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Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 52, pp. 7243 - 7246
We report the first diarylborane-catalysed hydrosilylation of epoxides and cyclic ethers. Mechanistic studies on the in situ generated Piers’ borane (C6F5)2BH... 
Ethers | Hydrosilylation
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 52, pp. 7243 - 7246
We report the first diarylborane-catalysed hydrosilylation of epoxides and cyclic ethers. Mechanistic studies on the in situ generated Piers' borane... 
ALCOHOLS | REARRANGEMENT | CATALYTIC HYDROGENOLYSIS | HYDROBORATION | BORON | REDUCTION | MECHANISM | DEOXYGENATION | SI-H | POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2011, Volume 50, Issue 27, pp. 6004 - 6011
In the last decade, an increasing number of useful catalytic reductions of carboxylic acid derivatives with hydrosilanes have been developed. Notably, the... 
hydrosilylation | amides | esters | reduction | synthetic methods | SELF-ENCAPSULATION | TERTIARY-AMINES | SILANE REDUCTION | TRANSFER HYDROGENATION | CHEMISTRY, MULTIDISCIPLINARY | TRIRUTHENIUM CARBONYL CLUSTER | STEREOSELECTIVE HYDROSILYLATION | FACILE TRANSFORMATION | RUTHENIUM COMPLEX
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 06/2013, Volume 19, Issue 26, pp. 8573 - 8590
The reactions of bis(borohydride) complexes [(RN)Mo(BH4)2(PMe3)2] (4: R=2,6‐Me2C6H3; 5: R=2,6‐iPr2C6H3) with hydrosilanes afford new silyl hydride derivatives... 
hydrides | hydrosilylation | fluxionality | silicon | molybdenum | ASYMMETRIC HYDROSILYLATION | TRANSITION-METAL-COMPLEXES | CRYSTAL-STRUCTURE | BOND FORMATION | ALDEHYDES | CATALYTIC HYDROSILYLATION | CHEMISTRY, MULTIDISCIPLINARY | KETONES | SI-H | ELECTRONIC-STRUCTURE | AROMATIC NITRILES | Like kind exchange | Ligands | Exchange | Silanes | Mathematical analysis | Hydrides | Hydrosilylation | Phosphines | Acetone
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 02/2019, Volume 2019, Issue 5, pp. 660 - 667
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 07/2019, Volume 2019, Issue 28, pp. 3335 - 3342
4‐Methoxy and 2,4‐di‐tBu substituted C,N‐chelating ligands 2‐[(2,6‐iPr2‐C6H3)N=CH]‐4‐MeO‐C6H3}– and {2‐[(2,6‐iPr2‐C6H3)N=CH]‐4,6‐tBu2‐C6H3}– and also... 
Hydrosilylation | N→Si coordination | Silicon | Structure elucidation | ACTIVATION | MECHANISM | N -> Si coordination | COMPLEXES | FREE CATALYTIC-HYDROGENATION | B(C6F5)-CATALYZED HYDROSILATION | REACTIVITY | CHEMISTRY, INORGANIC & NUCLEAR | REDUCTION | BOND COVALENT RADII | SI-H | Schiff bases | Substitutes | Chelation | Imines | Reaction kinetics
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 10/2018, Volume 872, pp. 73 - 78
In this paper, we propose an efficient method for the synthesis of new organosilicon compounds based on hydrosilylation of functional olefins with monohydrido... 
Organosilicon | Silsesquioxanes | Hydrosilylation | Siloxanes | Homogeneous catalysis | POLYMERS | POLYHEDRAL OLIGOSILSESQUIOXANE | CROSS-LINKING | CHEMISTRY, ORGANIC | CHEMISTRY, INORGANIC & NUCLEAR | FUNCTIONALIZATION | NANOCOMPOSITES | SILICONE-RUBBER | OLIGOMERIC SILSESQUIOXANE POSS | 1,1,3,3-TETRAMETHYLDISILOXANE | CATALYTIC-ACTIVITY | DERIVATIVES | Catalysis
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 68, pp. 9450 - 9453
Platinum–[diaminocarbene] complexes work as transition-metal photocatalysts for the hydrosilylation of alkynes. A catalytic system operates under visible light... 
Silanes | Light irradiation | Platinum | Photocatalysis | Light emitting diodes | Hydrosilylation | Coordination compounds | Photocatalysts | Diodes | Catalytic converters | Alkynes
Journal Article
Dalton Transactions, ISSN 1477-9226, 2018, Volume 47, Issue 12, pp. 4352 - 4359
The hydrido silyl iron complex (o-Ph2PC6H4SiMe2)Fe(PMe3)(3)H (2) was obtained via the activation of the Si-H bond of the bidentate silyl ligand... 
NICKEL-COMPLEXES | LIGANDS | REDUCTION | ALKANE HYDROXYLATION | COBALT COMPLEXES | PINCER COMPLEXES | PRIMARY AMIDES | RUTHENIUM | BOND ACTIVATION | ASYMMETRIC HYDROGENATION | CHEMISTRY, INORGANIC & NUCLEAR | Carbonyl compounds | Ketones | Activation | Catalytic activity | Iron | Hydrosilylation | Dehydration | Aldehydes | Benzamide | Alcohols | Hydrogen bonds | Catalysis | Carbonyls
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2016, Volume 81, Issue 10, pp. 4235 - 4243
The combination of amide activation by Tf2O with B­(C6F5)3-catalyzed hydrosilylation with TMDS constitutes a method for the one-pot reduction of secondary... 
ACID DERIVATIVES | CHEMOSELECTIVE REDUCTION | DIRECT TRANSFORMATION | CATALYTIC-HYDROGENATION | GLUTAMIC ACID | B(C6F5)-CATALYZED HYDROSILATION | TERTIARY AMIDES | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | SELECTIVE REDUCTION | GENERAL-METHOD | Amides | Chemical reactions | Amines | Chemical properties | Research
Journal Article
ChemCatChem, ISSN 1867-3880, 06/2018, Volume 10, Issue 11, pp. 2378 - 2382
Highly activated, monodispersed N,N‐dimethylformamide (DMF)‐stabilized iron‐oxide nanoparticles (Fe2O3 NPs) were synthesized by using iron(III) acetylacetonate... 
hydrosilylation | iron | sustainable chemistry | nanoparticles | colloids | METAL NANOCRYSTALS | ALPHA-FE2O3 | CHEMISTRY, PHYSICAL | C-H BONDS | NANOCLUSTERS | FUNCTIONALIZATION | CROSS-COUPLING REACTIONS | NICKEL | OLEFINS | XPS | STYRENE DERIVATIVES | Nanoparticles | Cytokinins | Dimethylformamide | Adsorption | Olefins | Green technology | X-ray spectroscopy
Journal Article
Green Chemistry, ISSN 1463-9262, 2017, Volume 19, Issue 11, pp. 2535 - 2540
An efficient, recyclable Pd-Cu bimetallic nanoparticle catalyst has been prepared, which exhibits superior activity and selectivity toward the hydrosilylation... 
PALLADIUM | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | CARBON | HYDROGENATION | SILANES | PLATINUM | ALLOY NANOPARTICLES | INTERNAL ALKYNES | SELECTIVE HYDROSILYLATION | REGIOSELECTIVE HYDROSILYLATION | CHEMISTRY, MULTIDISCIPLINARY | ALKENE HYDROSILYLATION
Journal Article