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carboxamido-n (49) 49
chemistry, inorganic & nuclear (30) 30
active-site (18) 18
crystal-structure (17) 17
ligands (16) 16
nitrile hydratase (16) 16
chemistry, multidisciplinary (15) 15
nonheme iron (12) 12
sulfur (12) 12
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oxidation (9) 9
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models, molecular (7) 7
chemistry (6) 6
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nitriles (6) 6
oxidation-reduction (6) 6
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thiolate (6) 6
biochemistry & molecular biology (5) 5
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containing nitrile hydratase (5) 5
donors (5) 5
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cysteine (4) 4
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activation (3) 3
amides (3) 3
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cysteine - chemistry (3) 3
density-functional theory (3) 3
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x-ray spectroscopy (3) 3
active-center (2) 2
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carbon-dioxide fixation (2) 2
carboxamido n (2) 2
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density functionals (2) 2
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electron spin resonance spectroscopy (2) 2
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INORGANIC CHEMISTRY, ISSN 0020-1669, 08/2019, Volume 58, Issue 16, pp. 10501 - 10507
Zinc thiolate bonds are intriguing targets of study because of their redox noninnocence and prevalence in bioinorganic sites. A five-coordinate zinc dithiolate... 
ELEMENTAL SULFUR | CARBON BONDS | REPAIR | LIGANDS | ACTIVE-SITE | COMPLEXES | CARBOXAMIDO-N | CHEMISTRY | METAL | SYNTHETIC ANALOGS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 47, pp. 18769 - 18783
The present perspective focusses on a variety of scaffolds based on a pyridine-2,6-dicarboxamide fragment and their noteworthy roles in coordination chemistry,... 
DIOXYGEN ACTIVATION | CARBON-DIOXIDE FIXATION | RUTHENIUM NITROSYLS | WATER-OXIDATION | CARBOXAMIDO-N | CONFORMATIONAL CONTROL | CATALYTIC-OXIDATION | COBALT(III) COMPLEXES | NITRILE HYDRATASE | OXYGEN-REBOUND MECHANISM | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 11/2016, Volume 45, Issue 47, pp. 18769 - 18783
The present perspective focusses on a variety of scaffolds based on a pyridine-2,6-dicarboxamide fragment and their noteworthy roles in coordination chemistry,... 
Catalysts | Stabilization | Transformations | Catalysis | Detection | Scaffolds | Recognition | Fragmentation
Journal Article
Dalton Transactions, ISSN 1477-9226, 10/2011, Volume 40, Issue 40, pp. 10758 - 10768
Using an acyclic hexadentate pyridine amide ligand, containing a -OCH2CH2O- spacer between two pyridine-2-carboxamide units... 
CYCLIC ALKENES | MONONUCLEAR | ACTIVE-SITE | THIOLATO-S | CATION-RADICAL COMPLEXES | RAY CRYSTAL-STRUCTURES | CARBOXAMIDO-N | NITROGEN DONORS | CONTAINING NITRILE HYDRATASE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2012, Volume 134, Issue 21, pp. 8758 - 8761
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 01/2016, Volume 55, Issue 2, pp. 566 - 572
Two mononuclear nonheme FeIII complexes, [PPh4]­[FeIII(PS3″)­(OCH3)] (1) and [PPh4]­[FeIII(PS3″)­(Cl)] (2), supported by a tris­(benzenethiolato)­phosphine... 
N(CH2CH2S)(3-) LIGAND | NONHEME IRON | THIOLATE | ACTIVE-SITE | RATE-DETERMINING STEP | CRYSTAL-STRUCTURE | ENZYMES | CATALYTIC NITRILE HYDRATION | CARBOXAMIDO-N | MODEL COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 04/2018, Volume 57, Issue 8, pp. 4277 - 4290
It has been before reported that, in addition to hydration of nitriles, the Fe-type nitrile hydratase (NHase) also catalyzes the hydrolysis of... 
CO-III COMPLEX | INFRARED-SPECTRA | MOLECULAR-ORBITAL METHODS | ACTIVE-SITE | ISONITRILE HYDRATASE | ORGANIC-SOLVENTS | NONHEME IRON CENTER | THIOLATO-S | CRYSTAL-STRUCTURE | CARBOXAMIDO-N | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 8/2012, Volume 41, Issue 36, pp. 1883 - 1899
The S-oxygenation of cysteine with dioxygen to give cysteine sulfinic acid occurs at the non-heme iron active site of cysteine dioxygenase. Similar... 
ISOPENICILLIN-N-SYNTHASE | ACTIVATION | S-OXYGENATION | CRYSTAL-STRUCTURE | ACTIVE-SITES | CARBOXAMIDO-N | CYSTEINE DIOXYGENASE MODEL | CATALYTIC-ACTIVITY | NITRILE HYDRATASE | SUBSTRATE-ANALOG | CHEMISTRY, INORGANIC & NUCLEAR | Enzymes | Cysteine | Focusing | Ligands | Iron | Transformations | Oxygenation | Sulfur
Journal Article
RSC ADVANCES, ISSN 2046-2069, 2016, Volume 6, Issue 76, pp. 72096 - 72106
A new family of sigma-aryl ruthenium(III) complexes [Ru(L1-4)(PPh3)(2)Cl] (1-4) (where (LH2)-H-1 = N-(quinolin-8-yl) benzamide for 1, (LH2)-H-2 =... 
METAL NITROSYLS | LIGANDS | SCHIFF-BASES | CARBOXAMIDO-N | CENTER-DOT | CATALYTIC TRANSFER HYDROGENATION | PHOTOLABILITY | NITROSYL COMPLEX | CHEMISTRY, MULTIDISCIPLINARY | VISIBLE-LIGHT IRRADIATION | AQUEOUS-SOLUTION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2011, Volume 133, Issue 11, pp. 3954 - 3963
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 12/2012, Volume 49, Issue 3, pp. 294 - 296
A series of Ru(ii) catalysts inspired by the metalloenzyme nitrile hydratase catalyze the hydration of benzonitrile with up to 242 turnovers under neutral... 
Ruthenium | Catalysts | Hydration | Product inhibition | Nitriles | Catalysis | Sulfur | Benzonitrile
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 12/2010, Volume 49, Issue 23, pp. 10875 - 10881
The ruthenium(II) dithiolate complex (bmmp-TASN)RuPPh3 (1) reacts with O-2 under limiting conditions to yield isolable sulfur oxygenated derivatives as a... 
K-EDGE XAS | THIOCYANATE HYDROLASE | ACTIVE-SITE | COMPUTATIONAL DESCRIPTION | NONHEME IRON CENTER | CARBOXAMIDO-N | OXIDIZED THIOLATE LIGANDS | CONTAINING NITRILE HYDRATASE | CATALYTIC-ACTIVITY | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 01/2017, Volume 2017, Issue 4, pp. 840 - 843
The presence of asymmetric cysteine sulfur‐oxygenation donors, consisting of sulfenate (SO), sulfinate (SO2), and thiolate (S), around a trivalent iron is... 
Oxidation | Enzyme catalysis | Bioinorganic chemistry | Metalloenzymes | S ligands | NONHEME IRON | CONTAINING NITRILE HYDRATASES | N,S COORDINATION | CRYSTAL-STRUCTURE | LOW-SPIN | CARBOXAMIDO-N | THIOLATO SULFUR | MODEL COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | SUPEROXIDE REDUCTASE | CATALYTIC-ACTIVITY | Sulfur | Nitrogen | Cysteine | Hydration | Polarization | Asymmetry | Nitrogen atoms | Nitriles | Activation | Iron | Bonding
Journal Article
Dalton Transactions, ISSN 1477-9226, 04/2011, Volume 40, Issue 13, pp. 3166 - 3175
The metal complexes, [M(Hdammthiol)(2)]Cl center dot 3H(2)O [M = Cr(III) (1), Fe(III) (2)] [where H(2)dammthiol is the thiol form of the ligand,... 
ANION RECEPTORS | CRYSTAL-STRUCTURE | CARBOXAMIDO-N | DONOR LIGAND | GAS-PHASE | MOLECULAR CHLORINE | AQUEOUS IONIC SOLVATION | MAGNETIC-PROPERTIES | NITRILE HYDRATASE | IRON(III) COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2015, Volume 21, Issue 44, pp. 15554 - 15563
Journal Article