALIZATION | DIHYDROPYRANS | ELECTRON-TRANSFER | CARBON | DIELS-ALDER REACTIONS | ESTERS | CONSTRUCTION | CHEMISTRY | CHEMISTRY, ORGANIC | CARBONYLATION-PEROXIDATION | ACCESS
Journal Article
Organic Letters, ISSN 1523-7060, 11/2013, Volume 15, Issue 21, pp. 5432 - 5435
The Brønsted acid catalyzed rearrangement of tert-butyl peroxides provides a new strategy to construct 2,3-disubstituted furans via 1,2-aryl migration. In... 
ALKENES | CHOLESTEROL | STRATEGY | EFFICIENT SYNTHESIS | OZONE | ACYLOXY | CHEMISTRY, ORGANIC | CATALYZED CARBONYLATION-PEROXIDATION | ALDEHYDES | CLEAVAGE | CYCLIZATION
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2017, Volume 82, Issue 3, pp. 1403 - 1411
A transition-metal-free and room-temperature coupling/decarboxylation reaction between α-oxocarboxylates and α-bromoketones is reported herein. It represents... 
OXIDATION | ANALOGS | 1,2-DIKETONES | COMPLEXES | CHEMISTRY, ORGANIC | CATALYZED CARBONYLATION-PEROXIDATION | SELECTIVE SYNTHESIS | DIKETONES | CLEAVAGE | FACILE | EFFICIENT
Journal Article
Organic Letters, ISSN 1523-7060, 03/2019, Volume 21, Issue 5, pp. 1480 - 1483
Nitration-peroxidation of alkenes for the synthesis of beta-peroxyl nitroalkanes has been developed by using tert-butyl nitrite and tert-butyl hydroperoxide.... 
STYRENES | C-N | CHEMISTRY | CHEMISTRY, ORGANIC | CATALYZED CARBONYLATION-PEROXIDATION | RADICALS | T-BUONO | TERT-BUTYL NITRITE | STEREOSELECTIVE NITRATION | EFFICIENT | CYCLIZATION
Journal Article
Organic Letters, ISSN 1523-7060, 2017, Volume 19, Issue 19, pp. 5260 - 5263
Disclosed herein is an unprecedented cobalt-catalyzed trifluoromethylation peroxidation of unactivated alkenes. In this process the hydroperoxide acts as a... 
3-COMPONENT OXYTRIFLUOROMETHYLATION | FACILE SYNTHESIS | RADICAL PROCESS | DIASTEREOSELECTIVE SYNTHESIS | ALLYLIC ALCOHOLS | CASCADE TRIFLUOROMETHYLATION/CYCLIZATION | CHEMISTRY, ORGANIC | CARBONYLATION-PEROXIDATION | VISIBLE-LIGHT-DRIVEN | METAL-FREE | PHOTOREDOX CATALYSIS
Journal Article
by Liu, RX and Zhang, F and Peng, Y and Yang, L
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 10/2019, Volume 55, Issue 80, pp. 12080 - 12083
From difunctionalization of a single alkene to radical-dual-difunctionalization of two different alkenes! Abundant aliphatic aldehydes were readily... 
KETONES | HYDROPEROXYARYLATION | CARBON | ESTERS | CATALYZED CARBONYLATION-PEROXIDATION | HYDROPEROXIDES | CHEMISTRY, MULTIDISCIPLINARY | STYRENE DERIVATIVES | UNACTIVATED ALKENES
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 01/2015, Volume 80, Issue 1, pp. 698 - 704
Iron-catalyzed acylation-oxygenation of terminal alkenes is reported. Acyl radicals generated by the oxidation of aldehydes add to terminal alkenes and... 
FUNCTIONALIZATION | HIGHLY ENANTIOSELECTIVE SYNTHESIS | KETONES | ASYMMETRIC 4+1 CYCLOADDITIONS | C-O | COUPLING REACTIONS | RADICAL CYCLIZATION | CHEMISTRY, ORGANIC | CARBONYLATION-PEROXIDATION | ALDEHYDES | 2,3-DIHYDROFURANS | Oxygen | Chemical properties | Aldehydes | Hydrogen | Olefins
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 10/2015, Volume 51, Issue 84, pp. 15422 - 15425
C-3 alkylation of coumarins has been accomplished using cycloalkanes or alkylbenzenes in the presence of di-tert-butylperoxide (DTBP) and Fe(III) catalyst.... 
Oxidants - chemistry | Stereoisomerism | Peroxides - chemistry | Coumarins - chemistry | Molecular Structure | Alkylation | tert-Butylhydroperoxide - chemistry
Journal Article
Chemical Communications, ISSN 1359-7345, 2015, Volume 51, Issue 84, pp. 15422 - 15425
C-3 alkylation of coumarins has been accomplished using cycloalkanes or alkylbenzenes in the presence of di-tert-butylperoxide (DTBP) and Fe-III catalyst.... 
ALKENES | ACTIVATION | SIMPLE ALKANES | BOND FUNCTIONALIZATION | CATALYZED CARBONYLATION-PEROXIDATION | ALDEHYDES | C(SP)-H | C-H FUNCTIONALIZATION | HECK REACTION | CHEMISTRY, MULTIDISCIPLINARY | ACCESS | Carbon-carbon composites | Cycloalkanes | Oxidants | Oxidizing agents | Bonding | Coumarin | Switching | Alkylation
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 95, pp. 12830 - 12833
A reaction protocol in which FeCl3 and tert-butyl hydroperoxide facilitated a selective radical coupling reaction of aryl alkenes or 1,3-enynes with tert-butyl... 
ORGANIC-SYNTHESIS | MONOXIDE-FREE AMINOCARBONYLATION | N-SUBSTITUTED FORMAMIDES | 1,4-DICARBONYL COMPOUNDS | ARYL ISONITRILES | DIRECT ADDITION | BOND FORMATION | CARBONYLATION-PEROXIDATION | CHEMISTRY, MULTIDISCIPLINARY | CARBON-CENTERED RADICALS | C-H
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2015, Volume 80, Issue 24, pp. 12562 - 12571
Iron-catalyzed divergent tandem radical annulations of aldehydes with olefins are reported. The new strategy allows the rapid and efficient construction of... 
FUNCTIONALIZATION | ACTIVATED ALKENES | ARYLTRIFLUOROMETHYLATION | C-H BOND | CHEMISTRY, ORGANIC | CARBONYLATION-PEROXIDATION | ACRYLAMIDES | (+/-)-LUNDURINE | KOPSIA-TENUIS | CYCLIZATION | ALKALOIDS | Chemical bonds | Carbonyl compounds | Usage | Research | Analysis | Iron catalysts
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 12/2015, Volume 56, Issue 48, pp. 6719 - 6721
Iron-catalyzed alkoxycarbonylation–peroxidation of alkenes with carbazates and T-Hydro was developed. A variety of β-ester peroxides were synthesized... 
Iron catalysis | Difunctionalization | Alkoxycarbonylation | Peroxidation | OXIDATION | HYDROPEROXYARYLATION | CARBON | CHEMISTRY, ORGANIC | ALDEHYDES | ARYLALKOXYCARBONYLATION | ENANTIOSELECTIVE PEROXIDATION | CARBONYLATION-PEROXIDATION | RADICALS | Olefins | Catalysis | Refining | Petroleum
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2019, Volume 361, Issue 22, pp. 5198 - 5209
The low‐cost cobalt(II) catalyst has been used for the first time to achieve P(O)‐radical‐mediated bisfunctionalization of alkenes with diarylphosphine oxide... 
difunctionalization | phosphonation | peroxidation | radicals | cobalt-catalyzed | ROOM-TEMPERATURE | STYRENES | CHEMISTRY, ORGANIC | CATALYZED CARBONYLATION-PEROXIDATION | CASCADE | ALPHA | ALDEHYDES | PHOSPHORUS-CENTERED RADICALS | ALKYLATION-PEROXIDATION | CHEMISTRY, APPLIED | CYCLIZATION | Alkenes | Peroxides
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2017, Volume 82, Issue 10, pp. 5487 - 5491
The structure of (±)-clavilactone D was revised, and the synthesis was achieved in seven steps from a substituted benzaldehyde. The key step was the... 
ALKENES | T-HYDRO | RADICAL CYCLIZATION | QINGHAOSU | CHEMISTRY, ORGANIC | CATALYZED CARBONYLATION-PEROXIDATION | HYDROPEROXIDES | ARTEMISININ | STRUCTURE ELUCIDATION | METATHESIS | CLAVILACTONE-B | Carbonyl compounds | Usage | Chemical properties | Chemical synthesis | Aldehydes
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 06/2018, Volume 59, Issue 26, pp. 2604 - 2606
The silylation-peroxidation of alkenes with hydrosilanes and -hydro was developed by using iron or cobalt catalyst. The three-component protocol provided a... 
Alkene | Difunctionalization | Silylation | Hydrosilane | Peroxidation | ROOM-TEMPERATURE | CHEMISTRY, ORGANIC | COPPER | ALDEHYDES | RADICAL-ADDITION | UNACTIVATED ALKENES | H FUNCTIONALIZATION | CARBONYLATION-PEROXIDATION | HYDROPEROXIDES | ALPHA,BETA-UNSATURATED ESTERS | TRIFLUOROMETHYLATION | Cobalt | Olefins | Peroxides
Journal Article
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