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Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 38, pp. 11545 - 11548
The first highly enantioselective iridium‐catalyzed allylic alkylation that provides access to products bearing an allylic all‐carbon quaternary stereogenic... 
iridium | quaternary stereocenter | carboxylic acid derivatives | allylic alkylation | umpolung | SUBSTITUTION | REAGENTS | CHEMISTRY, MULTIDISCIPLINARY | CARBON STEREOGENIC CENTERS | DIASTEREO | ORIGINS | STEREOCENTERS | CONSTRUCTION | ESTERS | REGIO | ARYL
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 01/2018, Volume 24, Issue 6, pp. 1394 - 1403
A full account on rhodium‐catalyzed asymmetric, directed hydroboration of functionalized prochiral cyclopropenes affording enantiomerically enriched... 
protecting groups | cyclopropenes | asymmetric catalysis | hydroboration | rhodium | Hydroboration | Rhodium | Halogens | Chelation | Esters | Catalysis | Carboxylic acids | Enantiomers | Substrates | Organic compounds
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 38, pp. 11649 - 11652
A decarboxylative silylation of aliphatic N‐hydroxyphthalimide (NHPI) esters using Si−B reagents as silicon pronucleophiles is reported. This C(sp3)−Si... 
cross-coupling | radical reactions | copper | decarboxylation | silicon | ACTIVATION | VISIBLE-LIGHT PHOTOCATALYSIS | NUCLEOPHILIC-SUBSTITUTION | BOND FORMATION | QUATERNARY CARBONS | SILICON NUCLEOPHILES | CHEMISTRY, MULTIDISCIPLINARY | NICKEL | ESTERS | ALKYL ELECTROPHILES | BORYLATION | Copper | Esters | Couplings | Cross coupling | Amines | Reagents | Amino acids | Silicon | Carboxylic acids | Substrates | Aliphatic compounds
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 10/2017, Volume 23, Issue 59, pp. 14848 - 14859
... in the pharmaceutical and fine‐chemical industry as well as in biomass conversion. The challenges are associated predominantly with the fact that these carboxylic acid derivatives... 
chemoselectivity | N-methylation | rhenium | heterogeneous catalysis | hydrogenation | Evaluation | Heterogeneous catalysis | Amines | Catalysts | Amides | Esters | Methylation | Hydrogenation | Organic acids | Chemical industry | Carbon dioxide | Byproducts | Alcohol | Selectivity | Carboxylic acids | pH effects | Alkylation | Alcohols | Aromatic compounds | Benzene | Rhenium | Titanium dioxide
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2011, Volume 50, Issue 27, pp. 6004 - 6011
In the last decade, an increasing number of useful catalytic reductions of carboxylic acid derivatives with hydrosilanes have been developed... 
hydrosilylation | amides | esters | reduction | synthetic methods | SELF-ENCAPSULATION | TERTIARY-AMINES | SILANE REDUCTION | TRANSFER HYDROGENATION | CHEMISTRY, MULTIDISCIPLINARY | TRIRUTHENIUM CARBONYL CLUSTER | STEREOSELECTIVE HYDROSILYLATION | FACILE TRANSFORMATION | RUTHENIUM COMPLEX
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2015, Volume 54, Issue 52, pp. 15632 - 15641
Visible‐light‐induced radical decarboxylative functionalization of carboxylic acids and their derivatives has recently received considerable attention as a novel and efficient method to create CC and CX bonds... 
radicals | photochemistry | synthetic methods | carboxylic acids | CC coupling | C-C coupling | ROOM-TEMPERATURE | OXIDATIVE DECARBOXYLATION | MERGING PHOTOREDOX | NICKEL CATALYSIS | SYNTHETIC APPLICATIONS | ALPHA-AMINO-ACIDS | BOND FORMATION | QUATERNARY CARBONS | C-H FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS | Organic acids | Catalysis | Acids
Journal Article